Photocatalytic Degradation of Rhodamine-B by Ni/Zn LDH Intercalated Polyoxometalate Compound

Yulizah Hanifah, Risfidian Mohadi, Mardiyanto, Aldes Lesbani

Abstract

NiAl-LDH and ZnAl-LDH intercalated polyoxometalate K4 [SiW12O40] and K3 [PW12O40] were synthesized to form composite NiAl-[SiW12O40], NiAl-[PW12O40], ZnAl-[SiW12O40], and ZnAl-[PW12O40]. The physicochemical properties of the materials were characterized by XRD, FTIR, SEM, and UV-DRS. The material used for degraded Rhodamine B (RhB) as a cation dye. The results successfully synthesized by showed the peak diffractions angles at 11.63°, 23.13°, and 35.16° for NiAl-LDH and diffractions at 10.39°, 20.17°, 34.6° and 60.52°for ZnAl-LDH. The LDH typical structure of the composite materials NiAl-[SiW12O40] and NiAl-[PW12O40] was demonstrated by apparent diffraction at 2???? angles of 10.76°, 26.59°, 30.8°, and 63.11° for NiAl [PW12O40], 2???? angles at 8.26°, 11.34°, 29°, and 35.1° for NiAl-[SiW12O40], 7.73°, 28.6° and 35.6° for ZnAl-[PW12O40], and 8.61°, 25.27°, 34.96° and 66.34° for ZnAl-[SiW12O40]. The materials were characterized as an advanced catalyst to improve photocatalytic activity for RhB elimination under visible light sources. The intercalation of polyoxometalate [SiW12O40]4- and [PW12O40]3- into LDH could enhance the degradation cationic dye of RhB. Intercalation improved the photodegradation performance determined under UV-Vis irradiation conditions which composite NiAl-LDH was better than ZnAl-LDH composite. It was present by the %degradation RhB performances NiAl-LDH, ZnAl-LDH, NiAl-[SiW12O40], NiAl-[PW12O40], ZnAl-[SiW12O40], and ZnAl-[PW12O40] were 91.48%, 88.59%, and 88.41%, and 87.87%, respectively. The %degradation for NiAl-LDH and ZnAl-LDH was 68.94% and 65.76%. Recovery and reusability experiment of the catalyst demonstrated by degradation percentage that the LDH intercalated polyoxometalate has a great photocatalytic ability.

References

Abideen, Z. U. and F. Teng (2020). Fe2O3-Promoted Interface Charge Separation and Visible-light Activity of Fe2O3@ Zn0. 3Cd0. 7S. Materials Chemistry and Physics, 246(2); 122811

Ahsaine, H. A., M. Zbair, Z. Anfar, Y. Naciri, N. El Alem, and M. Ezahri (2018). Cationic Dyes Adsorption Onto High Surface Area ‘almond Shell’Activated Carbon: Kinetics, Equilibrium Isotherms and Surface Statistical Modeling. Materials Today Chemistry, 8(3); 121–132

Amini, M., M. Khaksar, A. Ellern, and L. K. Woo (2018). A New Nanocluster Polyoxomolybdate [Mo36O110 (NO) 4 (H2O) 14]· 52H2O: Synthesis, Characterization and Application in Oxidative Degradation of Common Organic Dyes. Chinese Journal of Chemical Engineering, 26(2); 337–342

Danafar, H. and B. Yadollahi (2009). (TBA) 4PFeW11O39·3H2O Catalyzed Efficient and Facile Ring Opening Reaction of Epoxides with Aromatic Amines. Catalysis Communications, 10(6); 842–847

Das, S. (2021). Superior Photocatalytic Performance of Co Al LDH in the Race of Metal Incorporated LDH: a Comparison Study. Materials Today, 35(4); 275–280

Elhalil, A., M. Sadiq, M. Abdennouri, Y. Kadmi, L. Favier, and N. Barka (2018). Synthesis of Ba doped ZnO/Al2O3 Nanocomposite from Layered Double Hydroxide Structure and Their Photocatalytic Activity for the Degradation of Caffeine. Journal of Applied Surfaces and Interfaces, 4(1-3); 9–16

