Adsorption of Phenol from Aqueous Solution Using Zn/Al Layered Double Hydroxides-Cellulose Composite
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Keywords:
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Cellulose, Phenol, Adsorption, Layered Double Hydroxide
Abstract
The successful synthesis and preparation of Zn/Al layered double hydroxide, cellulose, and Zn/Al-cellulose materials were analyzed using XRD, FT-IR, and BET. The diffraction peaks of Zn/Al layered double hydroxide are at 10.3°; 20.3°; 34.8°; and 60.40°, while the diffraction peaks of cellulose are at 15.5°; 22.4°; and 34.5°. Diffraction peaks on Zn/Al layered double hydroxide and cellulose were observed at 3442 cm-1, 1642 cm-1, 1440-1620 cm-1, 1351 cm-1, 1153 cm-1, and 400-800 cm-1. The surface area of the material after the composite increased from 1.968 to 13.615 m2/g. The optimum pH for Zn/Al LDH was pH 4, pH 10 for cellulose, and pH 2 for Zn/Al-cellulose. The isotherm data of Zn/Al LDH and cellulose followed the Freundlich model, while Zn/Al-cellulose followed the Langmuir model. The reuse of adsorbents in the adsorption process can be used up to 3 times.
References
Ali, N. S., N. M. Jabbar, S. M. Alardhi, H. S. Majdi, and T. M. Albayati (2022). Adsorption of Methyl Violet Dye Onto a Prepared Bio-Adsorbent from Date Seeds: Isotherm, Kinetics, and Thermodynamic Studies. Heliyon, 8(8); 10276
Alnasrawi, F. A., A. A. Mohammed, and T. J. Al-Musawi (2022). Synthesis, Characterization and Adsorptive Performance of CuMgAl-Layered Double Hydroxides/Montmorillonite Nanocomposite for the Removal of Zn(II) Ions. Environmental Nanotechnology, Monitoring & Management, 19; 100771
Azad, H. and M. Mohsennia (2020). A Novel Free-Standing Polyvinyl Butyral Polyacrylonitrile/ZnAl-Layered Double Hydroxide Nanocomposite Membrane for Enhanced Heavy Metal Removal fromWastewater. Journal of Membrane Science, 615; 118487
Bessaies, H., S. Iftekhar, M. B. Asif, J. Kheriji, C. Necibi, M. Sillanpää, and B. Hamrouni (2021). Characterization and Physicochemical Aspects of Novel Cellulose-Based Layered Double Hydroxide Nanocomposite for Removal of Antimony and Fluoride from Aqueous Solution. Journal of Environmental Sciences, 102; 301–315
Çalışkan, M. and T. Baran (2022). Immobilized Palladium Nanoparticles on Schiff Base Functionalized ZnAl Layered Double Hydroxide: A Highly Stable and Retrievable Heterogeneous Nanocatalyst Towards Aryl Halide Cyanations. Applied Clay Science, 219; 106433
da Silva, M. C., C. Schnorr, S. F. Lütke, S. Knani, V. X. Nascimento, É. C. Lima, P. S. Thue, J. Vieillard, L. F. Silva, and G. L. Dotto (2022). KOH Activated Carbons from Brazil
Nut Shell: Preparation, Characterization, and Their Application in Phenol Adsorption. Chemical Engineering Research and Design, 187; 387–396
Dehmani, Y., J. Lainé, A. Daouli, L. Sellaoui, A. Bonilla-Petriciolet, T. Lamhasni, S. Abouarnadasse, and M. Badawi (2023). Unravelling the Adsorption Mechanism of Phenol on Zinc Oxide at Various Coverages Via Statistical Physics, Artificial Neural Network Modeling and Ab Initio Molecular Dynamics. Chemical Engineering Journal, 452; 139171
Dinari, M., A. Haghighi, and P. Asadi (2019). Facile Synthesis of ZnAl-EDTA Layered Double Hydroxide/Poly (Vinyl Alcohol) Nanocomposites as an Efficient Adsorbent of Cd(II) Ions from the Aqueous Solution. Applied Clay Science, 170; 21–28
