Selective Removal of Anionic and Cationic Dyes Using Magnetic Composites
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Keywords:
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Composite, Magnetic, Biochar, Anionic Dyes, Cationic Dyes
Abstract
Water is one of the most basic human needs, and dyes are one of the sources of water pollution. Since adsorption has proven to be effective in removing contaminants, it is the most widely used technique. In this adsorption, a LDH Zn-Al /magnetic biochar composite was used for dye removal. Zn-Al LDH, magnetic biochar, and LDH Zn-Al/biochar magnetic composite were successfully synthesized, based on XRD and FTIR studies. XRD analysis of the Zn-Al LDH material shows diffractions of (003), (006), (101), (012), (015), (107), and (110) around the 2theta angle at 10.29°, 20.07°, 29.59°, 32.12°, 34.02°, 48.06°, and 60.16° which are characteristic of LDH materials. In magnetic biochar and LDH Zn-Al/magnet biochar composites diffraction (220), (311), (422) and (440) at 2theta around 24.9°, 35°, 63° and 68.4° in these materials indicate the characteristics of carbon-based materials from biochar. FTIR analysis showed the appearance of a vibration peak at 1404cm−1 indicating the presence of C H groups contained in biochar. The characteristic double-layer hydroxy (M-O) vibrations below 1000 cm−1 also indicated that the composite preparation process had been successful. The study’s results show that cationic dyes are more easily adsorbed than anionic dyes. Specifically, the LDH Zn-Al/Magnetic Biochar composite more extensively absorbs the cationic dye malachite green.
References
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Siregar, P. M. S. B. N., A. Lesbani, and R. Mohadi (2022). Mg/Al-chitosan as a Selective Adsorbent in The Removal of Methylene Blue from Aqueous Solutions. Science and Technology Indonesia, 7(2); 170–178
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Su, X., F. Qian, and Y. Bao (2024). The Effect of Bulk-biochar and Nano-biochar Amendment on the Removal of Antibiotic Resistance Genes in Microplastic Contaminated Soil. Environmental Research, 240; 117488
Sudirgo, M. M., R. A. Surya, H. Kristianto, S. Prasetyo, and A. K. Sugih (2023). Application of Xanthan Gum As Coagulant-aid for Decolorization of Synthetic Congo Red Wastewater. Heliyon, 9(4); 95–110
Vinsiah, R., R. Mohadi, and A. Lesbani (2020). Performance of Graphite for Congo Red and Direct Orange Adsorption. Indonesian Journal of Environmental Management and Sustainability, 4(4); 125–132
Wang, B., X. Yang, L. Ma, L. Zhai, J. Xuan, C. Liu, and Z. Bai (2020). Ultra-high Efficient pH Induced Selective Removal of Cationic and Anionic Dyes from Complex Coexisted Solution by Novel Amphoteric Biocomposite Microspheres. Separation and Purification Technology, 231; 115922
Wang, P., X. Zhang, B. Zhou, F. Meng, Y. Wang, and G. Wen (2023a). Recent Advance of Layered Double Hydroxides Materials: Structure, Properties, Synthesis, Modification and Applications of Wastewater Treatment. Journal of Environmental Chemical Engineering; 111191
Wang, R., Y. Liu, Y. Lu, S. Liang, Y. Zhang, J. Zhang, R. Shi, and W. Yin (2023b). Fabrication of a Corn Stalk Derived Cellulose-based Bio-adsorbent to Remove Congo Red from Wastewater: Investigation on Its Ultra-high Adsorption Performance and Mechanism. International Journal of Biological Macromolecules, 241; 124545
Wibiyan, S., A. Wijaya, and P. M. S. B. N. Siregar (2023). Adsorption of Phenol using Cellulose and Hydrochar: Kinetic, Isotherm, and Regeneration Studies. Indonesian Journal of Material Research, 1(2); 61–67
