High Performance of Ni-Al/magnetite Biochar for Methyl Orange Removal in Aqueous Solution

Neza Rahayu Palapa, Zaqiya Artha Zahara, Risfidian Mohadi, Idha Royani, Aldes Lesbani

Abstract

Elevated concentrations of dyes in water have a significant impact on both the aquatic ecosystem and human well-being. The adsorption approach, which is cost-effective and simple to use, was chosen for color treatment. The adsorbents used in this study were Modified Layered Double Hydroxides (LDHs) and Magnetite Biochar (MBC). To prepare the Ni-Al/MBC composites, a technique called coprecipitation and hydrothermal was employed. The successful preparation of these composites was confirmed through the use of characterization tests including X-Ray Diffraction (XRD), Fourier Transform – Infra Red (FT-IR), Brunauer Emmet Teller (BET), and Vibrating Sample Magnometer (VSM). The study focused on analyzing the kinetics, isotherms, and thermodynamics of adsorption in order to anticipate the mechanism of Methyl Orange (MO) adsorption. Additionally, the regeneration process was investigated to assess the adsorbent's ability for repeated usage. The percentage of Ni-Al/MBC adsorbed during the first to fifth regeneration cycles was 86.940%, 82.545%, 70.752%, 56.244%, and 34.503% respectively. The duration of contact was 70 minutes, as determined by the Pseudo Second Order (PSO) equation, with an adsorption rate of 0.0030 g/mg.min. The Langmuir equation indicated a maximum adsorption capacity of 45.455 mg/g.

References

Abdallah, I. A., S. F. Hammad, A. Bedair, R. Abdelhameed, M. Locatelli, and F. R. Mansour (2023). Applications of Layered Double Hydroxides in Sample Preparation: A Review. Microchemical Journal; 108916

Ahmad, N., Z. A. Zahara, A. Wijaya, F. S. Arsyad, I. Royani, and A. Lesbani (2023). Fabrication and Characterization Fe3O4/Humic Acid for the Efficient Removal of Malachite Green. Science and Technology Indonesia, 8(4); 617–625

Akter, S. and M. S. Islam (2022). Effect of Additional Fe2+ Salt on Electrocoagulation Process for the Degradation of Methyl Orange Dye: An Optimization and Kinetic Study. Heliyon, 8(8); e10176

Alyasi, H., H. Mackey, and G. McKay (2023). Adsorption of Methyl Orange from Water Using Chitosan Bead-like Materials. Molecules, 28(18); 6561

Amri, A., R. Rezonsi, N. Ahmad, T. Taher, N. R. Palapa, R. Mohadi, and A. Lesbani (2023). Biochar Modified Layered Double Hydroxide for Highly Efficient on Phenol Adsorption. Bulletin of Chemical Reaction Engineering & Catalysis, 18(3); 460–472

Aruna Janani, V., D. Gokul, N. Dhivya, A. Nesarani, K. Mukilan, A. Suresh Kumar, and M. Vignesh Kumar (2023). Optimization Studies on Methyl Orange (MO) Dye Adsorption using Activated Carbon Nanoadsorbent of Ocimum basilicum Linn Leaves. Journal of Nanomaterials, 2023; 7969512

Bartel, C. J., S. L. Millican, A. M. Deml, J. R. Rumptz, W. Tumas, A. W. Weimer, S. Lany, V. Stevanović, C. B. Musgrave, and A. M. Holder (2018). Physical Descriptor for the Gibbs Energy of Inorganic Crystalline Solids and Temperature-Dependent Materials Chemistry. Nature Communications, 9(1); 4168

Bini, M. and F. Monteforte (2018). Layered Double Hydroxides (LDHs): Versatile and Powerful Hosts for Different Applications. Journal of Analytical and Pharmaceutical Research, 7(1); 00206

Chen, Q., Y. Tian, P. Li, C. Yan, Y. Pang, L. Zheng, H. Deng, W. Zhou, and X. Meng (2017). Study on Shale Adsorption Equation Based on Monolayer Adsorption, Multilayer Adsorption, and Capillary Condensation. Journal of Chemistry, 2017; 1496463

Daghooghi-Mobarakeh, H., N. Campbell, W. K. Bertrand, P. G. Kumar, S. Tiwari, L. Wang, R. Wang, M. Miner, and P. E. Phelan (2020). Ultrasound-Assisted Regeneration of Zeolite/water Adsorption Pair. Ultrasonics Sonochemistry, 64; 105042

El Maguana, Y., N. Elhadiri, M. Benchanaa, and R. Chikri (2020). Activated Carbon for Dyes Removal: Modeling and Understanding the Adsorption Process. Journal of Chemistry, 2020; 1–9

Elsawy, H. A., Y. G. Emam, and D. A. Ali (2022). Kinetics and Isotherm Studies For Adsorption Of Methyl Orange Dye From Aqueous Solutions Using Hydroxyapatite. Journal of Southwest Jiaotong University, 57(6); 1043–1052

