Green Synthesis of Nickel Aluminum Layered Double Hydroxide using Chitosan as Template for Adsorption of Phenol
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Keywords:
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Layered Double Hydroxide, Chitosan, Phenol, Adsorption
Abstract
In present study, a modification of the NiAl LDH composite with chitosan was successful. Characterization was carried out using X-rays, The results obtained show that there is an angle of 2θ at 11.57°(003); 22.91°(006); 35.04°(012); 39.73°(015); and 61.9°(110). The FT-IR spectrum of the Chitosan@NiAl LDH at Wavenumber 3448, 1635, 1543, and 601 cm−1. The NiAl LDH and chitosan have a surface area of 3.288 m2/g and 8.558 m2/g, respectively. An increase in the surface area of the composite Chitosan@NiAl LDH 9.493 m2/g, all of adsorbents follow type IV isotherm based on the classification according to IUPAC. The optimum pH of the NiAl LDH at pH 3. The optimum pH for chitosan and chitosan@NiAl LDH material is at the optimum pH of 5. The kinetic and isotherm model in the adsorption process is pseudo-second-order and Freundlich model, respectively. The maximum adsorption capacity of NiAl LDH, chitosan, and chitosan@NiAl LDH is 25.445, 23.753, and 33.223 mg/g, respectively. The increase in regeneration cycles causes a decrease in the percentage of adsorbed; sequentially, the percentage adsorbed during the fifth regeneration reaches 3.545, 1.966, 4.309%, respectively.
References
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Barbusiński, K., S. Salwiczek, and A. Paszewska (2018). The Use of Chitosan for Removing Selected Pollutants from Water and Wastewater–Short Review. Architecture, Civil Engineering, Environment, 9(2); 107-115
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Dehmani, Y., O. El Khalki, H. Mezougane, and S. Abouarnadasse (2021a). Comparative Study on Adsorption of Cationic Dyes and Phenol by Natural Clays. Chemical Data Collections, 33; 100674
Dehmani, Y., H. Lgaz, A. A. Alrashdi, T. Lamhasni, S. Abouarnadasse, and I. M. Chung (2021b). Phenol Adsorption Mechanism on the Zinc Oxide Surface: Experimental, Cluster DFT Calculations, and Molecular Dynamics Simulations. Journal of Molecular Liquids, 324; 114993
Gao, W., Z. Lin, H. Chen, S. Yan, H. Zhu, H. Zhang, H. Sun, S. Zhang, S. Zhang, and Y. Wu (2022). Roles of Graphitization Degree and Surface Functional Groups of N-Doped Activated Biochar for Phenol Adsorption. Journal of Analytical and Applied Pyrolysis, 167; 105700
Gupta, A. and C. Balomajumder (2015). Simultaneous Removal of Cr(VI) and Phenol from Binary Solution using Bacillus sp. Immobilized onto Tea Waste Biomass. Journal of Water Process Engineering, 6; 1–10
Jain, M., S. A. Khan, A. Sahoo, P. Dubey, K. K. Pant, Z. M. Ziora, and M. A. Blaskovich (2022). Statistical Evaluation of Cow-Dung Derived Activated Biochar for Phenol Adsorption: Adsorption Isotherms, Kinetics, and Thermodynamic Studies. Bioresource Technology, 352; 127030
Juleanti, N., N. Normah, P. M. S. B. N. Siregar, A. Wijaya, N. R. Palapa, T. Taher, N. Hidayati, R. Mohadi, and A. Lesbani (2022). Comparison of the Adsorption Ability of MgAl-HC, CaAl-HC, and ZaAl-HC Composite Materials Based on Duku Peel Hydrochar in Adsorption of Direct Green Anionic Dyes. Indonesian Journal of Chemistry, 22(1); 192–204
