Optimization of Sumatera Bentonite by Ammonium-impregnated as a Coagulant for Cassava Wastewater Treatment
Abstract
The original Sumatera Bentonite (SB), which has been impregnated to be ammonium bentonite (NH-B), was applied as a cassava wastewater coagulant. The modification was conducted using multi-step impregnation initiated by bentonite activation (sodium cation exchange), followed by ammonium impregnation. The optimization parameter focused on the coagulant dose that was used. The result of cassava wastewater coagulation by the ammonium-impregnated bentonite (with dose: 0.4 g/100 mL) shows high-efficiency reduction for turbidity up to 73.97% (from 1099 to 186 NTU), Total Suspended Solid up to 86.56% (from 588 to 79 mg/L), and Chemical Oxygen Demand up to 88.6% (from 559.7 to 63.3 mg/L). The existence of ammonium impregnated is characterized by X-Ray Diffraction analysis based on 2theta shifting at 10° and Fourier Transform Infra-Red analysis at 464, 521, and 1429 cm−1 as ammonium binding.
References
Adebowale, A., L. O. Sanni, and M. Onitilo (2008). Chemical Composition and Pasting Properties of Tapioca Grits from Different Cassava Varieties and Roasting Methods. African Journal of Food Science, 2; 77–82
Aguilar, M., J. Saez, M. Llorens, A. Soler, and J. Ortuno (2003). Microscopic Observation of Particle Reduction in Slaughter house Wastewater by Coagulation–Flocculation using Ferric Sulphate as Coagulant and Different Coagulant Aids. Water Research, 37(9); 2233–2241
Ahari, M., H. Ddahim, and R. Ramadane (2019). Performance of Bentonite Clay as a Coagulation Aid on Water Quality. Desalination and Water Treatment, 143; 229–234
Ahmad, A., S. Ismail, and S. Bhatia (2005). Optimization of Coagulation- Flocculation Process for Palm Oil Mill Effluent using Response Surface Methodology. Environmental Science & Technology, 39(8); 2828–2834
Ang, W. L. and A. W. Mohammad (2020). State of the Art and Sustainability of Natural Coagulants in Water and Wastewater Treatment. Journal of Cleaner Production, 262; 121267
Aryee, F., I. Oduro, W. Ellis, and J. Afuakwa (2006). The Physicochemical Properties of Flour Samples from the Roots of 31 Varieties of Cassava. Food Control, 17(11); 916–922
Brandt, M. J., K. M. Johnson, A. J. Elphinston, and D. D. Ratnayaka (2017). Storage, Clarification and Chemical Treatment. Twort’s Water Supply, 7; 323–366
Candrawati, I., F. Martak, and Y. I. Cahyo (2017). Absorption Activity of Cassava Peel (Manihot utilissima) as Chromium (VI) Metal Biosorbent in Electroplating Waste. The Journal of Pure and Applied Chemistry Research, 6(2); 117
Cheddie, D. (2012). Ammonia as a Hydrogen Source for Fuel Cells: a Review. InTech
Cooke, R., J. Rickard, and A. Thompson (1988). The Storage of Tropical Root and Tuber Cropscassava, Yam and Edible Aroids. Experimental Agriculture, 24(4); 457–470
Czemierska, M., A. Szczes, and A. Jarosz-Wilkolazka (2015). Purification of Wastewater by Natural Flocculants. BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology, 96(4); 272–278
Dayarathne, H., M. J. Angove, S. Jeong, R. Aryal, S. R. Paudel, and B. Mainali (2022). Effect of Temperature on Turbidity Removal by Coagulation: Sludge Recirculation for Rapid Settling. Journal of Water Process Engineering, 46; 102559