Eltaweil, A., H. A. Mohamed, E. M. Abd El-Monaem, and G. El-Subruiti (2020). Mesoporous Magnetic Biochar Composite for Enhanced Adsorption of Malachite Green Dye: Characterization, Adsorption Kinetics, Thermodynamics and Isotherms. Advanced Powder Technology, 31(3); 1253–1263

Ghani, U., W. Jiang, K. Hina, A. Idrees, M. Iqbal, M. Ibrahim, R. Saeed, M. K. Irshad, and I. Aslam (2022). Adsorption of Methyl Orange and Cr (VI) onto Poultry Manure-Derived Biochar from Aqueous Solution. Frontiers in Environmental Science, 10; 887425

Haque, M. M., M. A. Haque, M. K. Mosharaf, and P. K. Marcus (2021). Decolorization, Degradation and Detoxification of Carcinogenic Sulfonated Azo Dye Methyl Orange by Newly Developed Biofilm Consortia. Saudi Journal of Biological Sciences, 28(1); 793–804

Ighalo, J. O., A. G. Adeniyi, J. A. Adeniran, and S. Ogunniyi (2021). A Systematic Literature Analysis of the Nature and Regional Distribution of Water Pollution Sources in Nigeria. Journal of Cleaner Production, 283; 124566

Istratie, R., M. Stoia, C. Păcurariu, and C. Locovei (2019). Single and Simultaneous Adsorption of Methyl Orange and Phenol onto Magnetic Iron Oxide/carbon Nanocomposites. Arabian Journal of Chemistry, 12(8); 3704–3722

Jemai, R., M. A. Djebbi, S. Boubakri, H. Ben Rhaiem, and A. Ben Haj Amara (2023). Effective Removal of Methyl Orange Dyes Using an Adsorbent Prepared from Porous Starch Aerogel and Organoclay. Colorants, 2(2); 209–229

Jia, Y., L. Ding, P. Ren, M. Zhong, J. Ma, and X. Fan (2020). Performances and Mechanism of Methyl Orange and Congo Red Adsorbed on the Magnetic Ion-Exchange Resin. Journal of Chemical & Engineering Data, 65(2); 725–736

Juleanti, N., N. R. Palapa, T. Taher, N. Hidayati, B. I. Putri, and A. Lesbani (2021). The Capability of Biochar-Based CaAl and MgAl Composite Materials as Adsorbent for Removal Cr(VI) in Aqueous Solution. Science and Technology Indonesia,, 6(3); 196–203

Kameliya, J., A. Verma, P. Dutta, C. Arora, S. Vyas, and R. S. Varma (2023). Layered Double Hydroxide Materials: A Review on Their Preparation, Characterization, and Applications. Inorganics, 11(3); 121

Khan, A. U., M. Zahoor, M. U. Rehman, A. B. Shah, I. Zekker, F. A. Khan, R. Ullah, G. M. Albadrani, R. Bayram, and H. R. Mohamed (2022). Biological Mineralization of Methyl Orange by Pseudomonas aeruginosa. Water, 14(10); 1551

Kishor, R., D. Purchase, G. D. Saratale, R. G. Saratale, L. F. R. Ferreira, M. Bilal, R. Chandra, and R. N. Bharagava (2021). Ecotoxicological and Health Concerns of Persistent Coloring Pollutants of Textile Industry Wastewater and Treatment Approaches for Environmental Safety. Journal of Environmental Chemical Engineering, 9(2); 105012

Koo, K. N., A. F. Ismail, M. H. D. Othman, N. Bidin, and M. A. Rahman (2019). Preparation and Characterization of Superparamagnetic Magnetite (Fe3O4) Nanoparticles: A Short Review. Malaysian Journal of Fundamental and Applied Sciences, 15(1); 23–31

Liu, X., Z. Chen, W. Du, P. Liu, L. Zhang, and F. Shi (2022). Treatment of Wastewater Containing Methyl Orange Dye by Fluidized Three Dimensional Electrochemical Oxidation Process Integrated with Chemical Oxidation and Adsorption. Journal of Environmental Management, 311; 114775

Mamat, M., M. A. A. Abdullah, M. A. Kadir, A. M. Jaafar, and E. Kusrini (2018). Preparation of Layered Double Hydroxides with Different Divalent Metals for The Adsorption of Methyl Orange Dye from Aqueous Solutions. Chemical Engineering, 9(6); 1103–1111

Manalu, R. N., Z. A. Zahara, and R. Mohadi (2023). Ni-Cr Layered Double Hydroxide/Microcrystalline Cellulose Composite as Adsorbents for Malachite Green Dye. Indonesian Journal of Material Research, 1(2); 51–60

Meili, L., P. Lins, C. Zanta, J. Soletti, L. Ribeiro, C. Dornelas, T. Silva, and M. Vieira (2019). MgAl LDH/biochar Composites for Methylene Blue Removal by Adsorption. Applied Clay Science, 168; 11–20

Oktriyanti, M., N. R. Palapa, R. Mohadi, and A. Lesbani (2019). Modification Of Zn-Cr Layered Double Hydroxide With Keggin Ion. Indonesian Journal of Environmental Management and Sustainability, 3(3); 93–99