Khan, D., J. Kuntail, and I. Sinha (2022). Mechanism of Phenol and p-Nitrophenol Adsorption on Kaolinite Surface in Aqueous Medium: A Molecular Dynamics Study. Journal of Molecular Graphics and Modelling; 108251
Lesbani, A., N. R. Palapa, R. J. Sayeri, T. Taher, and N. Hidayati (2021). High Reusability of NiAl LDH/Biochar Composite in the Removal Methylene Blue from Aqueous Solution. Indonesian Journal of Chemistry, 21(2); 421–434
Liu, X., Y. Tu, S. Liu, K. Liu, L. Zhang, G. Li, and Z. Xu (2021). Adsorption of Ammonia Nitrogen and Phenol onto the Lignite Surface: An Experimental and Molecular Dynamics Simulation Study. Journal of Hazardous Materials, 416; 125966
Lupa, L., L. Cocheci, R. Pode, and I. Hulka (2018). Phenol Adsorption using Aliquat 336 Functionalized Zn-Al Layered Double Hydroxide. Separation and Purification Technology, 196; 82–95
Mandal, A. and S. K. Das (2019). Phenol Adsorption from Wastewater using Clarified Sludge from Basic Oxygen Furnace. Journal of Environmental Chemical Engineering, 7(4); 103259
Qu, Y., L. Qin, X. Liu, and Y. Yang (2022). Magnetic Fe3O4/ZIF-8 Composite as an Effective and Recyclable Adsorbent for Phenol Adsorption from Wastewater. Separation and Purification Technology, 294; 121169
Sathya Priya, D. and M. Sureshkumar (2020). Synthesis of Borassus Flabellifer Fruit Husk Activated Carbon Filter for Phenol Removal from Wastewater. International Journal of Environmental Science and Technology, 17(2); 829–842
Seedao, C., T. Rachphirom, M. Phiromchoei, and W. Jangiam (2018). Anionic Dye Adsorption from Aqueous Solutions by Chitosan Coated Luffa Fibers. ASEAN Journal of Chemical Engineering, 18(2); 31–40
Taher, T., R. Putra, N. R. Palapa, and A. Lesbani (2021). Preparation of Magnetite-Nanoparticle-Decorated NiFe Layered Double Hydroxide and its Adsorption Performance for Congo Red Dye Removal. Chemical Physics Letters, 777; 138712
Wang, P., X. Geng, L. Luo, Y. Liu, R. I. Eglitis, and X. Wang (2022). The Adsorption Behavior of Phenol on the Surface of 1D/2D M@MoS2 (M= Co and Rh) for Hydrodeoxidation Reaction: Insights from Theoretical Investigations. Applied Surface Science, 601; 154242
Xie, B., J. Qin, S. Wang, X. Li, H. Sun, and W. Chen (2020). Adsorption of Phenol on Commercial Activated Carbons: Modelling and Interpretation. International Journal of Environmental Research and Public Health, 17(3); 789
Zhang, J., N. Liu, H. Gong, Q. Chen, and H. Liu (2022). Hydroxyl-Functionalized Hypercrosslinked Polymers with Ultrafast Adsorption Rate as an Eficient Adsorbent for Phenol Removal. Microporous and Mesoporous Materials, 336; 111836
Ahmadi, S. and C. A. Igwegbe (2018). Adsorptive Removal of Phenol and Aniline by Modied Bentonite: Adsorption Isotherm and Kinetics Study. Applied Water Science, 8(6); 1–8
Al-Ghouti, M. A., J. Sayma, N. Munira, D. Mohamed, D. A. Da’na, H. Qiblawey, and A. Alkhouzaam (2022). Effective Removal of Phenol from Wastewater using a Hybrid Process of Graphene Oxide Adsorption and UV Irradiation. Environmental Technology & Innovation, 27; 102525
Alves, D. C., J. O. Goncalves, B. B. Coseglio, T. A. Burgo, G. L. Dotto, L. A. Pinto, and T. R. Cadaval Jr (2019). Adsorption of Phenol Onto Chitosan Hydrogel Scaffold Modied with Carbon Nanotubes. Journal of Environmental Chemical Engineering, 7(6); 103460
Asnaoui, H., Y. Dehmani, M. Khalis, and E. K. Hachem (2022). Adsorption of Phenol from Aqueous Solutions by Na–Bentonite: Kinetic, Equilibrium and Thermodynamic Studies. International Journal of Environmental Analytical Chemistry, 102(13); 3043–3057
