Innovative Modified of Cu-Al/C (C = Biochar, Graphite) Composites for Removal of Procion Red from Aqueous Solution
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Keywords:
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Composites, Adsorption, Procion Red Dye, Selectivity, Structural Stability
Abstract
Innovative modification of Cu-Al/C composites was synthesized by coprecipitation method at pH 10 and added biochar (BC) and graphite (GF) to form Cu-Al/BC and Cu-Al/GF composites. Pristine and composites were characterized by XRD, FT-IR, Thermalgravimetric, and surface area using the BET method. The XRD diffraction and FTIR spectrum of Cu-Al/BC and Cu-Al/GF showed that the composite material from LDH, biochar, and graphite was successfully prepared. Modified LDH were surface area higher than the pristine, which obtained 200.90 m2/g and 18.83 m2/g for Cu-Al/BC and Cu-Al/GF respectively. Cu-Al/BC and Cu-Al/GF were tested for selectivity on several anionic dyes, it was known that procion red (PR) dye was more easily adsorbed than other anionic dyes. Materials were applied as adsorbents of procion red (PR) dye. The advantages of composites were evaluated by the regeneration process of adsorbent on PR. The result of composite toward PR re-adsorption process showed that Cu-Al/BC and Cu-Al/GF had structural stability higher than starting materials until five cycles process. Furthermore, materials were applied as adsorbents of procion red (PR) dye. The maximum adsorption capacity obtained was 93.458 mg/g for Cu-Al/BC and 49.505 mg/g for Cu-Al/GF. Both innovative modified composites have shown effective adsorbents to the removal of PR from an aqueous solution.
References
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Palapa, N. R., B. R. Rahayu, T. Taher, A. Lesbani, and R. Mohadi (2019). Kinetic Adsorption of Direct Yellow Onto
Zn/Al and Zn/Fe Layered Double Hydroxides. Science and Technology Indonesia, 4(4); 101–104
Palapa, N. R., T. Taher, B. R. Rahayu, R. Mohadi, A. Rachmat, and A. Lesbani (2020b). CuAl LDH/Rice husk biochar composite for enhanced adsorptive removal of cationic dye from aqueous solution. Bulletin of Chemical Reaction Engineering and Catalysis, 15(2); 525–537
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Sarkar, S., A. Banerjee, U. Halder, R. Biswas, and R. Bandopadhyay (2017). Degradation of synthetic azo dyes of
textile industry: a sustainable approach using microbial enzymes. Water Conservation Science and Engineering, 2(4); 121–131
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thermodynamic parameters. Water, Air, and Soil Pollution, 229(10); 1–17
Shi, Q.-X., Y. Li, L. Wang, J. Wang, and Y.-L. Cao (2020). Preparation of supported chitosan adsorbent with high adsorption capacity for Titan Yellow removal. International Journal of Biological Macromolecules, 152; 449–455
Siregar, P. M. S. B. N., N. R. Palapa, A. Wijaya, E. S. Fitri, and A. Lesbani (2021). Structural stability of Ni/Al layered
double hydroxide supported on graphite and biochar toward adsorption of congo red. Science and Technology Indonesia, 6(2); 85–95
Streit, A. F., L. N. Côrtes, S. P. Druzian, M. Godinho, G. C. Collazzo, D. Perondi, and G. L. Dotto (2019). Development
of high quality activated carbon from biological sludge and its application for dyes removal from aqueous solutions. Science of The Total Environment, 660; 277–287
Tang, R., Y. Wang, S. Yuan, W. Wang, Z. Yue, X. Zhan, and Z.-H. Hu (2020). Organoarsenic feed additives in biological
wastewater treatment processes: Removal, biotransformation, and associated impacts. Journal of Hazardous Materials; 124789
Valencia, S., M. Pascua, J. Movillon, and H. Braza (2001). Adsorption of basic rhodamine red, basic methylene blue,
reactive procion red, and reactive procion blue textile dyes by cornstalk. Philippine Agricultural Scientist (Philippines), 84(3); 304–312
Zhang, M., Q. Yao, C. Lu, Z. Li, and W. Wang (2014). Layered double hydroxide–carbon dot composite: high-performance adsorbent for removal of anionic organic dye. ACS Applied Materials and Interfaces, 6(22); 20225–20233
Zhao, J., Q. Huang, M. Liu, Y. Dai, J. Chen, H. Huang, Y. Wen, X. Zhu, X. Zhang, and Y. Wei (2017). Synthesis of functionalized MgAl-layered double hydroxides via modied mussel inspired chemistry and their application in organic dye adsorption. Journal of Colloid and Interface Science, 505; 168–177
Composite with Stable Structure for Malachite Green Adsorption from Aqueous Solutions. Bulletin of Chemical Reaction Engineering and Catalysis, 16(1); 149–160
Demissie, H., G. An, R. Jiao, T. Ritigala, S. Lu, and D. Wang (2021). Modication of high content nanocluster-based coagulation for rapid removal of dye from water and the mechanism. Separation and Purication Technology, 259; 117845
Eltaweil, A., H. A. Mohamed, E. M. Abd El-Monaem, and G. El-Subruiti (2020). Mesoporous magnetic biochar composite for enhanced adsorption of malachite green dye: Characterization, adsorption kinetics, thermodynamics and isotherms. Advanced Powder Technology, 31(3); 1253–1263
Heraldy, E., R. R. Osa, and V. Suryanti (2016). Adsorption of Procion Red MX 8B using spent tea leaves as adsorbent.