Purnomo, A. S. and M. O. Mawaddah (2020). Biodecolorization of Methyl Orange by Mixed Cultures of Brown-Rot Fungus Daedalea Dickinsii and Bacterium Pseudomonas aeruginosa. Biodiversitas Journal of Biological Diversity, 21(5); 2297–2302

Radoor, S., J. Karayil, A. Jayakumar, J. Parameswaranpillai, and S. Siengchin (2021). Efficient Removal of Methyl Orange from Aqueous Solution Using Mesoporous ZSM-5 Zeolite: Synthesis, Kinetics and Isotherm Studies. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 611; 125852

Raji, Y., A. Nadi, M. Rouway, S. Jamoudi Sbai, W. Yassine, A. Elmahbouby, O. Cherkaoui, and S. Zyade (2022). Efficient Adsorption of Methyl Orange on Nanoporous Carbon from Agricultural Wastes: Characterization, Kinetics, Thermodynamics, Regeneration and Adsorption Mechanism. Journal of Composites Science, 6(12); 385

Regraguy, B., M. Rahmani, J. Mabrouki, F. Drhimer, I. Ellouzi, C. Mahmou, A. Dahchour, M. E. Mrabet, and S. E. Hajjaji (2022). Photocatalytic Degradation of Methyl Orange in the Presence of Nanoparticles NiSO4/TiO2. Nanotechnology for Environmental Engineering, 7(1); 157–171

Sajid, M. and I. Ihsanullah (2023). Magnetic Layered Double Hydroxide-Based Composites As Sustainable Adsorbent Materials for Water Treatment Applications: Progress, Challenges, and Outlook. Science of The Total Environment, 880; 163299

Santhosh, C., E. Daneshvar, K. M. Tripathi, P. Baltrenas, ˙ T. Kim, E. Baltrenait ˙ e, and A. Bhatnagar (2020). Synthesis ˙and Characterization of Magnetic Biochar Adsorbents for the Removal of Cr (VI) and Acid Orange 7 Dye from Aqueous Solution. Environmental Science and Pollution Research, 27; 32874–32887

Tran, H. N. (2023). Applying Linear Forms of Pseudo-SecondOrder Kinetic Model for Feasibly Identifying Errors in the Initial Periods of Time-Dependent Adsorption Datasets. Water, 15(6); 1231

Tran, H. N., E. C. Lima, R. S. Juang, J. C. Bollinger, and H. P. Chao (2021). Thermodynamic Parameters of Liquid–Phase Adsorption Process Calculated from Different Equilibrium Constants Related to Adsorption Isotherms: A Comparison Study. Journal of Environmental Chemical Engineering, 9(6); 106674

Utami, H. P., N. Ahmad, Z. A. Zahara, and M. R. Lesbani, A. (2022). Green Synthesis of Nickel Aluminum Layered Double Hydroxide using Chitosan as Template for Adsorption of Phenol. Science and Technology Indonesia, 7(4); 530–535

Wu, L., X. Liu, G. Lv, R. Zhu, L. Tian, M. Liu, Y. Li, W. Rao, T. Liu, and L. Liao (2021). Study on the Adsorption Properties of Methyl Orange by Natural One-Dimensional NanoMineral Materials with Different Structures. Scientific Reports, 11(1); 10640

Yuliasari, N., R. Mohadi, and A. Lesbani (2022). Modification of Pristine Layered Double Hydroxide to Form Metal Oxide Composites As an Anionic Dye Photodegradation Catalysts. Communications in Science and Technology, 7(2); 168–174

Zaghloul, A., R. Benhiti, A. Soudani, M. Chiban, M. Zerbet, and F. Sinan (2019). Removal of Methyl Orange from Aqueous Solution Using Synthetic Clay Type MgAl-LDH: Characterization, Isotherm and Thermodynamic Studies. Mediterranean Journal of Chemistry, 9(2); 155–163

Zahara, Z. A., I. Royani, N. R. Palapa, R. Mohadi, and A. Lesbani (2023). Treatment of Methylene Blue Using Ni-Al/Magnetite Biochar Layered Double Hydroxides Composite by Adsorption. Bulletin of Chemical Reaction Engineering & Catalysis, 18(4); 659–674

Zhang, Y., H. Xu, and S. Lu (2021). Preparation and Application of Layered Double Hydroxide Nanosheets. RSC Advances, 11(39); 24254–24281

Authors

Neza Rahayu Palapa
nezarahayu@gmail.com (Primary Contact)
Zaqiya Artha Zahara
Risfidian Mohadi
Idha Royani
Aldes Lesbani
Palapa, N. R., Zahara, Z. A., Mohadi, R., Royani, I., & Lesbani, A. (2024). High Performance of Ni-Al/magnetite Biochar for Methyl Orange Removal in Aqueous Solution. Science and Technology Indonesia, 9(1), 156–166. https://doi.org/10.26554/sti.2024.9.1.156-166

Article Details