Malachite Green Dye Adsorption from Aqueous Solution using a Ni/Al Layered Double Hydroxide-Graphene Oxide Composite Material

Amri Amri, Aldes Lesbani, Risfidian Mohadi


Ni/Al layered double hydroxide and Ni/Al-graphene oxide composite materials were created using the coprecipitation method. The materials were successfully synthesized and prepared using XRD, FT-IR, and BET studies. The optimal pH as a result of malachite green dye adsorption is pH 4. The kinetics models of all materials follow the pseudo second order model. After being composited with graphene oxide, the maximum adsorption capacity of Ni/Al layered double hydroxide increased from 99.010 to 111.111 mg/g. All materials’ isotherm models adhere to the Langmuir isotherm model. The adsorption process was endothermic and spontaneous. The Ni/Al-graphene oxide composite material has a more stable structure than the Ni/Al layered double hydroxide. The regeneration procedure was repeated five times, and the Ni/Al-graphene oxide composite material did not show a significant decrease until the
fifth cycle, when it dropped from 97.561 to 77.046%, however the Ni/Al layered double hydroxide material dropped rapidly from 85.00 to 5.667%.


Ahmad, N., F. S. Arsyad, I. Royani, and A. Lesbani (2023a). Charcoal Activated as Template Mg/Al Layered Double Hydroxide for Selective Adsorption of Direct Yellow on Anionic Dyes. Results in Chemistry, 5; 100766

Ahmad, N., F. S. Arsyad, I. Royani, P. M. S. B. N. Siregar, T. Taher, and A. Lesbani (2023b). High Regeneration of ZnAl/NiAl-Magnetite Humic Acid for Adsorption of Congo Red from Aqueous Solution. Inorganic Chemistry Communications, 150; 110517

Dey, B., L. Dipty, and S. Dey (2018). Efficient Removal of Malachite Green using Saal (Shorea robusta) Flower from Contaminated Water. International Journal of Green and Herbal Chemistry, 7(2); 392–405

Giri, B. S., R. K. Sonwani, S. Varjani, D. Chaurasia, T. Varadavenkatesan, P. Chaturvedi, S. Yadav, V. Katiyar, R. S. Singh, and A. Pandey (2022). Highly Efficient Bio-Adsorption of Malachite Green using Chinese Fan-Palm Biochar (Livistona chinensis). Chemosphere, 287; 132282

Guechi, E. K. and O. Hamdaoui (2016). Sorption of Malachite Green from Aqueous Solution by Potato Peel: Kinetics and Equilibrium Modeling using Non-Linear Analysis Method. Arabian Journal of Chemistry, 9; S416–S424

Heshami, M., Z. Tavangar, and B. Taheri (2023). Adsorption of Gold and Silver Glycinate on Graphene and Graphene Oxide Surface: A DFT Study. Applied Surface Science, 619; 156676

Hong, X., R. Mu, T. Lin, L. Dao, S. Wu, Z. Yan, and J. Pang (2023). Preparation of Konjac Glucomannan/ZIF-67 Hybrid Aerogel and its Adsorption Properties for Malachite Green. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 657; 130418

Hu, Z., L. Cai, J. Liang, X. Guo, W. Li, and Z. Huang (2019). Green Synthesis of Expanded Graphite/Layered Double Hydroxides Nanocomposites and their Application in Adsorption Removal of Cr(VI) from Aqueous Solution. Journal of Cleaner Production, 209; 1216–1227

Li, L., K. San Hui, K. N. Hui, and Y.-R. Cho (2017). Ultrathin Petal-Like NiAl Layered Double Oxide/Sulfide Composites as an Advanced Electrode for High-Performance Asymmetric Supercapacitors. Journal of Materials Chemistry A, 5(37); 19687–19696

Lv, H. W., H. L. Jiang, F. A. He, Q. D. Hu, Z. R. Zhong, and Y. Y. Yang (2022). Adsorption of Anionic
and Cationic Dyes by a Novel Crosslinked Cellulose-Tetrafluoroterephthalonitrile-Tannin Polymer. European Polymer Journal, 180; 111602

Mallakpour, S., E. Azadi, and M. Dinari (2023). Removal of Cationic and Anionic Dyes using Ca-Alginate and Zn-Al Layered Double Hydroxide/Metal-Organic Framework. Carbohydrate Polymers, 301; 120362

NirmalaDevi, V., M. Makeswari, T. Santhi, et al. (2018). Malachite Green Dye Degradation using ZnCl2 Activated Ricinus communis Stem by Sunlight Irradiation. Rasayan Journal of¯Chemistry, 11(1); 219–227

Normah, N., N. R. Palapa, T. Taher, R. Mohadi, H. P. Utami, and A. Lesbani (2021). The Ability of Composite Ni/Al-Carbon Based Material Toward Readsorption of Iron(II) in Aqueous Solution. Science and Technology Indonesia, 6(3); 156–165