AIP Conference Proceedings, 1710(1); 30025
Hu, S.-H. and S.-C. Hu (2014). Application of magnetically modied sewage sludge ash (SSA) in ionic dye adsorption.
Journal of the Air and Waste Management Association, 64(2); 141–149
Hua, P., L. Sellaoui, D. Franco, M. S. Netto, G. L. Dotto, A. Bajahzar, H. Belmabrouk, A. Bonilla-Petriciolet, and Z. Li (2020). Adsorption of acid green and procion red on a magnetic geopolymer based adsorbent: Experiments, characterization and theoretical treatment. Chemical Engineering Journal, 383; 123113
Juleanti, N., N. R. Palapa, T. Taher, N. Hidayati, B. I. Putri, and A. Lesbani (2021). The Capability of Biochar-Based
CaAl and MgAl Composite Materials as Adsorbent for Removal Cr(VI) in Aqueous Solution. Science and Technology
Indonesia, 6(3); 196–203
Kumar, S. G. and K. K. Rao (2017). Comparison of modication strategies towards enhanced charge carrier separation and photocatalytic degradation activity of metal oxide semiconductors (TiO2, W O3 and ZnO). Applied Surface Science, 391; 124–148
Kusrini, E., A. Suhrowati, A. Usman, M. Khalil, and V. Degirmenci (2019). Synthesis and characterization of graphite
oxide, graphene oxide and reduced graphene oxide from graphite waste using modied Hummers’s method and zinc as reducing agent. Synthesis, 10(6); 1093–1104
Lellis, B., C. Z. Fávaro-Polonio, J. A. Pamphile, and J. C. Polonio (2019). Eects of textile dyes on health and the environment and bioremediation potential of living organisms. Biotechnology Research and Innovation, 3(2); 275–290
Mcyotto, F., Q. Wei, D. K. Macharia, M. Huang, C. Shen, and C. W. Chow (2021). Eect of dye structure on color removal e ciency by coagulation. Chemical Engineering Journal, 405;
126674
Mohammad, S., I. Suzylawati, et al. (2020). Study of the adsorption/desorption of MB dye solution using bentonite
adsorbent coating. Journal of Water Process Engineering, 34; 101155
Mustapha, S., M. Ndamitso, A. Abdulkareem, J. Tijani, A. Mohammed, and D. Shuaib (2019). Potential of using kaolin
as a natural adsorbent for the removal of pollutants from tannery wastewater. Heliyon, 5(11); 2923
Namasivayam, C. and S. Sumithra (2006). Adsorption of anionic dyes on to waste Fe (III)/Cr (III). Journal of Environmental Science and Engineering, 48(1); 69–74
Natarajan, S., V. Anitha, G. P. Gajula, and V. Thiagarajan (2020). Synthesis and characterization of magnetic superadsorbent F e3O4-PEG-Mg-Al-LDH nanocomposites for ultrahigh removal of organic dyes. ACS Omega, 5(7); 3181–3193
Nazifa, T. H., N. Habba, A. Aris, and T. Hadibarata (2018). Adsorption of Procion Red MX-5B and Crystal Violet Dyes
from Aqueous Solution onto Corncob Activated Carbon. Journal of the Chinese Chemical Society, 65(2); 259–270
Nor, N. M., T. Hadibarata, Z. Yusop, and Z. M. Lazim (2015). Removal of brilliant green and procionred dyes from aqueous solutionby adsorption using selected agricultural wastes. Jurnal Teknologi, 74(11); 11
Normah, N. R. Palapa, T. Taher, R. Mohadi, H. P. Utami, and A. Lesbani (2021). The Ability of Composite Ni/Al-carbon
based Material Toward Readsorption of Iron(II) in Aqueous Solution. Science and Technology Indonesia, 6(3); 156–165
Oliveira, E., S. Montanher, and M. Rollemberg (2011). Removal of textile dyes by sorption on low-cost sorbents. A
case study: sorption of reactive dyes onto Lua cylindrica. Desalination and Water Treatment, 25(1-3); 54–64
Palapa, N. R., N. Juleanti, N. Normah, T. Taher, and A. Lesbani (2020a). Unique adsorption properties of malachite
green on interlayer space of Cu-Al and Cu-Al-SiW12O40 layered double hydroxides. Bulletin of Chemical Reaction Engineering and Catalysis, 15(3); 653–661
