Preparation and Characterization of Fe2O3 from Iron Sand of the Coastal Sea of Cidaun Beach-South Cianjur (Indonesia) using the Co-precipitation Method
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Keywords:
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Iron Sand, Maghemite, Hematite, Ilmenite, Milling
Abstract
The synthesis and characterization of Fe2O3 from Iron Sand of the coastal sea of Cidaun Beach - South Cianjur using the coprecipitation method has been carried out. The purpose of this research was to identify the crystal structure, magnetic mineral content, and magnetic properties of iron sands. The characterizations used in this research are X-Ray Diffraction (XRD), Scanning Electron Microscope-Energy Dispersive X-Ray (SEM-EDX) and Vibrating Sample Magnetometer (VSM). Based on the XRD results, it shows that the iron sand sample produces multi-phases, namely hematite (????-Fe2O3), maghemite (????-Fe2O3) and ilmenite (FeTiO3). SEM-EDX results indicate that the iron sand samples have an average particle size of 12.396 ????m. VSM results indicate that the iron sand sample is soft magnetic (ferrimagnetic) with saturation, remanence and coercivity values of 47 emu/g, 1.53 emu/g and 102.97 Oe, respectively.
References
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Shokrollahi, H. (2017). A Review of the Magnetic Properties, Synthesis Methods and Applications of Maghemite. Journal of Magnetism and Magnetic Materials, 426; 74–81
Sihombing, M. and E. Amiruddin (2020). Sintesis Dan Karakterisasi Nanopartikel Fe2O3 Dari Pasir Alam Desa Logas Kabupaten Kuantan Singingi. Komunikasi Fisika Indonesia, 17(2); 68–73 (In Indonesia)
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Susilawati, S., A. Doyan, M. Taufik, W. Wahyudi, E. R. Gunawan, A. Fitriani, and N. Nazarudin (2019). Characterization of Barium M-Hexaferrite with Doping Zn and Mn for Microwaves Absorbent. Materials Science Forum, 966; 282–289
Tadic, M., M. Panjan, V. Damnjanovic, and I. Milosevic (2014). Magnetic Properties of Hematite (????-Fe2O3) Nanoparticles Prepared by Hydrothermal Synthesis Method. Applied Surface Science, 320; 183–187
Togibasa, O., M. Akbar, A. Pratama, and S. Bijaksana (2019). Distribution of Magnetic Susceptibility of Natural Iron Sand in the Sarmi Coast Area. Journal of Physics: Conference Series, 1204(1); 012074
Togibasa, O., S. Bijaksana, and G. C. Novala (2018). Magnetic properties of iron sand from the Tor River Estuary, Sarmi, Papua. Geosciences, 8(4); 113
Wahyuningsih, S., A. Ramelan, H. Pranata, Q. Hanif, Y. Ismoyo, and K. Ichsan (2016). Preparation of Fe2O3-TiO2 Composite from Sukabumi Iron Sand Through Magnetic Separation, Pyrometallurgy, and Hydrometallurgy. Journal of Physics, 776(1); 012026
Widodo, R., S. Anis, A. Ichwani, B. Setiawan, D. Fitriyana, and L. Rochman (2020). Synthesis and Characterization of Iron (III) Oxide from Natural Iron Sand of the South Coastal Area, Purworejo Central Java. Journal of Physics, 1444(1); 012043
Yulia, W. and E. Erwin (2019). Analisis Sifat Magnetik dan Struktur Partikel Pasir Besi Pantai Arta Pariaman Sumatera Barat Menggunakan Ball Milling. Komunikasi Fisika Indonesia, 16(2); 107–112 (In Indonesia)
