Layered Double Hydroxide/C (C=Humic Acid;Hydrochar) As Adsorbents of Cr(VI)
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Keywords:
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Composite , Layered Double Hydroxide, Humic Acid, Hydrochar, Adsorption
Abstract
Layered double hydroxide (LDH) is known as a layered material that can be used as an adsorbent to remove pollutants from aqueous solutions. The use of layered double hydroxide as an adsorbent is not very effective due to its structure which is easily damaged so that it cannot be reused and its small surface area which results in a small adsorption capacity. This can be overcome by developing layered double hydroxide into a composite material. Modification of layered double hydroxide is done by using supporting materials in the form of humic acid and hydrochar. In this study the adsorbent was applied in the removal of Cr(VI) metal from aqueous solutions. The layered double hydroxide modification process was successfully carried out as seen from the XRD, FTIR, and BET analysis. XRD analysis shows the peaks that appear in Mg/Al-AH and Mg/Al-HC are peaks composed of their constituent materials, namely Mg/Al LDH, humic acid, and hydrochar. The vibrations that appear in Mg/Al-AH and Mg/Al-HC are vibrations originating from Mg/Al, humic acid, and hydrochar. The layered double hydroxide material composited with humic acid showed a surface area from 2.155 m2/g to 3.337 m2/g. The layered double hydroxide material composited with hydrochar showed a larger surface area than the Mg/Al LDH base material. The surface area increased 37 times, from 2.155 m2/g to 74.207 m2/g. The Mg/Al-AH composite showed the first adsorption ability of 89.064% and there was no significant decrease in the next cycle. The Mg/Al-HC composite showed adsorption ability in the first cycle which reached 97.079%, the ability to survive up to the fifth cycle with a final ability of 75.029%.
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Saheed, I. O., O. W. Da, and F. B. M. Suah (2020). Chi- tosan Modifications for Adsorption of Pollutants. Journal of Hazardous Materials, 408; 124889
Shrestha, S. L. (2018). Study of the Adsorption Kinetics of Iron Ion from Wastewater Using Banana Peel. International Journal of Advanced Research Chemical Science, 5(3); 1–8
Siregar, P. M. S. B. N., N. R. Palapa, A. Wijaya, E. S. Fitri, and A. Lesbani (2021). Structural Stability of Ni/Al Lay- ered Double Hydroxide Supported on Graphite and Biochar Toward Adsorption of Congo Red. Science and Technology Indonesia, 6(2); 85–95
Zhang, A., W. Chen, Z. Gu, Q. Li, and G. Shi (2018). Mecha- nism of Adsorption of Humic Acid by Modified Aged Refuse. RSC Advances, 8(59); 33642–33651
Zhang, L., F. He, W. Mao, and Y. Guan (2020). Fast and Effi- cient Removal of Cr(VI) to ppb Level Together with Cr(III) Sequestration in Water using Layered Double Hydroxide Interclated with Diethyldithiocarbamate. Science of The Total Environment, 727; 138701
Zhang, Y., J. Zhao, Z. Jiang, D. Shan, and Y. Lu (2014). Biosorption of Fe (II) and Mn (II) Ions from Aqueous So- lution by Rice Husk Ash. Biomed Research International, 2; 1–10
Zubair, M., I. Ihsanullah, H. A. Aziz, M. A. Ahmad, and M. A. Al-Harthi (2021). Sustainable Wastewater Treat- ment by Biochar/Layered Double Hydroxide Composites: Progress, Challenges, and Outlook. Bioresource Technology, 319; 124128