Haydari, I., A. Khalid, K. Sava, T. Daştan, N. Ouazzani, L. Mandi, and A. Faissal (2023). Green Synthesis of Reduced Graphene Oxide and Their Use on Column Adsorption of Phenol from Olive Mill Wastewater. Process Safety and Environmental Protection, 170; 1079–1091
Hu, Z., L. Cai, J. Liang, X. Guo,W. Li, and Z. Huang (2019). Green Synthesis of Expanded Graphite/Layered Double Hydroxides Nanocomposites and Their Application in Adsorption Removal of Cr(VI) from Aqueous Solution. Journal of Cleaner Production, 209; 1216–1227
Jabli, M., N. Sebeia, Y. El-Ghoul, R. Soury, Y. O. Al-Ghamdi, and T. A. Saleh (2022). Chemical Modification of Microcrystalline Cellulose with Polyethyleneimine and Hydrazine: Characterization and Evaluation of its Adsorption Power Toward Anionic Dyes. International Journal of Biological Macromolecules, 229; 210–223
Karamipour, A., P. K. Parsi, P. Zahedi, and S. M. A. Moosavian (2020). Using Fe3O−4 Coated Nanofibers Based on Cellulose Acetate/Chitosan for Adsorption of Cr(VI), Ni(II) and Phenol from Aqueous Solutions. International Journal of Biological Macromolecules, 154; 1132–1139
Keshvardoostchokami, M., M. Majidi, A. Zamani, and B. Liu (2021). Adsorption of Phenol on Environmentally Friendly Fe3O4/Chitosan/Zeolitic Imidazolate Framework-8 Nanocomposite: Optimization by Experimental Design Methodology. Journal of Molecular Liquids, 323; 115064
Kong, F., Y. Xie, C. Xia, H.Huang, D. Liang, Y. Qiu,Q. Zhang, X. Liu, H. Shao, and Z.Meng (2023). Removal of Hydrogen Sulfide by Layered Double Hydroxide Loaded Biochar in Dynamic Adsorption Experiment. Surfaces and Interfaces, 36; 102487
Li, Y., Q. Du, T. Liu, J. Sun, Y. Jiao, Y. Xia, L. Xia, Z.Wang, W. Zhang, and K.Wang (2012). Equilibrium, Kinetic and Thermodynamic Studies on the Adsorption of Phenol Onto Graphene. Materials Research Bulletin, 47(8); 1898–1904
Luo, X., Z. Huang, J. Lin, X. Li, J. Qiu, J. Liu, and X. Mao (2020). Hydrothermal Carbonization of Sewage Sludge and In-Situ Preparation of Hydrochar/MgAl-Layered Double Hydroxides Composites for Adsorption of Pb(II). Journal of Cleaner Production, 258; 120991
Luo, Y., Y. Wang, F. Hua, M. Xue, X. Xie, Y. Xie, S. Yu, L. Zhang, Z. Yin, and C. Xie (2023). Adsorption and Photodegradation of Reactive Red 120 with Nickel-Iron-Layered Double Hydroxide/Biochar Composites. Journal of Hazardous Materials, 443; 130300
Mahmoud, A. S. (2022). Effect of Nano Bentonite on Direct Yellow 50 Dye Removal; Adsorption Isotherm, Kinetic Analysis, and Thermodynamic Behavior. Progress in Reaction Kinetics and Mechanism, 47(2); 104517
Mallakpour, S., Z. Radfar, and M. Feiz (2023). Chitosan/Tannic Acid/ZnFe Layered Double Hydroxide and Mixed Metal Oxides Nanocomposite for the Adsorption of Reactive Dyes. Carbohydrate Polymers, 305; 120528
Nakhjiri, M. T., G. B. Marandi, and M. Kurdtabar (2021). Preparation of Magnetic Double Network Nanocomposite Hydrogel for Adsorption of Phenol and p-Nitrophenol from Aqueous Solution Journal of Environmental Chemical Engineering, 9(2); 105039
Rezvani, Z., L. J. Foruzin, and K. Nejati (2023). Intercalation ofMordant Orange 1 into ZnAl-Layered Double Hydroxide and its Dual-Color Photoluminescence Emission. Journal of Molecular Structure, 1274; 134555