Gascho, J. L., S. F. Costa, A. A. Recco, and S. H. Pezzin (2019). Graphene Oxide Films Obtained by Vacuum Filtration: Xray Diffraction Evidence of Crystalline Reorganization. Journal of Nanomaterials, 2019(4); 1–12

Hanifah, Y., R. Mohadi, M. Mardiyanto, and A. Lesbani (2022). Photocatalytic Degradation of Malachite Green by NiAlLDH Intercalated Polyoxometalate Compound. Bulletin of Chemical Reaction Engineering & Catalysis, 17(3); 627–637

Hanifah, Y., R. Mohadi, M. Mardiyanto, and A. Lesbani (2023). Polyoxometalate Intercalated MgAl-Layered Double Hydroxide for Degradation of Malachite Green. Ecological Engineering & Environmental Technology, 24(2); 109–119

Hasannia, S. and B. Yadollahi (2015). Zn-Al LDH Nanostructures Pillared by Fe Substituted Keggin Type Polyoxometalate: Synthesis, Characterization and Catalytic Effect in Green Oxidation of Alcohols. Polyhedron, 99; 260–265

Kangralkar, M., V. Kangralkar, N. Momin, and J. Manjanna (2019). Cu2O Nanoparticles for Removal of Methylene Blue Dye from Solution. Environmental Nanotechnology, Monitoring and amp; Management; 100265

Koppala, S. R., K. Balan, L. Banerjee, H. Li, K. Liu, K. Kumar, V. Raghava, Reddy, and V. Sadhu (2021). Room Temperature Synthesis of Novel Worn Like Tin Oxide Nanoparticle for Photocatalytic Degradation of Organic Pollutants. Material Science Energy Technologies, 4; 113-118

Lesbani, A. and R. Mohadi (2014). Brönsted Acid of Keggin Type Polyoxometalate Catalyzed Pinacol Rearrangement. Bulletin Chemical Reaction Engineering and Catalysis, 9(2); 236–141

Lesbani, A., P. M. S. B. N. Siregar, N. R. Palapa, T. Taher, and F. Riyanti (2021). Adsorptive Removal MethyleneBlue Using Zn/Al LDH Modified Rice Husk Biochar. Polish Journal of Environmental Studies, 30(4); 3117–3124

Li, Z., M. Chen, H. Hu, Q. Zhang, and D. Tao (2020). Mechanochemical Synthesis of Novel Pt Modified ZnAlLDH for Effective Ciprofloxacin Photodegradation. Journal of Solid State Chemistry, 290(8); 121594

Miao, Y. F., R. T. Guo, J. W. Gu, Y. Z. Liu, G. L. Wu, C. P. Duan, X. D. Zhang, and W. G. Pan (2020). Fabrication of ???? -In2S3/NiAl-LDH Heterojunction Photocatalyst with Enhanced Separation of Charge Carriers for Efficient CO2 Photocatalytic Reduction. Applied Surface Science, 527(8); 146792

Nayak, S. and K. Parida (2016). Nanostructured CeO2/MgAlLDH Composite for Visible Light Induced Water Reduction Reaction. International Journal of Hydrogen Energy, 41(46); 21166-21180

Normah, N., N. R. Palapa, T. Taher, R. Mohadi, H. P. Utami, and A. Lesbani (2021). The Ability of Composite Ni/AlCarbon Based Material Toward Readsorption of Iron (II) in Aqueous Solution. Science and Technology Indonesia, 6(3); 156–165

Qing, X., L. Yuan, Y. Wang, Z. Zhang, M. Bi, and X. Weng (2021). Synergistic Influence of Cr3+ and CrO42- on the Visible Near Infrared Spectrum of Mg-Al Layered Double Hydroxides for Efficient Visible Light Photocatalysis. Journal of Alloys and Compounds, 872; 159628

Siregar, P. M. S. B. N., A. Lesbani, and R. Mohadi (2022). Mg/Al Chitosan as a Selective Adsorbent in The Removal of Methylene Blue from Aqueous Solutions. Science and Technology Indonesia, 7(2); 170–178