Al Hadi, F. H., T. Haryati, N. Andarini, and Y. A. Sulistiyo (2023). Hydrothermal Synthesis of Hematite (????-Fe2O3) from Indonesia Iron Sand. Indonesian Chimica Letters, 2(1); 10–13
Babay, S., T. Mhiri, and M. Toumi (2015). Synthesis, Structural and Spectroscopic Characterizations of Maghemite ????- Fe2O3 Prepared by One-step Coprecipitation Route. Journal of Molecular Structure, 1085; 286–293
Dewi, S. H. and W. A. Adi (2018). Synthesis and Characterization of High Purity Fe3O4 and ???? Fe2O3 from Local Iron Sand. Journal of Physics, 1091; 012021
Fatmaliana, A., M. Maulinda, and N. Sari (2020). Synthesis and Characterization of Hematite (Fe2O3) of Iron Ore and Magnetite (Fe3O4) from Iron Sand Through Precipitation Method for Industrial Raw Materials. Jurnal Neutrino: Jurnal Fisika dan Aplikasinya, 12(2); 37–42
Fouda, A., S. E. D. Hassan, E. Saied, and M. S. Azab (2021). An Eco-friendly Approach to Textile and Tannery Wastewater Treatment Using Maghemite Nanoparticles (????-Fe2O3- NPs) Fabricated by Penicillium Expansum Strain (Kw). Journal of Environmental Chemical Engineering, 9(1); 104693
Gunanto, Y., M. Izaak, E. Jobiliong, L. Cahyadi, and W. Adi (2018). High purity Fe3O4 from local iron sand extraction. 1011(1); 012005
Karbeka, M., F. V. Koly, and N. M. Tellu (2021). Characterization of Magnetic Content From Puntaru Beach Iron Sand. Conference Proceedings, 2349(1)
Karbeka, M., F. V. L. Koly, and N. M. Tellu (2020). Karakterisasi Sifat Kemagnetan Pasir Besi Pantai Puntaru Kabupaten Alor-NTT. Lantanida Journal, 8(2); 108–116
Kazeminezhad, I. and S. Mosivand (2014). Phase Transition of Electrooxidized Fe3O4 to ???? and ????-Fe2O3 Nanoparticles Using Sintering Treatment. Acta Physica Polonica A, 125(5); 1210–1214
Kiswanto, H., A. H. P. Yuniarto, N. I. Istiqomah, and E. Suharyadi (2021). Struktur Kristal dan Sifat Kemagnetan Nanopartikel Mn-Ferrite yang Disintesis dari Bahan Alam Pasir Besi. Jurnal Fisika Unand, 10(4); 413–420 (In Indonesia)
Lassoued, A., B. Dkhil, A. Gadri, and S. Ammar (2017). Control of the Shape and Size of Iron Oxide (????-Fe2O3) Nanoparticles Synthesized Through the Chemical Precipitation Method. Results in Physics, 7; 3007–3015
Lepp, H. (1957). Stages in the oxidation of magnetite. Mineralogical Society of Americ
Liu, X., S. Tao, and Y. Shen (1997). Preparation and Characterization of Nanocrystalline ???? Fe2O3 by a Sol-gel Process. Sensors and Actuators B: Chemical, 40(2-3); 161–165
Mishra, M. and D. M. Chun (2015). ????-Fe2O3 as a Photocatalytic Material: A Review. Applied Catalysis A: General, 498; 126–141
Muhajir, M., P. Puspitasari, and J. A. Razak (2020). Synthesis and Applications of Hematite ???? Fe2O3: A Review. Journal of Mechanical Engineering Science and Technology (JMEST), 3(2); 51–58
Nengsi, S. W., A. Budiman, and D. Puryanti (2016). Karakterisasi Struktur Kristal dan Sifat Magnetik Maghemit (????- Fe2O3) yang Dioksidasi dari Magnetit (Fe3O4) dari Pasir Besi Batang Sukam Kabupaten Sijunjung Sumatera Barat dengan Variasi Waktu Oksidasi. Jurnal Fisika Unand, 5(3); 248–251 (In Indonesia)
Nurayni, S. and R. N. Nofitasari (2018). Characterization of Mineral Content of Iron Sand at Depok Beach, Sigandu Beach and Muara Beach in Batang Regency. Journal of Natural Sciences and Mathematics Research, 4(1); 23–26
