Preparation and Application of Nickel Electroplating on Copper (Ni/EC) Electrode for Glucose Detection
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Abstract
An electrode of the nickel electroplating on copper (Ni/EC) has been prepared for a simple and low cost glucose sensor in human urine detection. The electrode was prepared by using pure copper (99.9%) with electroplating method in NiSO4 solution. The electrochemical oxidation of Ni/EC electrode was investigated bys using cyclic voltammetry method. Material Ni/EC identification of morphology used Scanning Electron Magnetic (SEM) and Energy Dispersive X-Ray (EDX). The electrochemical reaction of glucose was analyzed by the cyclic voltammetry method in some electrolyte solutions. Calibration curved was constructed and a linear response for glucose concentration at range 0-0.004 M with R2 = 0.992, LOD and LOQ was determined 4.85x10−4 M, 1.6x10−3 respectively. The proposed electrode might open up a new possibility for the determination of glucose concentration in human urine. Its advantages are simple to prepare, low cost analyzing, and excellent results.
References
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Zhao, C., C. Shao, M. Li, and K. Jiao. (2007). Flow-injection analysis of glucose without enzyme based on electrocatalytic oxidation of glucose at a nickel electrode. Talanta, 71(4); 1769–1773.
Cai, H., B. Sun, H. Chen, X. Li, H. Suo, and C. Zhao. (2017). Enhanced electrochemical glucose-sensing properties of NiO nanospheres modified with indium. Journal of Materials Science 2017 52:19, 52(19); 11547–11553.
Cui, H.-F., J.-S. Ye, W.-D. Zhang, C.-M. Li, J. H. T. Luong, and F.-S. Sheu. (2007). Selective and sensitive electrochemical detection of glucose in neutral solution using platinum–lead alloy nanoparticle/carbon nanotube nanocomposites. Analytica Chimica Acta, 594(2); 175–183.
Das, D., P. K. Sen, and K. Das. (2006). Electrodeposited MnO2 as electrocatalyst for carbohydrate oxidation. Journal of Applied Electrochemistry, 36(6); 685–690.
de Sá, A. C., L. L. Paim, and N. R. Stradiotto. (2014). Sugars electrooxidation at glassy carbon electrode decorate with multi-walled carbon nanotubes with nickel oxy-hydroxide. International Journal of Electrochemical Science, 9(12); 7746–7762.
Guo, H., Z. Huang, Y. Zheng, and S. Weng. (2015). Electrodeposition of nickel nanoparticles modified glassy carbon electrode for nonenzymatic glucose biosensing. International Journal of Electrochemical Science, 10(12); 10703–10712.
Kannan, P. K., and C. S. Rout. (2015). High Performance Non-enzymatic Glucose Sensor Based on One-Step Electrodeposited Nickel Sulfide. Chemistry - A European Journal, 21(26); 9355–9359.
Lim, K. R., J. M. Park, H. N. Choi, and W. Y. Lee. (2013). Gold glyconanoparticle-based colorimetric bioassay for the determination of glucose in human serum. Microchemical Journal, 106 154–159.
Luo, P. F., T. Kuwana, D. K. Paul, and P. M. A. Sherwood. (1996). Electrochemical and XPS Study of the Nickel-Titanium Electrode Surface. Analytical Chemistry, 68(19); 3330–3337.
Marini, S., N. Ben Mansour, M. Hjiri, R. Dhahri, L. El Mir, C. Espro, A. Bonavita, S. Galvagno, G. Neri, and S. G. Leonardi. (2018). Non-enzymatic Glucose Sensor Based on Nickel/Carbon Composite. Electroanalysis, 30(4); 727–733.
Raziq, A., M. Tariq, R. Hussian, M. H. Mehmood, M. S. Khan, and A. Hassan. (2017). Electrochemical Investigation of Glucose Oxidation on a Glassy Carbon Electrode Using Voltammetric, Amperometric, and Digital Simulation Methods. ChemistrySelect, 2(30); 9711–9717.
Riyanto, and M. S. Hakim. (2018). Determination of glucose in human urine by cyclic voltammetry method using gold electrode. IOP Conference Series: Materials Science and Engineering, 299(1); 012001.
Riyanto, and I. Rofida. (2019). Preparation and application of nickel plating on copper electrode (NPCE) for uric acid analysis in human urine using cyclic voltammetry. International Journal of Electrochemical Science, 14(3); 2290–2304.
Wang, Li., X. Lu, Y. Ye, L. Sun, and Y. Song. (2013). Nickel-cobalt nanostructures coated reduced graphene oxide nanocomposite electrode for nonenzymatic glucose biosensing. Electrochimica acta, 114 484-493
Wu, H. X., W. M. Cao, Y. Li, G. Liu, Y. Wen, H. F. Yang, and S. P. Yang. (2010). In situ growth of copper nanoparticles on multiwalled carbon nanotubes and their application as non-enzymatic glucose sensor materials. Electrochimica Acta, 55(11); 3734–3740.
Xu, F., K. Cui, Y. Sun, C. Guo, Z. Liu, Y. Zhang, Y. Shi, and Z. Li. (2010). Facile synthesis of urchin-like gold submicrostructures for nonenzymatic glucose sensing. Talanta, 82(5); 1845–1852.
Yu, S., X. Peng, G. Cao, M. Zhou, L. Qiao, J. Yao, and H. He. (2012). Ni nanoparticles decorated titania nanotube arrays as efficient nonenzymatic glucose sensor. Electrochimica Acta, 76 512–517.
Yusan, S., M. M. Rahman, N. Mohamad, T. M. Arrif, A. Z. A. Latif, M. A. M. A., and W. S. B. Wan Nik. (2018). Development of an Amperometric Glucose Biosensor Based on the Immobilization of Glucose Oxidase on the Se-MCM-41 Mesoporous Composite. Journal of Analytical Methods in Chemistry, 2018 1–8.
Zhao, C., C. Shao, M. Li, and K. Jiao. (2007). Flow-injection analysis of glucose without enzyme based on electrocatalytic oxidation of glucose at a nickel electrode. Talanta, 71(4); 1769–1773.
Authors
Hakim, M. S., Pangestu, H., & Riyanto. (2022). Preparation and Application of Nickel Electroplating on Copper (Ni/EC) Electrode for Glucose Detection. Science and Technology Indonesia, 7(2), 208–212. https://doi.org/10.26554/sti.2022.7.2.208-212
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