de Faria Ferreira Carraro, C., C. C. A. Loures, and J. A. de Castro (2021). Microalgae Technique for Bioremediation Treatment of Cassava Wastewater. Water, Air, & Soil Pollution, 232(7); 281
de Souza, J. M. (2021). Cassava Wastewater: An Introduction, Characterization and Potential. Use of Cassava Wastewater and Scheelite Residues in Ceramic Formulations; 1–10
dos Santos, J. D., M. T. Veit, P. T. Juchen, G. da Cunha Gonçalves, S. M. Palacio, and M. Fagundes Klen (2018). Use of Different Coagulants for Cassava Processing Wastewater Treatment. Journal of Environmental Chemical Engineering, 6(2); 1821–1827
Eke-emezie, N., B. R. Etuk, O. P. Akpan, and O. C. Chinweoke (2022). Cyanide Removal from Cassava Wastewater onto H3PO4 Activated Periwinkle Shell Carbon. Applied Water Science, 12(7); 157
Elkhalifah, A. E., S. Maitra, M. A. Bustam, and T. Murugean (2013). Effects of Exchanged Ammonium Cations on Structure Characteristics and CO2 Adsorption capacities of bentonite clay. Applied Clay Science, 83; 391–398
Fleck, L., M. H. Tavares, E. Eyng, M. A. d. M. Andrade, and L. M. Frare (2017). Optimization of Anaerobic Treatment of Cassava Processing Wastewater. Engenharia Agrícola, 37(3); 574–590
Franck, H., M. Christian, A. Noël, P. Brigitte, H. D. Joseph, D. Cornet, and N. C. Mathurin (2011). Effects of Cultivar and Harvesting Conditions (age, season) on the Texture and Taste of Boiled Cassava Roots. Food Chemistry, 126(1); 127–133
Gandhi, D., R. Bandyopadhyay, and B. Soni (2022). Naturally Occurring Bentonite Clay: Structural Augmentation, Characterization and Application as Catalyst. Materials Today: Proceedings, 57; 194–201
Gönülşen, R., N. Yıldız, and A. Çalımlı (2003). Adsorption of Organic Compounds on to Bentonites Modified with Single or Dual Quaternary Ammonium Cations. Adsorption Science & Technology, 21(2); 135–148
Hasanudin, U., M. E. Kustyawati, D. A. Iryani, A. Haryanto, and S. Triyono (2019). Estimation of Energy and Organic Fertilizer Generation from Small Scale Tapioca Industrial Waste. In IOP Conference Series: Earth and Environmental Science, volume 230. IOP Publishing, page 012084
Hidayat, M. T. and I. Nugraha (2018). Kajian Kinerja Ca-Bentonit Kabupaten Pacitan-Jawa Timur Teraktivasi Asam Sulfat sebagai Material Lepas Lambat (Slow Release Material) Pupuk Organik Urin Sapi. Indonesian Journal of Materials Chemistry, 1(1); 27–37
Ibiene, A. A., N. C. Ekwuribe, A. U. Osadebe, and P. O. Okerentugba (2021). Biotreatment of Effluent from Cassava Processing Using Powdered Seeds of Moringa oleifera. Bioengineering and Bioscience, 8(2); 13–23
Kaewkannetra, P., W. Chiwes, and T. Chiu (2011). Treatment of Cassava Mill Wastewater and Production of Electricity Through Microbial Fuel Cell Technology. Fuel, 90(8); 2746–2750
Kuczman, O., M. H. F. Tavares, S. D. Gomes, L. P. C. Guedes, and G. Grisotti (2017). Effects of Stirring on Cassava Effluent Treatment in An Anaerobic Horizontal Tubular Pilot Reactor with Support Medium–A Review. Renewable and Sustainable Energy Reviews, 77; 984–989
Laipan, M., L. Xiang, J. Yu, B. R. Martin, R. Zhu, J. Zhu, H. He, A. Clearfield, and L. Sun (2020). Layered Intercalation Compounds: Mechanisms, New Methodologies, and Advanced Applications. Progress in Materials Science, 109; 100631
