Application of Non-Linear Kinetic and Isotherm Model for Investigation of Cod Removal from Tapioca Liquid Waste Onto Modified Lampung Natural Zeolite
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Keywords:
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Adsorption, Fractional-power, Khan-model, Non-linear, Tapioca Liquid Waste
Abstract
The experimental data analysis of tapioca liquid waste onto modified Lampung natural zeolite using non-linear regression models is limited. The adsorption data were analyzed with nine kinetic models (the pseudo-first-order, the pseudo-second-order, the intraparticle diusion, fractional power, Bangham, Elovich, mixed-1.2-order, modification of pseudo-second-order, and Avrami) and eight isotherm models (Langmuir, Freundlich, Dubinin-Radushkevich, Sips, Redlich-Peterson, Toth, Liu, and Khan). The percentage of adsorption was decreased from 61.29% to 13.66% with increasing Chemical Oxygen Demand (COD) concentration 310 mg/L to 9450 mg/L. The result showed that the power model (R2 : 0.98, X2 : 0.137), Avrami (R2 : 0.98, X2 : 0.141), Bangham (R2 : 0.98, X2 : 0.145) and modified pseudo-second-order (R2 : 0.98, X2 : 0.147) can be recommended as the best fied to experimental kinetic data. The Khan model (R2 : 0.99961, X2 : 0.03729) and Langmuir (R2 : 0.99478, X2 : 0.24902) was the most reliable for describing the isotherm model. Thus, the analysis of experimental adsorption data using a non-linear regression model is highly recommended.
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Wang, L. C., Ni, X. jiong, Cao, Y. H., & Cao, G. qun. (2018). Adsorption behavior of bisphenol A on CTAB-modified graphite. Applied Surface Science, 428, 165–170. https://doi.org/10.1016/j.apsusc.2017.07.093
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Darmansyah, Saputra, H., Simparmin, B. G., & Ardiana, L. (2016). Synthesis and characterization of MCM-41 from coal fly ash for tapioca wastewater treatment. ARPN Journal of Engineering and Applied Sciences, 11(7), 4772–4777.
de la Luz-Asunción, M., Pérez-Ramírez, E. E., Martínez-Hernández, A. L., Castano, V. M., Sánchez-Mendieta, V., & Velasco-Santos, C. (2019). Non-linear modeling of kinetic and equilibrium data for the adsorption of hexavalent chromium by carbon nanomaterials: Dimension and functionalization. Chinese Journal of Chemical Engineering, 27(4), 912–919. https://doi.org/10.1016/j.cjche.2018.08.024
Edma, N. A., Sulaiman, A., Noraida, S., & Rahim, A. (2014). Enzymatic saccharification of Tapioca processing wastes into biosugars through immobilization technology. 1, 2–6.
Fito, J., Tefera, N., & Hulle, S. W. H. Van. (2017). Journal of Environmental Chemical Engineering Adsorption of distillery spent wash on activated bagasse fl y ash : Kinetics and thermodynamics. Journal of Environmental Chemical Engineering, 5(6), 5381–5388. https://doi.org/10.1016/j.jece.2017.10.009
Guo, J., Chen, S., Liu, L., Li, B., Yang, P., Zhang, L., & Feng, Y. (2012). Adsorption of dye from wastewater using chitosan-CTAB modified bentonites. Journal of Colloid and Interface Science, 382(1), 61–66. https://doi.org/10.1016/j.jcis.2012.05.044
Haerifar, M., & Azizian, S. (2014). Fractal-like kinetics for adsorption on heterogeneous solid surfaces. Journal of Physical Chemistry C, 118(2), 1129–1134. https://doi.org/10.1021/jp4110882
Halim, A. A., Aziz, H. A., Johari, M. A. M., & Ariffin, K. S. (2010). Comparison study of ammonia and COD adsorption on zeolite, activated carbon and composite materials in landfill leachate treatment. Desalination, 262(1–3), 31–35. https://doi.org/10.1016/j.desal.2010.05.036
Hermiati, E., Azuma, J., Sunarti, T. C., & Suparno, O. (2012). Potential utilization of cassava pulp for ethanol production in Indonesia. Scientific Research and Essays, 7(2), 100–106. https://doi.org/10.5897/SREX11.022
Ho, Y. S., & McKay, G. (1998). A Comparison of chemisorption kinetic models applied to pollutant removal on various sorbents. Process Safety and Environmental Protection, 76(4), 332–340. https://doi.org/10.1205/095758298529696
Khambhaty, Y., Mody, K., Basha, S., & Jha, B. (2009). Kinetics, equilibrium and thermodynamic studies on biosorption of hexavalent chromium by dead fungal biomass of marine Aspergillus niger. Chemical Engineering Journal, 145(3), 489–495. https://doi.org/10.1016/j.cej.2008.05.002