Patimah, P. and T. E. Saraswati (2016). Pengaruh Suhu Kalsinasi Pada Sifat Kemagnetan Material Besi Oksida Hasil Elektrolisis. Jurnal Kimia Dan Pendidikan Kimia, 1(3); 149–156 (In Indonesia)
Rianna, M., T. Sembiring, M. Situmorang, C. Kurniawan, E. A. Setiadi, A. P. Tetuko, S. Simbolon, M. Ginting, and P. Sebayang (2018). Characterization of natural iron sand from Kata Beach, West Sumatra with high energy milling (Hem). Jurnal Natural, 18(2); 97–100
Rusianto, T., M. W. Wildan, and K. Abraha (2015). Characterizations of Ceramic Magnets from Iron Sand. International Journal of Technology, 6(6); 1017–1024
Saragi, T., E. Noelik, and D. Gustaman (2012). Pengembangan Bahan Magnetik Barium Heksaferite dari Mineral Yarosit Alam dan Karakterisasinya. Bionatura, 14(2); 156–163
Shokrollahi, H. (2017). A Review of the Magnetic Properties, Synthesis Methods and Applications of Maghemite. Journal of Magnetism and Magnetic Materials, 426; 74–81
Sihombing, M. and E. Amiruddin (2020). Sintesis Dan Karakterisasi Nanopartikel Fe2O3 Dari Pasir Alam Desa Logas Kabupaten Kuantan Singingi. Komunikasi Fisika Indonesia, 17(2); 68–73 (In Indonesia)
Soekansa, A. F., N. Sudirman, and S. Aini (2023). Sintesis dan Karakterisasi Pigmen Merah Hematit (????-Fe2O3) dari Pasir Besi Kabupaten Sijunjung, Sumatera Barat, Indonesia. Jurnal Periodic Jurusan Kimia UNP, 12(1); 9–13 (In Indonesia)
Susilawati, S., A. Doyan, M. Taufik, W. Wahyudi, E. R. Gunawan, A. Fitriani, and N. Nazarudin (2019). Characterization of Barium M-Hexaferrite with Doping Zn and Mn for Microwaves Absorbent. Materials Science Forum, 966; 282–289
Tadic, M., M. Panjan, V. Damnjanovic, and I. Milosevic (2014). Magnetic Properties of Hematite (????-Fe2O3) Nanoparticles Prepared by Hydrothermal Synthesis Method. Applied Surface Science, 320; 183–187
Togibasa, O., M. Akbar, A. Pratama, and S. Bijaksana (2019). Distribution of Magnetic Susceptibility of Natural Iron Sand in the Sarmi Coast Area. Journal of Physics: Conference Series, 1204(1); 012074
Togibasa, O., S. Bijaksana, and G. C. Novala (2018). Magnetic properties of iron sand from the Tor River Estuary, Sarmi, Papua. Geosciences, 8(4); 113
Wahyuningsih, S., A. Ramelan, H. Pranata, Q. Hanif, Y. Ismoyo, and K. Ichsan (2016). Preparation of Fe2O3-TiO2 Composite from Sukabumi Iron Sand Through Magnetic Separation, Pyrometallurgy, and Hydrometallurgy. Journal of Physics, 776(1); 012026
Widodo, R., S. Anis, A. Ichwani, B. Setiawan, D. Fitriyana, and L. Rochman (2020). Synthesis and Characterization of Iron (III) Oxide from Natural Iron Sand of the South Coastal Area, Purworejo Central Java. Journal of Physics, 1444(1); 012043
Yulia, W. and E. Erwin (2019). Analisis Sifat Magnetik dan Struktur Partikel Pasir Besi Pantai Arta Pariaman Sumatera Barat Menggunakan Ball Milling. Komunikasi Fisika Indonesia, 16(2); 107–112 (In Indonesia)
Authors
Puspita, E., Ginting, M. ., & Ramlan. (2023). Preparation and Characterization of Fe2O3 from Iron Sand of the Coastal Sea of Cidaun Beach-South Cianjur (Indonesia) using the Co-precipitation Method. Science and Technology Indonesia, 8(4), 594–598. https://doi.org/10.26554/sti.2023.8.4.594-598
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