Palapa, N. R., R. Mohadi, and A. Lesbani (2018). Adsorption of direct yellow dye from aqueous solution by Ni/Al and
Zn/Al layered double hydroxides. AIP Conference Proceedings, 2026(1); 20018
Palapa, N. R., B. R. Rahayu, T. Taher, A. Lesbani, and R. Mohadi (2019). Kinetic Adsorption of Direct Yellow Onto
Zn/Al and Zn/Fe Layered Double Hydroxides. Science and Technology Indonesia, 4(4); 101–104
Palapa, N. R., T. Taher, B. R. Rahayu, R. Mohadi, A. Rachmat, and A. Lesbani (2020b). CuAl LDH/Rice husk biochar composite for enhanced adsorptive removal of cationic dye from aqueous solution. Bulletin of Chemical Reaction Engineering and Catalysis, 15(2); 525–537
Quesada, H. B., T. P. de Araujo, D. T. Vareschini, M. A. S. D. de Barros, R. G. Gomes, and R. Bergamasco (2020). Chitosan, alginate and other macromolecules as activated carbon immobilizing agents: a review on composite adsorbents for the removal of water contaminants. International Journal of Biological Macromolecules, 164; 2535–2549
Sarkar, S., A. Banerjee, U. Halder, R. Biswas, and R. Bandopadhyay (2017). Degradation of synthetic azo dyes of
textile industry: a sustainable approach using microbial enzymes. Water Conservation Science and Engineering, 2(4); 121–131
Sarma, G. K., S. SenGupta, and K. G. Bhattacharyya (2018). Adsorption of monoazo dyes (Crocein Orange G and Procion Red MX5B) from water using raw and acid-treated montmorillonite K10: insight into kinetics, isotherm, and
thermodynamic parameters. Water, Air, and Soil Pollution, 229(10); 1–17
Shi, Q.-X., Y. Li, L. Wang, J. Wang, and Y.-L. Cao (2020). Preparation of supported chitosan adsorbent with high adsorption capacity for Titan Yellow removal. International Journal of Biological Macromolecules, 152; 449–455
Siregar, P. M. S. B. N., N. R. Palapa, A. Wijaya, E. S. Fitri, and A. Lesbani (2021). Structural stability of Ni/Al layered
double hydroxide supported on graphite and biochar toward adsorption of congo red. Science and Technology Indonesia, 6(2); 85–95
Streit, A. F., L. N. Côrtes, S. P. Druzian, M. Godinho, G. C. Collazzo, D. Perondi, and G. L. Dotto (2019). Development
of high quality activated carbon from biological sludge and its application for dyes removal from aqueous solutions. Science of The Total Environment, 660; 277–287
Tang, R., Y. Wang, S. Yuan, W. Wang, Z. Yue, X. Zhan, and Z.-H. Hu (2020). Organoarsenic feed additives in biological
wastewater treatment processes: Removal, biotransformation, and associated impacts. Journal of Hazardous Materials; 124789
Valencia, S., M. Pascua, J. Movillon, and H. Braza (2001). Adsorption of basic rhodamine red, basic methylene blue,
reactive procion red, and reactive procion blue textile dyes by cornstalk. Philippine Agricultural Scientist (Philippines), 84(3); 304–312
Zhang, M., Q. Yao, C. Lu, Z. Li, and W. Wang (2014). Layered double hydroxide–carbon dot composite: high-performance adsorbent for removal of anionic organic dye. ACS Applied Materials and Interfaces, 6(22); 20225–20233
Zhao, J., Q. Huang, M. Liu, Y. Dai, J. Chen, H. Huang, Y. Wen, X. Zhu, X. Zhang, and Y. Wei (2017). Synthesis of functionalized MgAl-layered double hydroxides via modied mussel inspired chemistry and their application in organic dye adsorption. Journal of Colloid and Interface Science, 505; 168–177
Authors
Wijaya, A., Bahar Nur Siregar, P. M. S., Priambodo, A. ., Palapa, N. R. ., Taher, T., & Lesbani, A. (2021). Innovative Modified of Cu-Al/C (C = Biochar, Graphite) Composites for Removal of Procion Red from Aqueous Solution . Science and Technology Indonesia, 6(4), 228–234. https://doi.org/10.26554/sti.2021.6.4.228-234
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