Barbusiński, K., S. Salwiczek, and A. Paszewska (2018). The Use of Chitosan for Removing Selected Pollutants from Water and Wastewater–Short Review. Architecture, Civil Engineering, Environment, 9(2); 107-115
Billah, R. E. K., Y. Abdellaoui, Z. Anfar, G. Giácoman-Vallejos, M. Agunaou, and A. Soufiane (2020). Synthesis and Characterization of Chitosan/Fluorapatite Composites for the Removal of Cr(VI) from Aqueous Solutions and Optimized Parameters. Water, Air, & Soil Pollution, 231(4); 1–14
Bouteraa, S., F. B. D. Saiah, S. Hamouda, and N. Bettahar (2020). Zn-M-CO3 Layered Double Hydroxides (M= Fe, Cr, or Al): Synthesis, Characterization, and Removal of Aqueous Indigo Carmine. Bulletin of Chemical Reaction Engineering & Catalysis, 15; 43–54
Cao, Y., Y. Wang, F. Zhou, J. Huang, and M. Xu (2022). Acylamino-Functionalized Hyper-Cross-Linked Polymers for Efficient Adsorption Removal of Phenol in Aqueous Solution. Separation and Purification Technology; 122229
Cardinale, A. M., C. Carbone, S. Consani, M. Fortunato, and N. Parodi (2020). Layered Double Hydroxides for Remediation of Industrial Wastewater from a Galvanic Plant. Crystals, 10(6); 443
da Silva, M. C., C. Schnorr, S. F. Lütke, S. Knani, V. X. Nascimento, É. C. Lima, P. S. Thue, J. Vieillard, L. F. Silva, and G. L. Dotto (2022). KOH Activated Carbons from Brazil Nut Shell: Preparation, Characterization, and their Application in Phenol Adsorption. Chemical Engineering Research and Design, 187; 387–396
de Farias, M. B., P. Prediger, and M. G. A. Vieira (2022). Conventional and Green-Synthesized Nanomaterials Applied for the Adsorption and/or Degradation of Phenol: A Recent Overview. Journal of Cleaner Production; 132980
De la Luz-Asunción, M., V. Sánchez-Mendieta, A. Martínez-Hernández, V. Castaño, and C. Velasco-Santos (2015). Adsorption of Phenol from Aqueous Solutions by Carbon Nanomaterials of One and Two Dimensions: Kinetic and Equilibrium Studies. Journal of Nanomaterials, 2015
Dehmani, Y., A. A. Alrashdi, H. Lgaz, T. Lamhasni, S. Abouarnadasse, and I. M. Chung (2020). Removal of Phenol from Aqueous Solution by Adsorption onto Hematite (α-Fe2O3): Mechanism Exploration from Both Experimental and Theoretical Studies. Arabian Journal of Chemistry, 13(5); 5474–5486
Dehmani, Y., O. El Khalki, H. Mezougane, and S. Abouarnadasse (2021a). Comparative Study on Adsorption of Cationic Dyes and Phenol by Natural Clays. Chemical Data Collections, 33; 100674
Dehmani, Y., H. Lgaz, A. A. Alrashdi, T. Lamhasni, S. Abouarnadasse, and I. M. Chung (2021b). Phenol Adsorption Mechanism on the Zinc Oxide Surface: Experimental, Cluster DFT Calculations, and Molecular Dynamics Simulations. Journal of Molecular Liquids, 324; 114993
Gao, W., Z. Lin, H. Chen, S. Yan, H. Zhu, H. Zhang, H. Sun, S. Zhang, S. Zhang, and Y. Wu (2022). Roles of Graphitization Degree and Surface Functional Groups of N-Doped Activated Biochar for Phenol Adsorption. Journal of Analytical and Applied Pyrolysis, 167; 105700
Gupta, A. and C. Balomajumder (2015). Simultaneous Removal of Cr(VI) and Phenol from Binary Solution using Bacillus sp. Immobilized onto Tea Waste Biomass. Journal of Water Process Engineering, 6; 1–10
Jain, M., S. A. Khan, A. Sahoo, P. Dubey, K. K. Pant, Z. M. Ziora, and M. A. Blaskovich (2022). Statistical Evaluation of Cow-Dung Derived Activated Biochar for Phenol Adsorption: Adsorption Isotherms, Kinetics, and Thermodynamic Studies. Bioresource Technology, 352; 127030
