The Synthesis of CuO/Polystyrene Nanocomposite Superhydrophobic Layer using The Spin Coating Method
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Keywords:
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Copper Oxide, Calcination Temperature, Contact Angle, an Energy Gap
Abstract
This paper shows the synthesis of CuO/Polystyrene(PS) nanocomposite superhydrophobic layer using the spin coating method. The objective of this study was to determine the effect of calcination temperature on the contact angle, morphology, and energy gap of the CuO/PS nanocomposite thin layer. Preparation of copper powder into copper oxide (CuO) nanoparticles using the method of High Energy 3 Dimensional Milling (HEM-3D) for 20 hours. The calcination temperature variations used were 100◦C , 150◦C, 180◦C, 200◦C, and 300◦C. In this study, sample analysis was performed using X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), and Ultraviolet-Visible (UV-Vis) Spectrophotometry. The contact angle was determined using the sessile drop method. The findings indicate that the calcination temperature affects the contact angle of the nanocomposite thin films the highest contact angle was obtained at 162◦ at a temperature of 200◦C. The results of SEM analysis obtained that at a temperature of 200◦C, the particle size was 62.91 nm and the particles were evenly distributed in the composite layer. The energy gap at 200◦C is 2.03 eV. We found that CuO/PS synthesized at a temperature of 200◦C was superhydrophobic.
References
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Zhang, Y. P., P. P. Li, P. F. Liu, W. Q. Zhang, J. C. Wang, C. X. Cui, X. J. Li, and L. B. Qu (2019b). Fast and Sim- ple Fabrication of Superhydrophobic Coating by Polymer Induced Phase Separation. Nanomaterials, 9(3); 411
Celia, E., T. Darmanin, E. T. de Givenchy, S. Amigoni, and F. Guittard (2013). Recent Advances in Designing Superhy- drophobic Surfaces. Journal of Colloid and Interface Science, 402; 1–18
Guan, Y., C. Yu, J. Zhu, R. Yang, X. Li, D. Wei, and X. Xu (2018). Design and Fabrication of Vapor-Induced Super- hydrophobic Surfaces Obtained from Polyethylene Wax and Silica Nanoparticles in Hierarchical Structures. RSC Advances, 8(44); 25150–25158
Huang, J., S. Wang, and S. Lyu (2017). Facile Preparation of a Robust and Durable Superhydrophobic Coating using Biodegradable Lignin-Coated Cellulose Nanocrystal Parti- cles. Materials, 10(9); 1080
Johan, M. R., M. S. M. Suan, N. L. Hawari, and H. A. Ching (2011). Annealing Effects on The Properties of Copper Oxide Thin Films Prepared by Chemical Deposition. Inter- national Journal Electrochemical Science, 6(12); 6094–6104
Latthe, S. S., P. Sudhagar, C. Ravidhas, A. J. Christy, D. D. Kirubakaran, R. Venkatesh, A. Devadoss, C. Terashima, K. Nakata, and A. Fujishima (2015). Self-Cleaning and Superhydrophobic CuO Coating by Jet-Nebulizer Spray Pyrolysis Technique. CrystEngComm, 17(13); 2624–2628
Li, B. and Y. Wang (2010). Facile Synthesis and Photocatalytic Activity of ZnO–CuO Nanocomposite. Superlattices and Microstructures, 47(5); 615–623
Liu, E., H. J. Lee, and X. Lu (2020). Superhydrophobic Sur- faces Enabled by Femtosecond Fiber Laser-Written Nanos- tructures. Applied Sciences, 10(8); 2678
Liu, H., S. W. Gao, J. S. Cai, C. L. He, J. J. Mao, T. X. Zhu, Z. Chen, J. Y. Huang, K. Meng, and K. Q. Zhang (2016). Recent Progress in Fabrication and Applications of Superhy- drophobic Coating on Cellulose-Based Substrates. Materials, 9(3); 124
