The Capability of Biochar-Based CaAl and MgAl Composite Materials as Adsorbent for Removal Cr(VI) in Aqueous Solution
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Keywords:
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Adsorption, Cr6 , Regeneration, Selectivity, Biochar, Layared Double Hydroxide
Abstract
The development of layered double hydroxide materials into composites with carbon-based materials in the form of CaAl-Biochar and MgAl-Biochar has been successfully carried out. The success parameters of the preparation process include XRD, FT-IR, Adsorption-Desorption N2, SEM, and TG-DTA. The success through XRD is evidenced by the appearance of the typical diffraction peaks of double-layer hydroxy around 2???? = 11°(003), 20°(006), and 60°(113). In addition, there is diffraction around 22°(002) which is the typical diffraction of biochar. FT-IR analysis showed successful preparation in the presence of functional groups around 1381cm−1 which indicated nitrate vibrations from double-layer hydroxy. Another spectrum that also appears on 1103 cm−1 is a characteristic of biochar (???? Si-O-Si). Adsorption-Desorption N2 analysis showed that the surface area data of 2 −1 2 −1 CaAl-Biochar was greater than MgAl-Biochar, which were 150.987 m .g and 111,404 m .g , respectively. The adsorption capacity of CaAl-Biochar reached 588.235 mg.g−1 and 426.316 mg.g−1 for MgAl-Biochar. The adsorbent materials of CaAl, MgAl, Biochar, CaAl-Biochar, and MgAl-Biochar tend to follow the Langmuir isotherm model with adsorption processes that tend to be spontaneous. The results of regeneration of the composite material lasted up to 5 cycles. The first cycle of CaAl-Biochar reached 96.647% to 82.666% in the last cycle, while MgAl-Biochar reached 90.885% in the first cycle to 73.454% in the last cycle.
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Ashiq, A., N. M. Adassooriya, B. Sarkar, A. U. Rajapaksha, Y. S.Ok, and M. Vithanage (2019). Municipal solid waste biocharbentonite composite for the removal of antibiotic cipro oxacin from aqueous media. Journal of environmental management, 236; 428–435
Badri, A. F., P. M. S. B. N. Siregar, N. R. Palapa, R. Mohadi, M. Mardiyanto, and A. Lesbani (2021). Mg-Al/Biochar Composite with Stable Structure for Malachite Green Adsorption from Aqueous Solutions. Bulletin of Chemical Reaction Engineering & Catalysis, 16(1); 149–160
Chen, T., T. Da, and Y. Ma (2020). Reasonable calculation of the thermodynamic parameters from adsorption equilibrium constant. Journal of Molecular Liquids, 322; 114980
Hassan, M., Y. Liu, R. Naidu, S. J. Parikh, J. Du, F. Qi, and I. R. Willett (2020). In uences of feedstock sources and pyrolysis temperature on the properties of biochar and functionality as adsorbents: A meta-analysis. Science of The Total Environment; 140714
Heraldy, E., K. Nugrahaningtyas, et al. (2017). X-ray Di ractionAnalysis on Post Treatment of Ca-Mg-Al-Layered Double Hydroxide Slurry. In IOP Conference Series: Materials Science and Engineering, volume 176. IOP Publishing, page 012020
Huong, P. T., K. Jitae, T. Al Tahtamouni, N. L. M. Tri, H.-H. Kim, K. H. Cho, and C. Lee (2020). Novel activation of peroxymonosulfate by biochar derived from rice husk toward oxidation of organic contaminants in wastewater. Journal of Water Process Engineering, 33; 101037
Lee, S. Y., J.-W. Choi, K. G. Song, K. Choi, Y. J. Lee, and K.-W. Jung (2019a). Adsorption and mechanistic study for phosphate removal by rice husk-derived biochar functionalized with Mg/Al-calcined layered double hydroxides via co-pyrolysis. Composites Part B: Engineering, 176; 107209
Lee, S. Y., J.-W. Choi, K. G. Song, K. Choi, Y. J. Lee, and K.-W. Jung (2019b). Adsorption and mechanistic study for phosphate removal by rice husk-derived biochar functionalized with Mg/Al-calcined layered double hydroxides via co-pyrolysis. Composites Part B: Engineering, 176; 107209
Lesbani, A., F. Asri, N. Palapa, T. Taher, and A. Rachmat (2020). E cient removal of methylene blue by adsorption using composite based Ca/Al layered double hydroxide-biochar. Global NEST Journal, 22(2); 250–257
Li, S., Y. Yang, S. Huang, Z. He, C. Li, D. Li, B. Ke, C. Lai, and Q. Peng (2020). Adsorption of humic acid from aqueous solution by magnetic Zn/Al calcined layered double hydroxides. Applied clay science, 188; 105414
