Biogenic Silica Extracted from Salacca Leaves Ash for The Adsorption of Salycilic Acid
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Keywords:
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Adsorption, Biogenic Silica, Salicylic Acid
Abstract
Extraction of biogenic silica from Salacca leaves ash and it’s utilization as adsorbent for salycilic acid has been successfully conducted. The caustic extraction by Refluxing the ash in NaOH followed by slow titration using acid produced the silica gel, and in order to evaluate the physicochemical character for adsorption purpose, the sintering of the dried gel was varied at 300, 400 and 500oC. Instrumental analysis of x-ray diffraction, scanning electron microscopy, gas sorption analysis, and Fourier transform infrared spectroscopy were employed. The kinetics of the salycilic acid adsorption was investigated in a batch adsorption system and the quantitative analysis was based on UV–Vis spectrometry. The results showed that the produced silica exhibited adsorption capability for salycilic acid in an aqueous solution. At varied sintering temperature, the highest adsorption capacity and affinity was achieved by temperature of 500oC, and the adsorption kinetics obeyed the Langmuir isotherm. The varied pH for adsorption suggested neutral pH is the most feasible compared to the acidic and basic conditions.
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Rangaraj, S. and R. Venkatachalam (2017). A lucrative chem-
ical processing of bamboo leaf biomass to synthesize bio- compatible amorphous silica nanoparticles of biomedical
importance. Applied Nanoscience, 7(5); 145–153
Sadhu, K., A. Mukherjee, S. K. Shukla, K. Adhikari, and S. Dutta (2014). Adsorptive removal of phenol from coke-
oven wastewater using Gondwana shale, India: experiment, modeling and optimization. Desalination and Water Treatment, 52(34-36); 6492–6504
Silviana, S. and W. J. Bayu (2018). Silicon conversion from bamboo leaf silica by magnesiothermic reduction for devel- opment of Li-ion baterry anode. In Matec Web of Conferences, 156; 05021
Xu, H., Y. Gao, Q. Tao, A. Li, Z. Liu, Y. Jiang, H. Liu, R. Yang, and Y. Liu (2021). Synthesizing a surface-imprinted poly- mer based on the nanoreactor SBA-15 for optimizing the ad- sorption of salicylic acid from aqueous solution by response surface methodology. New Journal of Chemistry, 45(14); 6192–6205
Yagub, M., T. Sen, S. Afroze, and H. Ang (2014). Dye and its removal from aqueous solution by adsorption: a review. Advances Colloid Interface, 209; 172–184
Yuan, N., H. Cai, T. Liu, Q. Huang, and X. Zhang (2019). Adsorptive removal of methylene blue from aqueous solu- tion using coal fly ash-derived mesoporous silica material. Adsorption Science & Technology, 37(3-4); 333–348
Zou, C., J. Liang, W. Jiang, Y. Guan, and Y. Zhang (2018). Adsorption behavior of magnetic bentonite for removing Hg (II) from aqueous solutions. The Royal Society of Chemistry Advances, 8(48); 27587–27595
Cabrera-Lafaurie, W. A., F. R. Román, and A. J. Hernández- Maldonado (2014). Removal of salicylic acid and carba- mazepine from aqueous solution with Y-zeolites modified with extraframework transition metal and surfactant cations: equilibrium and fixed-bed adsorption. Journal of Environ- mental Chemical Engineering, 2(2); 899–906
Câmara, L. and A. S. Neto (2008). Modeling of the kinetic of salicylic acid adsorption in polymeric and activated charcoal adsorbent. Revista de Engenharia Térmica, 7(1); 49–54
Choi, J. and W. S. Shin (2020). Removal of salicylic and ibupro- fen by hexadecyltrimethylammonium-modified montmoril- lonite and zeolite. Minerals, 10(10); 898
Chun, J., Y. M. Gu, J. Hwang, K. K. Oh, and J. H. Lee (2020). Synthesis of ordered mesoporous silica with various pore structures using high-purity silica extracted from rice husk. Journal of Industrial and Engineering Chemistry, 81; 135–143
Dada, A., A. Olalekan, A. Olatunya, and O. Dada (2012). Langmuir, Freundlich, Temkin and Dubinin–Radushkevich isotherms studies of equilibrium sorption of Zn2+ unto phos- phoric acid modified rice husk. Journal of Applied Chemistry, 3(1); 38–45
Fatimah, I., S. N. Amaliah, M. F. Andrian, T. P. Handayani, R. Nurillahi, N. I. Prakoso, W. P. Wicaksono, and L. Chuen- chom (2019). Iron oxide nanoparticles supported on bio- genic silica derived from bamboo leaf ash for rhodamine B photodegradation. Sustainable Chemistry and Pharmacy, 13(3); 100149
Freitas, R., S. Silvestro, F. Coppola, V. Meucci, F. Battaglia, L. Intorre, A. M. Soares, C. Pretti, and C. Faggio (2020). Combined effects of salinity changes and salicylic acid expo- sure in Mytilus galloprovincialis. Science of The Total Envi- ronment, 715; 136804