Amin, M., A. Alazba, and M. Shafiq (2020). LDH of NiZnFe and Its Composites with Carbon Nanotubes and Data Palm Biochar with Efficient Adsorption Capacity for RB5 Dye from Aqueous Solutions: Isotherm, Kinetic, and Thermody- namics Studies. Current Applied Physics, 2(1); 1–11
Bolbol, H., M. Fekri, and M. Hejazi-Mehrizi (2019). Layered Double Hydroxide Loaded Biochar as a Sorbent for The Removal of Aquatic Phosphorus: Behavior and Mechanism Insights. Arabian Journal of Geosciences, 12(16); 1–11
Chen, W., Y. Shen, Y. Ling, Y. Peng, M. Ge, and Z. Pan (2019). Synthesis of Positively Charged Polystyrene Microspheres for The Removal of Congo Red, Phosphate, and Chromium (VI). ACS Omega, 4(4); 6669–6676
Chen, Y. X., R. Zhu, Q. F. Ke, Y. S. Gao, C. Q. Zhang, and Y. P. Guo (2017). MgAl Layered Double Hydroxide/Chitosan Porous Scaffolds Loaded with PFTα to Promote Bone Re- generation. Nanoscale, 9(20); 6765–6776
El-Sherif, I., N. Fathy, A and A. Hanna (2013). Removal of Mn (II) and Fe (II) Ions from Aqueous Solution using Precipitation and Adsorption Methods. Journal of Applied Sciences Research, 9(1); 233–239
Gadekar, M. R. and M. M. Ahammed (2016). Coagula- tion/Flocculation Process for Dye Removal Using Water Treatment Residuals: Modelling Through Artificial Neural Networks. Desalination and Water Treatment, 57(55); 26392– 26400
Hasan, I., D. Bhatia, S. Walia, and P. Singh (2020). Removal of Malachite Green by Polyacrylamide-G-Chitosan γ-Fe2O3 Nanocomposite an Application of Central Composite De- sign. Groundwater for Sustainable Development, 11(4); 1–12
Hatami, H., A. Fotovat, and A. Halajnia (2018). Comparison of Adsorption and Desorption of Phosphate on Synthesized Zn-Al LDH by Two Methods in a Simulated Soil Solution. Applied Clay Science, 152; 333–341
Helal, A. A., G. Murad, and A. Helal (2011). Characterization of Different Humic Materials by Various Analytical Tech- niques. Arabian Journal of Chemistry, 4(1); 51–54
Hosseinzadeh, H. and S. Ramin (2018). Effective Removal of Copper from Aqueous Solutions by Modified Magnetic Chitosan/Graphene Oxide Nanocomposites. International Journal of Biological Macromolecules, 113; 859–868
Hu, H., S. Wageh, A. A. Al-Ghamdi, S. Yang, Z. Tian, B. Cheng, and W. Ho (2020). NiFe-LDH Nanosheet/Carbon Fiber Nanocomposite with Enhanced Anionic Dye Adsorp- tion Performance. Applied Surface Science, 511; 145570
Huang, Z., T. Wang, M. Shen, Z. Huang, Y. Chong, and L. Cui (2019). Coagulation Treatment of Swine Wastewater by The Method of in situ Forming Layered Double Hydroxides and Sludge Recycling for Preparation of Biochar Composite Catalyst. Chemical Engineering Journal, 369; 784–792
Lee, S. Y., J. W. Choi, K. G. Song, K. Choi, Y. J. Lee, and K.W. Jung (2019). Adsorption and Mechanistic Study for Phos- phate Removal by Rice Husk Derived Biochar Functional- ized with Mg/Al-Calcined Layered Double Hydroxides Via Co-Pyrolysis. Composites Part B: Engineering, 176; 107209
Li, S., Y. Yang, S. Huang, Z. He, C. Li, D. Li, B. Ke, C. Lai, and Q. Peng (2020a). Adsorption of Humic Acid from Aque- ous Solution by Magnetic Zn/Al Calcined Layered Double Hydroxides. Applied Clay Science, 188(3); 1–10
Li, Z., H. Hanafy, L. Zhang, L. Sellaoui, M. S. Netto, M. L.Oliveira, M. K. Seliem, G. L. Dotto, A. Bonilla-Petriciolet, and Q. Li (2020b). Adsorption of Congo Red and Methylene Blue Dyes on an Ashitaba Waste and a Walnut Shell Based Activated Carbon from Aqueous Solutions: Experiments, Characterization and Physical Interpretations. Chemical En- gineering Journal, 388; 124263