Pawar, S. (2011). Nanocrystalline CuO Thin Films for H2S Monitoring: Microstructural and Optoelectronic Characteri- zation. Journal of Sensor Technology, 1; 36–46
Radwan, A. B., A. M. Abdullah, A. Mohamed, and M. A. Al-Maadeed (2018). New Electrospun Polystyrene/Al2O3 Nanocomposite Superhydrophobic Coatings; Synthesis, Characterization, and Application. Coatings, 8(2); 65
Ratnawulan, A. Fauzi, and S. H. AE (2017). Effect of Calcina- tion Temperature on Phase Transformation and Crystallite Size of Copper Oxide (CuO) Powders. AIP Conference Pro- ceedings, 1868; 060009
Ratnawulan, R., R. Ramli, A. Fauzi, and S. Hayati AE (2021). Synthesis and Characterization of Polystyrene/CuO-Fe2O3 Nanocomposites from Natural Materials as Hydrophobic Photocatalytic Coatings. Crystals, 11(1); 31
Sabbah, A., A. Youssef, and P. Damman (2016). Superhy- drophobic Surfaces Created by Elastic Instability of PDMS. Applied Sciences, 6(5); 152
Sarimai, Ratnawulan, Yulkifli, and A. Fauzi (2019). Fabrica- tion of Superhydrophobic CuO/Polystyrene Nanocompos- ite Coating with Variation Concentration. Journal of Physics: Conference Series, 1185(1); 012014
Simpson, J. T., S. R. Hunter, and T. Aytug (2015). Superhydrophobic Materials and Coatings: a Review. Reports on
Progress in Physics, 78(8); 086501
Sun, Y., X. Zhao, R. Liu, G. Chen, and X. Zhou (2018). Synthesis and Characterization of Fluorinated Polyacrylate as Water and Oil Repellent and Soil Release Finishing Agent for Polyester Fabric. Progress in Organic Coatings, 123; 306– 313
Vidal, K., E. Gómez, A. M. Goitandia, A. Angulo-Ibáñez, and E. Aranzabe (2019). The Synthesis of a Superhydropho- bic and Thermal Stable Silica Coating Via Sol-Gel Process. Coatings, 9(10); 627
Wang, G., J. Yang, and Q. Shi (2011). Preparation of Trans- parent Ultrahydrophobic Silica Film by Sol–Gel Process. Journal of Coatings Technology and Research, 8(1); 53–60
Wienke, D., Y. Xie, and P. K. Hopke (1995). Classification of Airborne Particles by Analytical Scanning Electron Mi- croscopy Imaging and a Modified Kohonen Neural Network
(3MAP). Analytica Chimica Acta, 310(1); 1–14
Xu, X., Z. Zhang, F. Guo, J. Yang, X. Zhu, X. Zhou, and
Q. Xue (2012). Fabrication of Bionic Superhydropho- bic Manganese Oxide/Polystyrene Nanocomposite Coating. Journal of Bionic Engineering, 9(1); 11–17
Yao, C. W., D. Sebastian, I. Lian, Ö. Günaydın-Şen, R. Clarke, K. Clayton, C. Y. Chen, K. Kharel, Y. Chen, and Q. Li (2018). Corrosion Resistance and Durability of Superhy- drophobic Copper Surface in Corrosive NaCl Aqueous So- lution. Coatings, 8(2); 70
Ye, Y., F. Zeng, M. Zhang, S. Zheng, J. Li, and P. Fei (2020). Hydrophobic Edible Composite Packaging Mem- brane Based on Low-Methoxyl Pectin/Chitosan: Effects of Lotus Leaf Cutin. Food Packaging and Shelf Life, 26; 100592
Zhang, B., W. Xu, Q. Zhu, S. Yuan, and Y. Li (2019a). Lotus- Inspired Multiscale Superhydrophobic AA5083 Resisting Surface Contamination and Marine Corrosion Attack. Ma- terials, 12(10); 1592
Zhang, Y. P., P. P. Li, P. F. Liu, W. Q. Zhang, J. C. Wang, C. X. Cui, X. J. Li, and L. B. Qu (2019b). Fast and Sim- ple Fabrication of Superhydrophobic Coating by Polymer Induced Phase Separation. Nanomaterials, 9(3); 411
Authors
Ratnawulan, R., Fauzi, A. ., & Sarimai, S. (2022). The Synthesis of CuO/Polystyrene Nanocomposite Superhydrophobic Layer using The Spin Coating Method. Science and Technology Indonesia, 7(2), 158–163. https://doi.org/10.26554/sti.2022.7.2.158-163
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