Gómez-Oliván, L. M., M. Galar-Martínez, H. Islas-Flores, S. García-Medina, and N. SanJuan-Reyes (2014). DNA damage and oxidative stress induced by acetylsalicylic acid in Daphnia magna. Comparative Biochemistry and Physiology Part C: Toxicology & Pharmacology, 164; 21–26
Jaafari, S. A. A. H., J. Athinarayanan, V. S. Periasamy, and A. A. Alshatwi (2020). Biogenic silica nanostructures derived from Sorghum bicolor induced osteogenic differentiation through BSP, BMP-2 and BMP-4 gene expression. Process Biochemistry, 91(12); 231–240
Lee, W., S. Yoon, J. K. Choe, M. Lee, and Y. Choi (2018). An- ionic surfactant modification of activated carbon for enhanc- ing adsorption of ammonium ion from aqueous solution. Science of The Total Environment, 639; 1432–1439
Maseko, N. N., D. Schneider, S. Wassersleben, D. Enke, S. A. Iwarere, J. Pocock, and A. Stark (2021). The production of biogenic silica from different South African agricultural residues through a thermo-chemical treatment method. Sus- tainability, 13(2); 577
Mattos, B. D., O. J. Rojas, and W. L. Magalhães (2016). Bio- genic SiO2 in colloidal dispersions via ball milling and ultra- sonication. Powder Technology, 301; 58–64
Mustafa, S., B. Dilara, A. Naeem, N. Rehana, and K. Nargis (2003). Temperature and pH effect on the sorption of diva- lent metal ions by silica gel. Adsorption Science & Technology, 21(4); 297–307
Nunes, B. (2019). Acute ecotoxicological effects of salicylic acid on the Polychaeta species Hediste diversicolor: evidences of low to moderate pro-oxidative effects. Environmental Science and Pollution Research, 26(8); 7873–7882
Otero, M., C. A. Grande, and A. E. Rodrigues (2004). Adsorp- tion of salicylic ccid onto polymeric adsorbents and activated charcoal. Reactive and Functional Polymers, 60; 203–213
Peerzada, J. G. and R. Chidambaram (2020). A statistical approach for biogenic synthesis of nano-silica from different agro-wastes. Silicon, 13(7); 1–13
Prasad, R. and M. Pandey (2012). Rice husk ash as a renew- able source for the production of value added silica gel and its application: an overview. Bulletin of Chemical Reaction Engineering and Catalysis, 7(1); 1–25
Rahangdale, D., G. Archana, and A. Kumar (2016). Molecu- larly imprinted chitosan-based adsorbents for the removal of salicylic acid and its molecular modeling to study the in- fluence of intramolecular hydrogen bonding of template on
molecular recognition of molecularly imprinted polymer.
Adsorption Science & Technology, 34(7-8); 405–425
Rakić, V., N. Rajić, A. Daković, and A. Auroux (2013). The ad- sorption of salicylic acid, acetylsalicylic acid and atenolol from aqueous solutions onto natural zeolites and clays: Clinoptilolite, bentonite and kaolin. Microporous and Meso-
porous Materials, 166; 185–194
Rakishev, A., M. Vedenyapina, S. Kulaishin, and D. Kurilov
(2021). Adsorption of salicylic acid from aqueous solutions on microporous granular activated carbon. Solid Fuel Chem- istry, 55(2); 117–122
Rangaraj, S. and R. Venkatachalam (2017). A lucrative chem-
ical processing of bamboo leaf biomass to synthesize bio- compatible amorphous silica nanoparticles of biomedical
importance. Applied Nanoscience, 7(5); 145–153
Sadhu, K., A. Mukherjee, S. K. Shukla, K. Adhikari, and S. Dutta (2014). Adsorptive removal of phenol from coke-
oven wastewater using Gondwana shale, India: experiment, modeling and optimization. Desalination and Water Treatment, 52(34-36); 6492–6504
Silviana, S. and W. J. Bayu (2018). Silicon conversion from bamboo leaf silica by magnesiothermic reduction for devel- opment of Li-ion baterry anode. In Matec Web of Conferences, 156; 05021
Xu, H., Y. Gao, Q. Tao, A. Li, Z. Liu, Y. Jiang, H. Liu, R. Yang, and Y. Liu (2021). Synthesizing a surface-imprinted poly- mer based on the nanoreactor SBA-15 for optimizing the ad- sorption of salicylic acid from aqueous solution by response surface methodology. New Journal of Chemistry, 45(14); 6192–6205
Yagub, M., T. Sen, S. Afroze, and H. Ang (2014). Dye and its removal from aqueous solution by adsorption: a review. Advances Colloid Interface, 209; 172–184
Yuan, N., H. Cai, T. Liu, Q. Huang, and X. Zhang (2019). Adsorptive removal of methylene blue from aqueous solu- tion using coal fly ash-derived mesoporous silica material. Adsorption Science & Technology, 37(3-4); 333–348
Zou, C., J. Liang, W. Jiang, Y. Guan, and Y. Zhang (2018). Adsorption behavior of magnetic bentonite for removing Hg (II) from aqueous solutions. The Royal Society of Chemistry Advances, 8(48); 27587–27595
Authors
Fatimah, I., Ulfiyani Zaenuri, F., Narulita Doewandono, L., Yahya, A., Widya Citradewi, P., Sagadevan, S., & Oh, W.-C. (2021). Biogenic Silica Extracted from Salacca Leaves Ash for The Adsorption of Salycilic Acid . Science and Technology Indonesia, 6(4), 296–302. https://doi.org/10.26554/sti.2021.6.4.296-302
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