Juleanti, N., N. Normah, P. M. S. B. N. Siregar, A. Wijaya, N. R. Palapa, T. Taher, N. Hidayati, R. Mohadi, and A. Lesbani (2022). Comparison of the Adsorption Ability of MgAl-HC, CaAl-HC, and ZaAl-HC Composite Materials Based on Duku Peel Hydrochar in Adsorption of Direct Green Anionic Dyes. Indonesian Journal of Chemistry, 22(1); 192–204
Khan, D., J. Kuntail, and I. Sinha (2022). Mechanism of Phenol and p-Nitrophenol Adsorption on Kaolinite Surface in Aqueous Medium: A Molecular Dynamics Study. Journal of Molecular Graphics and Modelling; 108251
Lesbani, A., N. R. Palapa, R. J. Sayeri, T. Taher, and N. Hidayati (2021). High Reusability of NiAl LDH/Biochar Composite in the Removal Methylene Blue from Aqueous Solution. Indonesian Journal of Chemistry, 21(2); 421–434
Liu, X., Y. Tu, S. Liu, K. Liu, L. Zhang, G. Li, and Z. Xu (2021). Adsorption of Ammonia Nitrogen and Phenol onto the Lignite Surface: An Experimental and Molecular Dynamics Simulation Study. Journal of Hazardous Materials, 416; 125966
Lupa, L., L. Cocheci, R. Pode, and I. Hulka (2018). Phenol Adsorption using Aliquat 336 Functionalized Zn-Al Layered Double Hydroxide. Separation and Purification Technology, 196; 82–95
Mandal, A. and S. K. Das (2019). Phenol Adsorption from Wastewater using Clarified Sludge from Basic Oxygen Furnace. Journal of Environmental Chemical Engineering, 7(4); 103259
Qu, Y., L. Qin, X. Liu, and Y. Yang (2022). Magnetic Fe3O4/ZIF-8 Composite as an Effective and Recyclable Adsorbent for Phenol Adsorption from Wastewater. Separation and Purification Technology, 294; 121169
Sathya Priya, D. and M. Sureshkumar (2020). Synthesis of Borassus Flabellifer Fruit Husk Activated Carbon Filter for Phenol Removal from Wastewater. International Journal of Environmental Science and Technology, 17(2); 829–842
Seedao, C., T. Rachphirom, M. Phiromchoei, and W. Jangiam (2018). Anionic Dye Adsorption from Aqueous Solutions by Chitosan Coated Luffa Fibers. ASEAN Journal of Chemical Engineering, 18(2); 31–40
Taher, T., R. Putra, N. R. Palapa, and A. Lesbani (2021). Preparation of Magnetite-Nanoparticle-Decorated NiFe Layered Double Hydroxide and its Adsorption Performance for Congo Red Dye Removal. Chemical Physics Letters, 777; 138712
Wang, P., X. Geng, L. Luo, Y. Liu, R. I. Eglitis, and X. Wang (2022). The Adsorption Behavior of Phenol on the Surface of 1D/2D M@MoS2 (M= Co and Rh) for Hydrodeoxidation Reaction: Insights from Theoretical Investigations. Applied Surface Science, 601; 154242
Xie, B., J. Qin, S. Wang, X. Li, H. Sun, and W. Chen (2020). Adsorption of Phenol on Commercial Activated Carbons: Modelling and Interpretation. International Journal of Environmental Research and Public Health, 17(3); 789
Zhang, J., N. Liu, H. Gong, Q. Chen, and H. Liu (2022). Hydroxyl-Functionalized Hypercrosslinked Polymers with Ultrafast Adsorption Rate as an Eficient Adsorbent for Phenol Removal. Microporous and Mesoporous Materials, 336; 111836
Authors
Paluta Utami, H., Ahmad, N., Zahara, Z. A., Lesbani, A., & Mohadi, R. (2022). Green Synthesis of Nickel Aluminum Layered Double Hydroxide using Chitosan as Template for Adsorption of Phenol. Science and Technology Indonesia, 7(4), 530–535. https://doi.org/10.26554/sti.2022.7.4.530-535
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