Sodium Methoxide Catalyzed Preparation of Nitrogen Compounds from Palm Oil Methyl Esters as Corrosion Inhibitor
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Keywords:
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Nitrogen Compounds, Palm Oil Methyl Esters, Green Corrosion Inhibitors, Mild Steel, Wheel Test
Abstract
This research was conducted to study preparation of nitrogen compounds by reacting palm oil derived methyl esters and diethanolamine using sodium methoxide as a catalyst. The chemical composition of the product was analyzed using the gas chromatography-mass spectrometry (GC-MS) method. The product was then applied as a corrosion inhibitor for mild steel in CO2 saturated 3% NaCl solution. Experimental results indicate that the reaction product contains six nitrogen compounds with a relative percentage of 63.7%, and the rest 36.7% are a mixture of unreacted diethanolamine and unreacted methyl esters. The results of the corrosion experiments show that the product obtained exhibited appreciably high performance as reflected by a percentage of protection (%P) of 96.85%. The performance of the product as a corrosion inhibitor is also supported by the SEM image of the mild steel sample, which shows that the surface of the sample is well protected. The results of this work demonstrate that nitrogen compounds obtained have promising potential as corrosion inhibitors, particularly to prevent corrosion by CO2 gas.
References
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Pandiangan, K. D., W. Simanjuntak, N. Jamarun, and S. Arief (2021). The Use of MgO/SiO2 as Catalyst for Transesterification of Rubber Seed Oil with Different Alcohols. In Journal of Physics: Conference Series, volume 1751. IOP Publishing, page 012100
Sari, F., B. Susanto, and S. Bismo (2018). The Potential Utilization of Coconut Oil and Palm Oil As Raw Material of Alkanolamide under Alkaline Conditions. Conference Series: Earth and Environmental Science, 105(1); 012035
Shahin, M., S. Bilgic, and H. Yilmaz (2002). The Inhibition Effects of Some Cyclic Nitrogen Compounds on the Corrosion of the Steel in NaCl Mediums. Applied Surface Science 195(1); 1
Surya, I., H. Ismail, and A. Azura (2013). Alkanolamide As an Accelerator, Filler-dispersant and a Plasticizer in Silicafilled Natural Rubber Compounds. Polymer Testing, 32(8); 1313–1321
Syamsuddin, Y., M. Murat, and B. Hameed (2016). Synthesis of Fatty Acid Methyl Ester from the Transesterification of High-and Low-acid-content Crude Palm Oil (elaeis Guineensis) and Karanj Oil (pongamia Pinnata) Over a Calcium–lanthanum–aluminum Mixed-oxides Catalyst. Bioresource Technology, 214; 248–252
Wongwanichkangwarn, I., S. Limtrakul, T. Vatanatham, and P. A. Ramachandran (2021). Amidation Reaction System: Kinetic Studies and Improvement by Product Removal. ACS omega, 6(45); 30451–30464
Zaafarany, I. and M. Abdallah (2010). Ethoxylated Fatty Amide As Corrosion Inhibitors for Carbon Steel in Hydrochloric Acid Solution. International Journal of Electrochemical Science, 5(1); 18–28
Al-Amiery, A. A., W. N. R. W. Isahak, and W. K. Al-Azzawi (2023). Corrosion Inhibitors: Natural and Synthetic Organic Inhibitors. Lubricants, 11(4); 174
Anggraini, I. F., M. Said, and M. Faizal (2019). Production Methy Ester Sulfonate (MES) Based Rubber Seeds As One Of Chemical Injection Solutions In Enhanched Oil Recovery (EOR) Process. Science and Technology Indonesia, 4(2); 52–56
Avdeev, Y. G., K. Anfilov, and Y. I. Kuznetsov (2021). Effect of Nitrogen-containing Inhibitors on the Corrosion Inhibition of Low-carbon Steel in Solutions of Mineral Acids with Various Anionic Compositions. International Journal of Corrosion and Scale Inhibition, 10(4); 1566–1586
Chandran, K., R. Nithya, K. Sankaran, A. Gopalan, and V. Ganesan (2006). Synthesis and Characterization of Sodium Alkoxides. Bulletin of Materials Science, 29; 173–179
Hossain, M. A., S. M. Chowdhury, Y. Rekhu, K. S. Faraz, and M. U. Islam (2012). Biodiesel from Coconut Oil: A Renewable Alternative Fuel for Diesel Engine. International Journal of Chemical and Molecular Engineering, 6(8); 524–528
Ilim, I., A. I. N. Afifah, L. Hidayah, H. Herliana, K. D. Pandiangan, and W. Simanjuntak (2022a). Study on Corrosion Inhibition Activity of Nitrogen Compounds Derived from Coconut Oil Methyl Ester. International Journal of Corrosion and Scale Inhibition, 11(4); 1639–1651