Milagres, J. L., C. R. Bellato, R. S. Vieira, S. O. Ferreira, and C. Reis (2017). Preparation and evaluation of the Ca-Al layered double hydroxide for removal of copper (II), nickel (II), zinc (II), chromium (VI) and phosphate from aqueous solutions. Journal of environmental chemical engineering, 5(6); 5469–5480
Mohadi, R., N. R. Palapa, and A. Lesbani (2021). Preparation of Ca/Al-Layered Double Hydroxides/Biochar Composite with High Adsorption Capacity and Selectivity toward Cationic Dyes in Aqueous. Bulletin of Chemical Reaction Engineering & Catalysis, 16(2); 244–252
Onder, A., P. Ilgin, H. Ozay, and O. Ozay (2020). Removal of dye from aqueous medium with pH-sensitive poly [(2-
(acryloyloxy) ethyl] trimethylammonium chloride-co-1-vinyl2-pyrrolidone] cationic hydrogel. Journal of Environmental Chemical Engineering, 8(5); 104436
Palapa, N. R., N. Juleanti, N. Normah, T. Taher, and A. Lesbani (2020a). Unique Adsorption Properties of Malachite Green on Interlayer Space of Cu-Al and Cu-Al-SiW12O40 Layered Double Hydroxides. Bulletin of Chemical Reaction Engineering & Catalysis, 15(3); 653–661
Palapa, N. R., R. Mohadi, A. Rachmat, et al. (2020b). Adsorption study of malachite green removal from aqueous solution using Cu/M3+ (M3+= Al, Cr) layered double hydroxide. Mediterranean Journal of Chemistry, 10(1); 33–45
Palapa, N. R., T. Taher, B. R. Rahayu, R. Mohadi, A. Rachmat, and A. Lesbani (2020c). CuAl LDH/Rice Husk Biochar Composite for Enhanced Adsorptive Removal of Cationic Dye from Aqueous Solution. Bulletin of Chemical Reaction Engineering & Catalysis, 15(2); 525–537
Palapa, N. R., T. Taher, B. R. Rahayu, R. Mohadi, A. Rachmat, and A. Lesbani (2020d). CuAl LDH/Rice Husk Biochar Composite for Enhanced Adsorptive Removal of Cationic Dye from Aqueous Solution. Bulletin of Chemical Reaction Engineering & Catalysis, 15(2); 525–537
Pšenička, M., J. Škoda, and M. Pospíšil (2020). Structural arrangement and properties of layered double hydroxide drug nanocarrier intercalated by sulindac and mefenamic acid solved by molecular simulation methods. Applied Clay Science, 189; 105560
Rajapaksha, A. U., Y. S. Ok, A. El-Naggar, H. Kim, F. Song, S. Kang, and Y. F. Tsang (2019). Dissolved organic matter characterization of biochars produced from di erent feedstock materials. Journal of environmental management, 233; 393–399
Sahmoune, M. N. (2019). Evaluation of thermodynamic parameters for adsorption of heavy metals by green adsorbents. Environmental Chemistry Letters, 17(2); 697–704
Shaji, A. and A. K. Zachariah (2017). Surface area analysis of nanomaterials. Elsevier
Siregar, P. M. S. B. N., N. R. Palapa, A. Wijaya, E. S. Fitri, and A. Lesbani (2021). Structural stability of Ni/Al layered double hydroxide supported on graphite and biochar toward adsorption of congo red. Science and Technology Indonesia, 6(2); 85–95
Xue, X., J. Zhong, J. Liu, Z. Hou, X. Wu, S. Li, and M. Yu (2020). Hydrolysis of metal-organic framework towards threedimensional nickel cobalt-layered double hydroxide for high performance supercapacitors. Journal of Energy Storage, 31; 101649
Yang, L., Z. Liu, S. Zhu, L. Feng, and W. Xing (2020). Ni-based layered double hydroxide catalysts for oxygen evolution reaction. Materials Today Physics; 100292
Yang, X., A. Tsibart, H. Nam, J. Hur, A. El-Naggar, F. M. Tack,
C.-H. Wang, Y. H. Lee, D. C. Tsang, and Y. S. Ok (2019a). E ect
of gasication biochar application on soil quality: Trace metal
behavior, microbial community, and soil dissolved organic
matter. Journal of hazardous materials, 365; 684–694
Yang, X., I. K. Yu, D.-W. Cho, S. S. Chen, D. C. Tsang, J. Shang, A. C. Yip, L. Wang, and Y. S. Ok (2019b). Tin-functionalized wood biochar as a sustainable solid catalyst for glucose isomerization in biorenery. ACS Sustainable Chemistry & Engineering, 7(5); 4851–4860
Zhang, J., J. Jin, M. Wang, R. Naidu, Y. Liu, Y. B. Man, X. Liang,
M. H. Wong, P. Christie, Y. Zhang, et al. (2020). Co-pyrolysis of sewage sludge and rice husk/bamboo sawdust for biochar with high aromaticity and low metal mobility. Environmental Research, 191; 110034
Zhang, X., B. Gao, A. E. Creamer, C. Cao, and Y. Li (2017). Adsorption of VOCs onto engineered carbon materials: A review. Journal of hazardous materials, 338; 102–123
Authors
Juleanti, N., Palapa, N. R., Taher, T., Hidayati, N., Putri, B. I. ., & Lesbani, A. (2021). The Capability of Biochar-Based CaAl and MgAl Composite Materials as Adsorbent for Removal Cr(VI) in Aqueous Solution. Science and Technology Indonesia, 6(3), 196–203. https://doi.org/10.26554/sti.2021.6.3.196-203
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