Mahjoubi, F. Zahra, A. Khalidi, A. Elhalil, R. Elmoubarki, O. Cherkaoui, S. Mhamed, and N. Barka (2017). Perfor- mance of Zn-, Mg- and Ni-Al Layered Double Hydroxides in Treating an Industrial Textile Wastewater. Journal of Ap- plied Surfaces and Interfaces, 2(3); 1–11
Marques, B. S., K. Dalmagro, K. S. Moreira, M. L. Oliveira, S. L. Jahn, T. A. de Lima Burgo, and G. L. Dotto (2020). Ca- Al, Ni-Al and Zn-Al LDH Powders as Efficient Materials to Treat Synthetic Effluents Containing o-nitrophenol. Journal of Alloys and Compounds, 838; 155628
Normah, N., N. Juleanti, P. M. S. B. N. Siregar, A. Wijaya, N. R. Palapa, T. Taher, and A. Lesbani (2021). Size Selec- tivity of Anionic and Cationic Dyes Using LDH Modified Adsorbent with Low-Cost Rambutan Peel to Hydrochar. Bulletin of Chemical Reaction Engineering & Catalysis, 16(4); 869–880
Palapa, N. R., T. Taher, P. M. S. B. N. Siregar, N. Normah, N. Juleanti, A. Wijaya, A. F. Badri, and A. Lesbani (2021). High Structural Stability and Adsorption Capacity of Zn/Al- Biochar and Cu/Al-Biochar Toward Adsorption of Cr(VI). Journal of Ecological Engineering, 22(4); 213–223
Rahmadan, J., V. Parhusip, N. R. Palapa, T. Taher, R. Mo- hadi, and A. Lesbani (2021). ZnAl-Humic Acid Composite as Adsorbent of Cadmium(II) from Aqueous Solution. Sci- ence and Technology Indonesia, 6(4); 247–255
Rahmanian, O., M. Dinari, and S. Neamati (2018). Synthesisand Characterization of Citrate Intercalated Layered Double Hydroxide as a Green Adsorbent for Ni2+ And Pb2+ Re- moval. Environmental Science and Pollution Research, 25(36); 36267–36277
Saheed, I. O., O. W. Da, and F. B. M. Suah (2020). Chi- tosan Modifications for Adsorption of Pollutants. Journal of Hazardous Materials, 408; 124889
Shrestha, S. L. (2018). Study of the Adsorption Kinetics of Iron Ion from Wastewater Using Banana Peel. International Journal of Advanced Research Chemical Science, 5(3); 1–8
Siregar, P. M. S. B. N., N. R. Palapa, A. Wijaya, E. S. Fitri, and A. Lesbani (2021). Structural Stability of Ni/Al Lay- ered Double Hydroxide Supported on Graphite and Biochar Toward Adsorption of Congo Red. Science and Technology Indonesia, 6(2); 85–95
Zhang, A., W. Chen, Z. Gu, Q. Li, and G. Shi (2018). Mecha- nism of Adsorption of Humic Acid by Modified Aged Refuse. RSC Advances, 8(59); 33642–33651
Zhang, L., F. He, W. Mao, and Y. Guan (2020). Fast and Effi- cient Removal of Cr(VI) to ppb Level Together with Cr(III) Sequestration in Water using Layered Double Hydroxide Interclated with Diethyldithiocarbamate. Science of The Total Environment, 727; 138701
Zhang, Y., J. Zhao, Z. Jiang, D. Shan, and Y. Lu (2014). Biosorption of Fe (II) and Mn (II) Ions from Aqueous So- lution by Rice Husk Ash. Biomed Research International, 2; 1–10
Zubair, M., I. Ihsanullah, H. A. Aziz, M. A. Ahmad, and M. A. Al-Harthi (2021). Sustainable Wastewater Treat- ment by Biochar/Layered Double Hydroxide Composites: Progress, Challenges, and Outlook. Bioresource Technology, 319; 124128
Authors
Siregar, P. M. S. B. N., Wijaya, A., Amri, Nduru, J. P., Hidayati, N., Lesbani, A., & Mohadi, R. (2022). Layered Double Hydroxide/C (C=Humic Acid;Hydrochar) As Adsorbents of Cr(VI). Science and Technology Indonesia, 7(1), 41–48. https://doi.org/10.26554/sti.2022.7.1.41-48
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