Safwat, S. M., M. Medhat, and H. Abdel-Halim (2019). Adsorption of Phenol Onto Aluminium Oxide and Zinc Oxide: A Comparative Study with Titanium Dioxide. Separation Science and Technology, 54(17); 2840–2852
Sas, O. G., M. Castro, Á. Domínguez, and B. González (2019). Removing Phenolic Pollutants Using Deep Eutectic Solvents. Separation and Purification Technology, 227; 115703
Siregar, P. M. S. B. N., A.Wijaya, Amri, J. P. Nduru, N. Hidayati, A. Lesbani, and R. Mohadi (2022). Layered Double Hydroxide/C (C= Humic Acid; Hydrochar) As Adsorbents of Cr(VI). Science and Technology Indonesia, 7(1); 41–48
Tshemese, S. J., W. Mhike, and S. M. Tichapondwa (2021). Adsorption of Phenol and Chromium(VI) from Aqueous Solution Using Exfoliated Graphite: Equilibrium, Kinetics and Thermodynamic Studies. Arabian Journal of Chemistry, 14(6); 103160
Wang, L., H. Yang, M. Guo, Z.Wang, and X. Zheng (2022). Adsorption of Antibiotics on Different Microplastics (MPs): Behavior and Mechanism. Science of the Total Environment, 863; 161022
Wu, S., H. Liang, Z. Zhang, Q. Zhang, Q. Han, J. Wang, M. Gao, H. Fan, J. Yang, and J. Lang (2022). The Photocatalytic Degradation and Mechanism of Rhodamine B by Zn-Al Layered Double Hydroxide. OpticalMaterials, 131; 112636
Zhang, B., R. Zhao, D. Sun, Y. Li, and T. Wu (2019). Sustainable Fabrication of Graphene Oxide/Manganese Oxide Composites for Removing Phenolic Compounds by Adsorption Oxidation Process. Journal of Cleaner Production, 215; 165–174
Zhang, C., J. Zheng, and Z. Wang (2023). Plasma-Induced Exfoliation in NiMn-Layered Double Hydroxides for Enhanced Oxygen Evolution Reaction Activity. Catalysis Today
Zhang, X., Z. Song, Y. Dou, Y. Xue, Y. Ji, Y. Tang, and M. Hu (2021). Removal Difference of Cr(VI) by Modified Zeolites Coated with MgAl and ZnAl-Layered Double Hydroxides: Efficiency, Factors and Mechanism. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 621; 126583
Zubair, M., H. A. Aziz, I. Ihsanullah, M. A. Ahmad, and M. A. Al-Harthi (2022). Engineered Biochar Supported Layered Double Hydroxide-Cellulose Nanocrystals Composite: Synthesis, Characterization and Azo Dye Removal Performance. Chemosphere, 307; 136054
Alnasrawi, F. A., A. A. Mohammed, and T. J. Al-Musawi (2022). Synthesis, Characterization and Adsorptive Performance of CuMgAl-Layered Double Hydroxides/Montmorillonite Nanocomposite for the Removal of Zn(II) Ions. Environmental Nanotechnology, Monitoring & Management, 19; 100771
Azad, H. and M. Mohsennia (2020). A Novel Free-Standing Polyvinyl Butyral Polyacrylonitrile/ZnAl-Layered Double Hydroxide Nanocomposite Membrane for Enhanced Heavy Metal Removal fromWastewater. Journal of Membrane Science, 615; 118487
Bessaies, H., S. Iftekhar, M. B. Asif, J. Kheriji, C. Necibi, M. Sillanpää, and B. Hamrouni (2021). Characterization and Physicochemical Aspects of Novel Cellulose-Based Layered Double Hydroxide Nanocomposite for Removal of Antimony and Fluoride from Aqueous Solution. Journal of Environmental Sciences, 102; 301–315
Çalışkan, M. and T. Baran (2022). Immobilized Palladium Nanoparticles on Schiff Base Functionalized ZnAl Layered Double Hydroxide: A Highly Stable and Retrievable Heterogeneous Nanocatalyst Towards Aryl Halide Cyanations. Applied Clay Science, 219; 106433