Pavlovic, M., A. Szerlauth, S. Muráth, G. Varga, and I. Szilagyi (2022). Surface Modification of Two-Dimensional Layered Double Hydroxide Nanoparticles with Biopolymers for Biomedical Applications. Advanced Drug Delivery Reviews, 191; 114590

Putranto, A., Z. W. Ng, T. Hadibarata, M. Aziz, J. Y. J. Yeo, S. Ismadji, and J. Sunarso (2022). Effects of Pyrolysis Temperature and Impregnation Ratio on Adsorption Kinetics and Isotherm of Methylene Blue on Corn Cobs Activated Carbons. South African Journal of Chemical Engineering, 42; 91–97

Rashed, S. H., A. Abd-Elhamid, S. Y. H. Abdalkarim, R. H. ElSayed, A. A. El-Bardan, H. M. Soliman, and A. Nayl (2022). Preparation and Characterization of Layered-Double Hydroxides Decorated on Graphene Oxide for Dye Removal from Aqueous Solution. Journal of Materials Research and Technology, 17; 2782–2795

Santosa, S. J., P. A. Krisbiantoro, T. T. M. Ha, N. T. T. Phuong, and G. Gusrizal (2021). Composite of Magnetite and Zn/Al Layered Double Hydroxide as a Magnetically Separable Adsorbent for Effective Removal of Humic Acid. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 614; 126159

Shi, M., Z. Zhao, Y. Song, M. Xu, J. Li, and L. Yao (2020). A Novel Heat-Treated Humic Acid/MgAl Layered Double Hydroxide Composite for Efficient Removal of Cadmium: Fabrication, Performance and Mechanisms. Applied Clay Science, 187; 105482

Valeikiene, L., R. Paitian, I. Grigoraviciute-Puroniene, K. Ishikawa, and A. Kareiva (2019). Transition Metal Substitution Effects in Sol-Gel Derived Mg3-xMx/Al1 (M= Mn, Co, Ni, Cu, Zn) Layered Double Hydroxides. Materials Chemistry and Physics, 237; 121863

Vigneshwaran, S., P. Sirajudheen, P. Karthikeyan, and S. Meenakshi (2021). Fabrication of Sulfur Doped Biochar Derived from Tapioca Peel Waste with Superior Adsorption Performance for the Removal of Malachite Green and Rhodamine B Dyes. Surfaces and Interfaces, 23; 100920

Wang, G., W. Su, B. Hu, A. A. Al-Huqail, H. S. Majdi, J. S. Algethami, Y. Jiang, and H. E. Ali (2022). Assessment in Carbon-Based Layered Double Hydroxides for Water and Wastewater: Application of Artificial Intelligence and Recent Progress. Chemosphere, 308(P3); 136303

Wijaya, A., P. M. S. B. N. Siregar, A. Priambodo, N. R. Palapa, T. Taher, and A. Lesbani (2021). Innovative Modified of Cu-Al/C (C= Biochar, Graphite) Composites for Removal ofProcion Red from Aqueous Solution. Science and Technology Indonesia, 6(4); 228–234

Yan, J., K. Li, J. Yan, Y. Fang, and B. Liu (2022). A Magnetically Recyclable Magnetic Graphite Oxide Composite Functionalized with Polydopamine and ???? -Cyclodextrin for Cationic Dyes Wastewater Remediation: Investigation on Adsorption Performance, Reusability and Adsorption Mechanism. Applied Surface Science, 602; 154338

Zhang, H., Y. Liu, T. Feng, S. Zhao, and W. Qiao (2023). Optical Modulation Properties of the Ni Based Layered Double Hydroxides for Dual-Wavelength Q-switched Er: YAP Laser at 2.7 ????m. Optical Materials, 137; 113499

Zhang, P., D. O’Connor, Y. Wang, L. Jiang, T. Xia, L. Wang, D. C. Tsang, Y. S. Ok, and D. Hou (2020). A Green Biochar/Iron Oxide Composite for Methylene Blue Removal. Journal of Hazardous Materials, 384; 121286

Zubair, M., H. A. Aziz, I. Ihsanullah, M. A. Ahmad, and M. A. Al-Harthi (2022). Engineered Biochar Supported Layered Double Hydroxide-Cellulose Nanocrystals Composite : Synthesis, Characterization and Azo Dye Removal Performance. Chemosphere, 307; 136054


Amri Amri
Aldes Lesbani
Risfidian Mohadi (Primary Contact)
Amri, A., Lesbani, A., & Mohadi, R. (2023). Malachite Green Dye Adsorption from Aqueous Solution using a Ni/Al Layered Double Hydroxide-Graphene Oxide Composite Material. Science and Technology Indonesia, 8(2), 280–287.

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