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Yu, J., X. Wang, T. Liu, X. Bai, Z. He, Y. He, J. Tao, Q. Wang, and Q. Wu (2023). Synthesis of Magnetic Hyper-crosslinked Polymer from Waste-expanded Polystyrene As Efficient Sorbent for Removal of Congo Red and Crystal Violet. Sustainable Materials and Technologies, 38; e00760
Aghaei, F., S. Tangestaninejad, M. Bahadori, M. Moghadam, V. Mirkhani, I. Mohammadpoor, M. Khalaji, V. Asadi. (2023). Green Synthesize of Nano-MOF-Ethylcellulose Composite Fibers for Efficient Adsorption of Congo Red from Water. Journal of Colloid and Interface Science, 4(5); 60–68
Ahmad, N., F. S. Arsyad, I. Royani, and A. Lesbani (2022). Adsorption of Methylene Blue on Magnetite Humic Acid: Kinetic, Isotherm, Thermodynamic, and Regeneration Studies. Results in Chemistry, 4; 100629
Ahmad, N., R. Rohmatullaili, Y. Hanifah, S. Wibiyan, A. Amri, A. Wijaya, M. Mardiyanto, R. Mohadi, I. Royani, and A. Lesbani (2023). Recycle Performance of Heterogeneous Catalyst Metal Oxides Based Layered Double Hydroxide for Oxidative Desulfurization Process of 4-methyldibenzothiophene. Bulletin of Chemical Reaction Engineering & Catalysis, 18(4); 548–558
Akdemir, M., B. Isik, F. Cakar, and O. Cankurtaran (2022). Comparison of the Adsorption Efficiency of Cationic (crystal Violet) and Anionic (congo Red) Dyes on Valeriana Officinalis Roots: Isotherms, Kinetics, Thermodynamic Studies, and Error Functions. Materials Chemistry and Physics, 291; 126763
Amri, A., R. Rezonsi, N. Ahmad, T. Taher, N. R. Palapa, R. Mohadi, and A. Lesbani (2023). Biochar Modified Layered Double Hydroxide for Highly Efficient on Phenol Adsorption. Bulletin of Chemical Reaction Engineering & Catalysis, 18(3); 460–472
Fitri, E. S. and R. Ardiansyah (2023). Study and Characterization of Hydrochar from Duku (Lansium domesticum) Peel. Indonesian Journal of Material Research, 1(2); 44–50
Fitri, E. S., T. N. Yunita, R. Mohadi, and A. Lesbani (2023). Ca/Al and Mg/Al LDH Supported on Biochars As Effective Adsorbent and Highly Regeneration Ability for Phenol Removal from Aqueous Solution. Indonesian Journal of Material Research, 1(3); 106–116
He, S., J. Sun, X. Jin, Q. Chen, X. Wu, F. Tian, X. Zhang, P. Li, and H. Sheng (2023). Adsorption Enhancement of Congo Red Dye from Wastewater Based on Edamame Shell Originated Activated Carbon by the Cations: Experimental and Theoretical Studies. Diamond and Related Materials, 136; 109930
Li, Z., H. Hanafy, L. Zhang, L. Sellaoui, M. S. Netto, M. L. Oliveira, M. K. Seliem, G. L. Dotto, A. Bonilla-Petriciolet, and Q. Li (2020). Adsorption of Congo Red and Methylene Blue Dyes on an Ashitaba Waste and a Walnut Shell-based Activated Carbon from Aqueous Solutions: Experiments, Characterization and Physical Interpretations. Chemical Engineering Journal, 388; 124263
Liu, Z., Y. Hu, J. Zhang, Y. Guan, L. Zhang, P. Ye, T. Zhang, X. Huang, M. Wang, and H. Gao (2023). Enhanced Adsorption of Congo Red from Urea/calcium Chloride Co-modified Biochar: Performance, Mechanisms and Toxicity Assessment. Bioresource Technology, 388; 129783
Manalu, R. N., Z. A. Zahara, R. Mohadi. (2023). Ni-Cr Layered Double Hydroxide/Microcrystalline Cellulose Composite as Adsorbents for Malachite Green Dye. Indonesian Journal of Material Research, 1(2); 51–60
Mohadi, R., N. Ahmad, S. Wibiyan, Z. A. Zahara, E. S. F. Royani, I. Mardiyanto, and A. Lesbani (2023). Synthesis of Zn/Al-ZnO Composite Using Zn/Al-Layered Double Hydroxide for Oxidative Desulfurization of 4-Methyldibenzothiophene. Science and Technology Indonesia, 8(4); 701–9
Ni’mah, Y. L., I. Rohmawati, I. Ulfin, H. Harmami, H. Juwono, D. Sugiarso, F. Kurniawan, and S. Suprapto (2020). The Adsorption of Remasol, Indigosol and Naphtol Yellow Mixed Dyes Using Activated Carbon. In AIP Conference Proceedings, volume 2229. AIP Publishing