Langeroudi, M. P. and E. Binaeian (2018). Tannin-APTES modified Fe3O4 Nanoparticles as a Carrier of Methotrexate Drug: Kinetic, Isotherm and Thermodynamic Studies. Materials Chemistry and Physics, 218; 210–217
Léotard, G., A. Duputié, F. Kjellberg, E. J. Douzery, C. Debain, J.-J. De Granville, and D. McKey (2009). Phylogeography and the Origin ofCcassava: New Insights from the Northern Rim of the Amazonian Basin. Molecular Phylogenetics and Evolution, 53(1); 329–334
Li, D., P. Li, Y. Xu, W. Guo, M. Li, M. Chen, H. Wang, and H. Lin (2022). Progress in Montmorillonite Functionalized Artificial Bone Scaffolds: Intercalation and Interlocking, Nanoenhancement, and Controlled Drug Release. Journal of Nanomaterials, 2022; 1–20
Lian, C., G. Wang, W. Lv, Z. Sun, and S. Zheng (2019). Effect of Calcination Temperature on The Structure of Chitosan Modified Montmorillonites and their Adsorption of Aflatoxin B 1. Clays and Clay Minerals, 67(4); 357–366
Lindgreen, H. (1994). Ammonium Fixation during Illite Smectite Diagenesis in Upper Jurassic Shale, North Sea. Clay Minerals, 29(4); 527–537
Lubis, S. (2007). Preparasi Bentonit Terpilar Alumina dari Bentonit Alam dan Pemanfaatannya sebagai Katalis pada Reaksi Dehidrasi Etanol, 1-Propanol Serta 2-Propanol. Jurnal Rekayasa Kimia & Lingkungan, 6(2); 77–81
Marey, A. (2019). Composite of Chitosan and Bentonite as Coagulant Agents in Removing Turbidity from Ismailia Canal as Water Treatment Plant. Bionatura, 4(3); 897–900
Mcyotto, F. O., Q. Wei, C. W. Chow, Z. Nadeem, Z. Li, and J. Liu (2020). Eco-Friendly Decolorization of Cationic Dyes by Coagulation using Natural Coagulant Bentonite and Biodegradable Flocculant Sodium Alginate. Journal of Earth Sciences & Environmental Studies, 5(2); 51–60
Naceradska, J., L. Pivokonska, and M. Pivokonsky (2019). On the Importance of pH Value in Coagulation. Journal of Water Supply: Research and Technology-Aqua, 68(3); 222–230
Nnaji, C. C. and C. C. Akanno (2022). Assessment of Environmental Degradation due to Processing of Cassava into Garri Flakes using Pollution Indices. Environmental Processes, 9(3); 46
Nuraini, Y. and M. Felani (2015). Phytoremediation of Tapioca Wastewater using Water Hyacinth Plant (Eichhornia crassipes). Journal of Degraded and Mining Lands Management, 2(2); 295
Nwokocha, L. M., N. A. Aviara, C. Senan, and P. A. Williams (2009). A Comparative Study of Some Properties of Cassava (Manihot esculenta, Crantz) and Cocoyam (Colocasia esculenta, Linn) Starches. Carbohydrate Polymers, 76(3); 362–367
Ocieczek, A., D. Mesinger, and H. Toczek (2022). Hygroscopic Properties of Three Cassava (Manihot esculenta Crantz) Starch Products: Application of BET and GAB Models. Foods, 11(13); 1966
Omer, N. H. (2019). Water Quality Parameters. Water Quality-science, Assessments and Policy, 18; 1–34
Paulo, P. L., T. A. Colman-Novaes, L. D. S. Obregão, and M. Á. Boncz (2013). Anaerobic Digestion of Cassava Wastewater Pre-Treated by Fungi. Applied Biochemistry and Biotechnology, 169(8); 2457–2466
Pérez-Maqueda, L., V. Balek, J. Poyato, J. Perez-Rodriquez, J. Šubrt, I. Bountsewa, I. Beckman, and Z. Málek (2003). Study of Natural and Ion Exchanged Vermiculite by Emanation Thermal Analysis, TG, DTA And XRD. Journal of Thermal Analysis and Calorimetry, 71(3); 715–726