Ilim, I., S. Bahri, R. Marjunus, and W. Simanjuntak (2021b). The Effect of Initiator Concentrations on Corrosion Inhibition Activity of Polymeric Derivatives of 2-vinylpyridin. In Journal of Physics: Conference Series, volume 1751. IOP Publishing, page 012094
Ilim, I., S. Bahri, W. Simanjuntak, Y. M. Syah, B. Bundjali, and B. Buchari (2017c). Performance of Oligomer 4-vinylpiperidine As a Carbon Dioxide Corrosion Inhibitor of Mild Steel. Journal of Materials and Environmental Sciences, 8(07); 2381–2390
Ilim, I., R. Fitriani, T. Prabowo, S. Bahri, R. Marjunus, and W. Simanjuntak (2021d). Molecular Weight Distribution and Corrosion Inhibitor Activity of 4-vinylpyridine Oligomer Synthesized Using Low Concentration Hydrogen Peroxide As the Initiator. International Journal of Corrosion and Scale Inhibition, 10(1); 284–301
Ilim, I., A. Jefferson, W. Simanjuntak, M. Jeannin, M. S. Yana, B. Bundjali, and B. Buchari (2016e). Synthesis and Characterization of Oligomer 4-vinylpyridine As a Corrosion Inhibitor for Mild Steel in CO−2 Saturated Brine Solution. Indonesian Journal of Chemistry, 16(2); 198–207
Jevremović, I., M. Singer, S. Nešić, and V. Mišković-Stanković (2016). Electrochemistry of Carbon Dioxide Corrosion Mitigation Using Tall Oil Diethylenetriamine Imidazoline As Corrosion Inhibitor for Mild Steel. Materials and Corrosion, 67(7); 756–768
Keleş, H., D. M. Emir, and M. Keleş (2015). A Comparative Study of the Corrosion Inhibition of Low Carbon Steel in Hcl Solution by an Imine Compound and Its Cobalt Complex. Corrosion Science, 101; 19–31
Lu, Y., Z. Zhang, Y. Xu, Q. Liu, and G. Qian (2015). Cafeal Mixed Oxide Derived Heterogeneous Catalysts for Transesterification of Soybean Oil to Biodiesel. Bioresource technology, 190; 438-441
Mahmmod, A., M. Ismael, A. Fadhil, and N. Kurshed (2019). Corrosion Control of Cu-Ni Alloy in Hydrochloric Acid by Amines Compounds. International Journal of Corrosion and Scale Inhibition, 8(2); 356–365
Masyithah, Z., S. Yudhika, L. Simanjuntak, and A. Ginting (2019). Optimization of Alkyl diethanolamide Synthesis from Fatty Acid Methyl Ester of Coconut Oil Using Box behnken Design. Rasayan Journal of Chemistry. 12(2), 733–740.
Minaria, M. and R. Mohadi (2016). Preparation and Characterization of Calcium Oxide from Crab Shells (portunus Pelagicus) and Its Application in Biodiesel Synthesis of Waste Cooking Oil, Palm and Coconut Oil. Science and Technology Indonesia, 1(1); 1–7
Pandiangan, K. D., W. Simanjuntak, N. Jamarun, and S. Arief (2021). The Use of MgO/SiO2 as Catalyst for Transesterification of Rubber Seed Oil with Different Alcohols. In Journal of Physics: Conference Series, volume 1751. IOP Publishing, page 012100
Sari, F., B. Susanto, and S. Bismo (2018). The Potential Utilization of Coconut Oil and Palm Oil As Raw Material of Alkanolamide under Alkaline Conditions. Conference Series: Earth and Environmental Science, 105(1); 012035
Shahin, M., S. Bilgic, and H. Yilmaz (2002). The Inhibition Effects of Some Cyclic Nitrogen Compounds on the Corrosion of the Steel in NaCl Mediums. Applied Surface Science 195(1); 1
Surya, I., H. Ismail, and A. Azura (2013). Alkanolamide As an Accelerator, Filler-dispersant and a Plasticizer in Silicafilled Natural Rubber Compounds. Polymer Testing, 32(8); 1313–1321
Syamsuddin, Y., M. Murat, and B. Hameed (2016). Synthesis of Fatty Acid Methyl Ester from the Transesterification of High-and Low-acid-content Crude Palm Oil (elaeis Guineensis) and Karanj Oil (pongamia Pinnata) Over a Calcium–lanthanum–aluminum Mixed-oxides Catalyst. Bioresource Technology, 214; 248–252
Wongwanichkangwarn, I., S. Limtrakul, T. Vatanatham, and P. A. Ramachandran (2021). Amidation Reaction System: Kinetic Studies and Improvement by Product Removal. ACS omega, 6(45); 30451–30464
Zaafarany, I. and M. Abdallah (2010). Ethoxylated Fatty Amide As Corrosion Inhibitors for Carbon Steel in Hydrochloric Acid Solution. International Journal of Electrochemical Science, 5(1); 18–28
Authors
Ilim, Hidayah, L., Yuliyanda, D., Delilawati Pandiangan, K., & Simanjuntak, W. (2024). Sodium Methoxide Catalyzed Preparation of Nitrogen Compounds from Palm Oil Methyl Esters as Corrosion Inhibitor. Science and Technology Indonesia, 9(1), 113–119. https://doi.org/10.26554/sti.2024.9.1.113-119
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