Palapa, N. R., B. R. Rahayu, T. Taher, A. Lesbani, and R. Mohadi (2019). Kinetic Adsorption of Direct Yellow Onto Zn/Al and Zn/Fe Layered Double Hydroxides. Science and Technology Indonesia, 4(4); 101–104
Rahmadan, J., V. Parhusip, N. R. Palapa, T. Taher, R. Mohadi, and A. Lesbani (2021). Znal-humic Acid Composite As Adsorbent of Cadmium (II) from Aqueous Solution. Science and Technology Indonesia, 6(4); 247–255
Semwal, N., D. Mahar, M. Chatti, A. Dandapat, and M. C. Arya (2023). Adsorptive Removal of Congo Red Dye from its Aqueous Solution by Ag–Cu–CeO2 Nanocomposites: Adsorption Kinetics, Isotherms, and Thermodynamics. Heliyon, 9(11); 110–120
Siregar, P. M. S. B. N., A. Lesbani, and R. Mohadi (2022). Mg/Al-chitosan as a Selective Adsorbent in The Removal of Methylene Blue from Aqueous Solutions. Science and Technology Indonesia, 7(2); 170–178
Siregar, P. M. S. B. N., N. R. Palapa, A. Wijaya, E. S. Fitri, and A. Lesbani (2021). Structural Stability of Ni/Al Layered Double Hydroxide Supported on Graphite and Biochar toward Adsorption of Congo Red. Science and Technology Indonesia, 6(2); 85–95
Stefancu, A., S. D. Iancu, and N. Leopold (2021). Selective Single Molecule Serrs of Cationic and Anionic Dyes by Cl– and Mg2+ Adions: An Old New Idea. The Journal of Physical Chemistry C, 125(23); 12802–12810
Su, X., F. Qian, and Y. Bao (2024). The Effect of Bulk-biochar and Nano-biochar Amendment on the Removal of Antibiotic Resistance Genes in Microplastic Contaminated Soil. Environmental Research, 240; 117488
Sudirgo, M. M., R. A. Surya, H. Kristianto, S. Prasetyo, and A. K. Sugih (2023). Application of Xanthan Gum As Coagulant-aid for Decolorization of Synthetic Congo Red Wastewater. Heliyon, 9(4); 95–110
Vinsiah, R., R. Mohadi, and A. Lesbani (2020). Performance of Graphite for Congo Red and Direct Orange Adsorption. Indonesian Journal of Environmental Management and Sustainability, 4(4); 125–132
Wang, B., X. Yang, L. Ma, L. Zhai, J. Xuan, C. Liu, and Z. Bai (2020). Ultra-high Efficient pH Induced Selective Removal of Cationic and Anionic Dyes from Complex Coexisted Solution by Novel Amphoteric Biocomposite Microspheres. Separation and Purification Technology, 231; 115922
Wang, P., X. Zhang, B. Zhou, F. Meng, Y. Wang, and G. Wen (2023a). Recent Advance of Layered Double Hydroxides Materials: Structure, Properties, Synthesis, Modification and Applications of Wastewater Treatment. Journal of Environmental Chemical Engineering; 111191
Wang, R., Y. Liu, Y. Lu, S. Liang, Y. Zhang, J. Zhang, R. Shi, and W. Yin (2023b). Fabrication of a Corn Stalk Derived Cellulose-based Bio-adsorbent to Remove Congo Red from Wastewater: Investigation on Its Ultra-high Adsorption Performance and Mechanism. International Journal of Biological Macromolecules, 241; 124545
Wibiyan, S., A. Wijaya, and P. M. S. B. N. Siregar (2023). Adsorption of Phenol using Cellulose and Hydrochar: Kinetic, Isotherm, and Regeneration Studies. Indonesian Journal of Material Research, 1(2); 61–67
Xu, Q., Z. Yue, R. Deng, X. Wang, X. Chuai, K. Zhang, and J. Wang (2023). Process and Mechanism of Recovering Layered Double Hydroxides (ldhs) from Acid Mine Drainage (amd) and Synergetic Removal of Manganese. Journal of Environmental Chemical Engineering, 11(5); 110844
Yu, J., X. Wang, T. Liu, X. Bai, Z. He, Y. He, J. Tao, Q. Wang, and Q. Wu (2023). Synthesis of Magnetic Hyper-crosslinked Polymer from Waste-expanded Polystyrene As Efficient Sorbent for Removal of Congo Red and Crystal Violet. Sustainable Materials and Technologies, 38; e00760
Authors
Fitri, E. S., Mohadi, R., Palapa, N. R., Susila Arita Rachman, & Lesbani, A. (2024). Selective Removal of Anionic and Cationic Dyes Using Magnetic Composites. Science and Technology Indonesia, 9(1), 129–136. https://doi.org/10.26554/sti.2024.9.1.129-136
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