da Silva, M. C., C. Schnorr, S. F. Lütke, S. Knani, V. X. Nascimento, É. C. Lima, P. S. Thue, J. Vieillard, L. F. Silva, and G. L. Dotto (2022). KOH Activated Carbons from Brazil
Nut Shell: Preparation, Characterization, and Their Application in Phenol Adsorption. Chemical Engineering Research and Design, 187; 387–396
Dehmani, Y., J. Lainé, A. Daouli, L. Sellaoui, A. Bonilla-Petriciolet, T. Lamhasni, S. Abouarnadasse, and M. Badawi (2023). Unravelling the Adsorption Mechanism of Phenol on Zinc Oxide at Various Coverages Via Statistical Physics, Artificial Neural Network Modeling and Ab Initio Molecular Dynamics. Chemical Engineering Journal, 452; 139171
Dinari, M., A. Haghighi, and P. Asadi (2019). Facile Synthesis of ZnAl-EDTA Layered Double Hydroxide/Poly (Vinyl Alcohol) Nanocomposites as an Efficient Adsorbent of Cd(II) Ions from the Aqueous Solution. Applied Clay Science, 170; 21–28
Haydari, I., A. Khalid, K. Sava, T. Daştan, N. Ouazzani, L. Mandi, and A. Faissal (2023). Green Synthesis of Reduced Graphene Oxide and Their Use on Column Adsorption of Phenol from Olive Mill Wastewater. Process Safety and Environmental Protection, 170; 1079–1091
Hu, Z., L. Cai, J. Liang, X. Guo,W. Li, and Z. Huang (2019). Green Synthesis of Expanded Graphite/Layered Double Hydroxides Nanocomposites and Their Application in Adsorption Removal of Cr(VI) from Aqueous Solution. Journal of Cleaner Production, 209; 1216–1227
Jabli, M., N. Sebeia, Y. El-Ghoul, R. Soury, Y. O. Al-Ghamdi, and T. A. Saleh (2022). Chemical Modification of Microcrystalline Cellulose with Polyethyleneimine and Hydrazine: Characterization and Evaluation of its Adsorption Power Toward Anionic Dyes. International Journal of Biological Macromolecules, 229; 210–223
Karamipour, A., P. K. Parsi, P. Zahedi, and S. M. A. Moosavian (2020). Using Fe3O−4 Coated Nanofibers Based on Cellulose Acetate/Chitosan for Adsorption of Cr(VI), Ni(II) and Phenol from Aqueous Solutions. International Journal of Biological Macromolecules, 154; 1132–1139
Keshvardoostchokami, M., M. Majidi, A. Zamani, and B. Liu (2021). Adsorption of Phenol on Environmentally Friendly Fe3O4/Chitosan/Zeolitic Imidazolate Framework-8 Nanocomposite: Optimization by Experimental Design Methodology. Journal of Molecular Liquids, 323; 115064
Kong, F., Y. Xie, C. Xia, H.Huang, D. Liang, Y. Qiu,Q. Zhang, X. Liu, H. Shao, and Z.Meng (2023). Removal of Hydrogen Sulfide by Layered Double Hydroxide Loaded Biochar in Dynamic Adsorption Experiment. Surfaces and Interfaces, 36; 102487
Li, Y., Q. Du, T. Liu, J. Sun, Y. Jiao, Y. Xia, L. Xia, Z.Wang, W. Zhang, and K.Wang (2012). Equilibrium, Kinetic and Thermodynamic Studies on the Adsorption of Phenol Onto Graphene. Materials Research Bulletin, 47(8); 1898–1904
Luo, X., Z. Huang, J. Lin, X. Li, J. Qiu, J. Liu, and X. Mao (2020). Hydrothermal Carbonization of Sewage Sludge and In-Situ Preparation of Hydrochar/MgAl-Layered Double Hydroxides Composites for Adsorption of Pb(II). Journal of Cleaner Production, 258; 120991
Luo, Y., Y. Wang, F. Hua, M. Xue, X. Xie, Y. Xie, S. Yu, L. Zhang, Z. Yin, and C. Xie (2023). Adsorption and Photodegradation of Reactive Red 120 with Nickel-Iron-Layered Double Hydroxide/Biochar Composites. Journal of Hazardous Materials, 443; 130300