Photharin, Y., S. Wangngae, U. Ngivprom, K. Chansaenpak, A. Kamkaew, and R.-Y. Lai (2022). Extract of Cassava Waste as a Lixiviant for Gold Leaching from Electronic Waste. Green Chemistry Letters and Reviews, 15(2); 437–448
Precious Sibiya, N., S. Rathilal, and E. Kweinor Tetteh (2021). Coagulation Treatment of Wastewater: Kinetics and Natural Coagulant Evaluation. Molecules, 26(3); 698
Ramli, S. F. and H. A. Aziz (2020). The Effects of Mixing Speed and Reaction Time on the Removal of Colour and Turbidity from Alor Pongsu Landfill Using Tin Tetrachloride. In Proceedings of AICCE’19: Transforming the Nation for a Sustainable Tomorrow 4. Springer, pages 1077–1089
Ratnadewi, A. A. I., A. B. Santoso, E. Sulistyaningsih, and W. Handayani (2016). Application of Cassava Peel and Waste as Raw Materials for Xylooligosaccharide Production using Endoxylanase from Bacillus Subtilis of Soil Termite Abdomen. Procedia Chemistry, 18; 31–38
Rosińska, A. and L. Dąbrowska (2021). Influence of Type and Dose of Coagulants on Effectiveness of Pah Removal in Coagulation Water Treatment. Water Science and Engineering, 14(3); 193–200
Sánchez, A. S., Y. L. Silva, R. A. Kalid, E. Cohim, and E. A. Torres (2017). Waste Bio-Refineries for The Cassava Starch Industry: New Trends and Review of Alternatives. Renewable and Sustainable Energy Reviews, 73; 1265–1275
Sarkar, M. and K. Dana (2022). Intercalation of Montmorillonite with Dialkylammonium Cationic Surfactants. Journal of Molecular Structure, 1256; 132468
Sirait, M., N. Bukit, and N. Siregar (2017). Preparation and Characterization of Natural Bentonite in to Nanoparticles by Co-Precipitation Method. In AIP Conference Proceedings, volume 1801. AIP Publishing LLC, page 020006
Sudibyo, S., L. Hermida, and S. Suwardi (2017). Application of Taguchi Optimization on the Cassava Starch Wastewater Electrocoagulation using Batch Recycle Method. In AIP Conference Proceedings, volume 1904. AIP Publishing
Trevisan, A. P., E. B. Lied, F. L. Fronza, K. U. Devens, and S. D. Gomes (2019). Cassava Wastewater Treatment by Coagulation/Flocculation using Moringa oleifera Seeds. CET Journal-Chemical Engineering Transactions, 74; 367–372
Yaghmaeiyan, N., M. Mirzaei, and R. Delghavi (2022). Montmorillonite Clay: Introduction and Evaluation of its Applications in Different Organic Syntheses as Catalyst: a Review. Results in Chemistry; 100549
Zanetti, E. G. B., E. M. G. Cardoso, D. P. Dourado, E. Reina, and C. T. Muraishi (2014). Performance of Two Cassava Varieties Submitted to Different Spacings, Grown in the Cerrado Region. Applied Research & Agrotechnology, 7(1); 39–46
Zhang, M., L. Xie, Z. Yin, S. K. Khanal, and Q. Zhou (2016). Biorefinery Approach for Cassava Based Industrial Wastes: Current Status and Opportunities. Bioresource Technology, 215; 50–62
Zhang, Y., A. He, R. Tian, S. Yang, and H. Li (2022). Co-Aggregation of Mixture Components of Montmorillonite, Kaolinite and Humus. European Journal of Soil Science, 73(1); e13158
Zhang, Y., M. Li, G. Zhang, W. Liu, J. Xu, Y. Tian, Y. Wang, X. Xie, Z. Peng, A. Li, et al. (2023). Efficient Treatment of the Starch Wastewater by Enhanced Flocculation–Coagulation of Environmentally Benign Materials. Separation and Purification Technology, 307; 122788
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