Syah, R., A. Al-Khowarizmi, M. Elveny, and A. Khan (2021). Machine Learning Based Simulation of Water Treatment Using LDH/MOF Nanocomposites. Environmental Technology & Innovation, 23; 101805

Wang, Y., F. Song, J. Zhu, Y. Zhang, L. Du, and C. Kan (2018). Highly Selective Fluorescent Probe Based on a Rhodamine B and Furan-2-carbonyl Chloride Conjugate for Detection of Fe3+ in Cells. Tetrahedron letters, 59(42); 3756–3762

Wijaya, A., P. M. S. B. N. Siregar, A. Priambodo, N. R. Palapa, T. Taher, and A. Lesbani (2021). Innovative Modified of CuAl/C (C= Biochar, Graphite) Composites for Removal of Procion Red from Aqueous Solution. Science and Technology Indonesia, 6(4); 228–234

Wu, X., C. Ci, Y. Du, X. Liu, X. Li, and X. Xie (2018). Facile Synthesis of NiAl-LDHs with Tunable Establishment of Acid-base Activity Sites. Materials Chemistry and Physics, 211; 72–78

Xiang, L., X. Zhu, L. Kong, H. Zhou, M. Wu, H. Qian, and W. Wang (2018). Small Lanthanide-doped Sr2YbF7 Nanocrystals: Upconversion Fluorescence and Upconversion-driven Photodegradation. Optical Materials, 86; 537–544

Xu, M., B. Bi, B. Xu, Z. Sun, and L. Xu (2018). Polyoxometalate Intercalated ZnAlFe Layered Double Hydroxides for Adsorbing Removal and Photocatalytic Degradation of Cationic Dye. Applied Clay Science, 157; 86–91

Xu, M., G. Pan, Y. Meng, Y. Guo, T. Wu, and H. Chen (2019). Effect of Ce3+ on the Photocatalytic Activity of MAlCe Ternary Hydrotalcites Like Compounds in Methylene Blue Photodegradation. Applied Clay Science, 170; 46–56

Xue, X., F. Yu, J. G. Li, G. Bai, H. Yuan, J. Hou, B. Peng, L. Chen, M. F. Yuen, and G. Wang (2020). Polyoxometalate Intercalated NiFe Layered Double Hydroxides for Advanced Water Oxidation. International Journal of Hydrogen Energy, 45(3); 1802–1809

Yuliasari, N., A. Wijaya, R. Mohadi, E. Elfita, and A. Lesbani (2022). Photocatalytic Degradation of Malachite Green by Layered Double Hydroxide Based Composites. Bulletin of Chemical Reaction Engineering & Catalysis, 17(2); 240–249

Zhang, F., B. Lu, and P. Sun (2020). Highly Stable Ni-based Catalysts Derived from LDHs Supported on Zeolite for CO2 Methanation. International Journal of Hydrogen Energy, 45(32); 16183–16192

Zhang, L., Y. Meng, H. Shen, J. Li, C. Yang, B. Xie, and S. Xia (2021). Photocatalytic Degradation of Rhodamine B by Bi2O3@ LDHs Scheme Heterojunction: Performance, Kinetics and Mechanism. Applied Surface Science, 567; 150760

Zhang, S., Y. Han, L. Wang, Y. Chen, and P. Zhang (2014). Treatment of Hypersaline Industrial Wastewater from Salicylaldehyde Production by Heterogeneous Catalytic Wet Peroxide Oxidation on Commercial Activated Carbon.
Chemical Engineering Journal, 252; 141–149

Authors

Yulizah Hanifah
Risfidian Mohadi
Mardiyanto
Aldes Lesbani
aldeslesbani@pps.unsri.ac.id (Primary Contact)
Hanifah, Y., Mohadi, R., Mardiyanto, & Lesbani, A. . (2023). Photocatalytic Degradation of Rhodamine-B by Ni/Zn LDH Intercalated Polyoxometalate Compound. Science and Technology Indonesia, 8(1), 93–99. https://doi.org/10.26554/sti.2023.8.1.93-99

Article Details

Most read articles by the same author(s)

1 2 3 4 5 6 7 > >>