Mahmoud, A. S. (2022). Effect of Nano Bentonite on Direct Yellow 50 Dye Removal; Adsorption Isotherm, Kinetic Analysis, and Thermodynamic Behavior. Progress in Reaction Kinetics and Mechanism, 47(2); 104517
Mallakpour, S., Z. Radfar, and M. Feiz (2023). Chitosan/Tannic Acid/ZnFe Layered Double Hydroxide and Mixed Metal Oxides Nanocomposite for the Adsorption of Reactive Dyes. Carbohydrate Polymers, 305; 120528
Nakhjiri, M. T., G. B. Marandi, and M. Kurdtabar (2021). Preparation of Magnetic Double Network Nanocomposite Hydrogel for Adsorption of Phenol and p-Nitrophenol from Aqueous Solution Journal of Environmental Chemical Engineering, 9(2); 105039
Rezvani, Z., L. J. Foruzin, and K. Nejati (2023). Intercalation ofMordant Orange 1 into ZnAl-Layered Double Hydroxide and its Dual-Color Photoluminescence Emission. Journal of Molecular Structure, 1274; 134555
Safwat, S. M., M. Medhat, and H. Abdel-Halim (2019). Adsorption of Phenol Onto Aluminium Oxide and Zinc Oxide: A Comparative Study with Titanium Dioxide. Separation Science and Technology, 54(17); 2840–2852
Sas, O. G., M. Castro, Á. Domínguez, and B. González (2019). Removing Phenolic Pollutants Using Deep Eutectic Solvents. Separation and Purification Technology, 227; 115703
Siregar, P. M. S. B. N., A.Wijaya, Amri, J. P. Nduru, N. Hidayati, A. Lesbani, and R. Mohadi (2022). Layered Double Hydroxide/C (C= Humic Acid; Hydrochar) As Adsorbents of Cr(VI). Science and Technology Indonesia, 7(1); 41–48
Tshemese, S. J., W. Mhike, and S. M. Tichapondwa (2021). Adsorption of Phenol and Chromium(VI) from Aqueous Solution Using Exfoliated Graphite: Equilibrium, Kinetics and Thermodynamic Studies. Arabian Journal of Chemistry, 14(6); 103160
Wang, L., H. Yang, M. Guo, Z.Wang, and X. Zheng (2022). Adsorption of Antibiotics on Different Microplastics (MPs): Behavior and Mechanism. Science of the Total Environment, 863; 161022
Wu, S., H. Liang, Z. Zhang, Q. Zhang, Q. Han, J. Wang, M. Gao, H. Fan, J. Yang, and J. Lang (2022). The Photocatalytic Degradation and Mechanism of Rhodamine B by Zn-Al Layered Double Hydroxide. OpticalMaterials, 131; 112636
Zhang, B., R. Zhao, D. Sun, Y. Li, and T. Wu (2019). Sustainable Fabrication of Graphene Oxide/Manganese Oxide Composites for Removing Phenolic Compounds by Adsorption Oxidation Process. Journal of Cleaner Production, 215; 165–174
Zhang, C., J. Zheng, and Z. Wang (2023). Plasma-Induced Exfoliation in NiMn-Layered Double Hydroxides for Enhanced Oxygen Evolution Reaction Activity. Catalysis Today
Zhang, X., Z. Song, Y. Dou, Y. Xue, Y. Ji, Y. Tang, and M. Hu (2021). Removal Difference of Cr(VI) by Modified Zeolites Coated with MgAl and ZnAl-Layered Double Hydroxides: Efficiency, Factors and Mechanism. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 621; 126583
Zubair, M., H. A. Aziz, I. Ihsanullah, M. A. Ahmad, and M. A. Al-Harthi (2022). Engineered Biochar Supported Layered Double Hydroxide-Cellulose Nanocrystals Composite: Synthesis, Characterization and Azo Dye Removal Performance. Chemosphere, 307; 136054
Authors
Mohadi, R. ., Amri, Badaruddin, M. ., Ahmad, N., & Lesbani, A. (2023). Adsorption of Phenol from Aqueous Solution Using Zn/Al Layered Double Hydroxides-Cellulose Composite. Science and Technology Indonesia, 8(1), 123–128. https://doi.org/10.26554/sti.2023.8.1.123-128
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