Kumar, K. V., Porkodi, K., & Rocha, F. (2008). Comparison of various error functions in predicting the optimum isotherm by linear and non-linear regression analysis for the sorption of basic red 9 by activated carbon. Journal of Hazardous Materials, 150(1), 158–165. https://doi.org/10.1016/j.jhazmat.2007.09.020
Kuo, C. (2009). Comparison with as-grown and microwave modi fi ed carbon nanotubes to removal aqueous bisphenol A. DES, 249(3), 976–982. https://doi.org/10.1016/j.desal.2009.06.058
Liu, J., Cheng, X., Zhang, Y., Wang, X., Zou, Q., & Fu, L. (2017). Zeolite modification for adsorptive removal of nitrite from aqueous solutions. Microporous and Mesoporous Materials, 252, 179–187. https://doi.org/10.1016/j.micromeso.2017.06.029
Marczewski, A. W. (2010). Application of mixed order rate equations to adsorption of methylene blue on mesoporous carbons. Applied Surface Science, 256(17), 5145–5152. https://doi.org/10.1016/j.apsusc.2009.12.078
Moussout, H., Ahlafi, H., Aazza, M., & Maghat, H. (2018). Critical of linear and nonlinear equations of pseudo-first order and pseudo-second order kinetic models. Karbala International Journal of Modern Science, 4(2), 244–254. https://doi.org/10.1016/j.kijoms.2018.04.001
Nagy, B., Mânzatu, C., Măicăneanu, A., Indolean, C., Barbu-Tudoran, L., & Majdik, C. (2017). Linear and nonlinear regression analysis for heavy metals removal using Agaricus bisporus macrofungus. Arabian Journal of Chemistry. https://doi.org/10.1016/j.arabjc.2014.03.004
Rodríguez, A., García, J., Ovejero, G., & Mestanza, M. (2009). Adsorption of anionic and cationic dyes on activated carbon from aqueous solutions: Equilibrium and kinetics. Journal of Hazardous Materials, 172(2–3), 1311–1320. https://doi.org/10.1016/j.jhazmat.2009.07.138
Rosa, A., Cristiani-urbina, M. C., & Cristiani-, E. (2015). Chromium Biosorption from Cr ( VI ) Aqueous Solutions by Cupressus lusitanica Bark : Kinetics , Equilibrium and Thermodynamic Studies. Vi, 1–23. https://doi.org/10.1371/journal.pone.0137086
Shen, L., Wang, W., Li, T., Cui, Y., Wang, B., Yu, G., Wang, X., Wei, D., Xiao, J., & Deng, S. (2019). Powdered activated coke for COD removal in the advanced treatment of mixed chemical wastewaters and regeneration by Fenton oxidation. Chemical Engineering Journal, 371(February), 631–638. https://doi.org/10.1016/j.cej.2019.04.086
Sivarajasekar, N., & Baskar, R. (2014). Adsorption of basic red 9 on activated waste Gossypium hirsutum seeds: Process modeling, analysis and optimization using statistical design. Journal of Industrial and Engineering Chemistry, 20(5), 2699–2709. https://doi.org/10.1016/j.jiec.2013.10.058
State, K., State, E., & State, K. (2012). Langmuir , Freundlich , Temkin and Dubinin – Radushkevich Isotherms Studies of Equilibrium Sorption of Zn 2 + Unto Phosphoric Acid Modified Rice Husk. 3(1), 38–45.
Taylor, P., Verma, S., Prasad, B., Mishra, I. M., Verma, S., Prasad, B., & Mishra, I. M. (2014). Separation Science and Technology Adsorption Kinetics and Thermodynamics of COD Removal of Acid Pre-treated Petrochemical Wastewater by using Granular Activated Carbon Adsorption Kinetics and Thermodynamics of COD Removal of Acid Pre-treated Petrochemical Wastewater by using Granular INTRODUCTION. October, 37–41. https://doi.org/10.1080/01496395.2013.870200
Wang, L. C., Ni, X. jiong, Cao, Y. H., & Cao, G. qun. (2018). Adsorption behavior of bisphenol A on CTAB-modified graphite. Applied Surface Science, 428, 165–170. https://doi.org/10.1016/j.apsusc.2017.07.093
Zhao, Q., Gao, Y., & Ye, Z. (2013). Reduction of COD in TNT red water through adsorption on macroporous polystyrene resin RS 50B. Vacuum, 95, 71–75. https://doi.org/10.1016/j.vacuum.2013.02.016
Authors
Supriyadi, D., Darmansyah, Puspita Sari, . R. ., & Citra Farhan, A. . (2021). Application of Non-Linear Kinetic and Isotherm Model for Investigation of Cod Removal from Tapioca Liquid Waste Onto Modified Lampung Natural Zeolite. Science and Technology Indonesia, 6(4), 218–227. https://doi.org/10.26554/sti.2021.6.4.218-227
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