Catalytic Oxidative Desulfurization of Dibenzothiophene by Composites Based Ni/Al-Oxide
Article Sidebar
Keywords:
-
Desulfurization, Dibenzothiophene, Layered Double Hydroxide, Composite
Abstract
In the present study, composite layer double hydroxide-metal oxide (Ni/Al-TiO2 and Ni/Al-ZnO) was successfully prepared and used as catalyst of oxidative desulfurization of dibenzothiophene. Characterization of catalyst was used XRD, FTIR, and SEM-EDS. The structure of Ni/Al-LDH, TiO2, and ZnO in composite Ni/Al-TiO2 and Ni/Al-ZnO was consistent, which also indicated that the preparation of composite did not change the form of precursors. FTIR spectra of Ni/Al-TiO2 and Ni/Al-ZnO absorption band at 3398, 1639, 1339, 832, 731, and 682 cm−1. The catalysts have an irregular structure, TiO2 and ZnO adhere to the surface of Ni/Al LDH. The percent mass of Ti and Zn on the composite at 29.3% and 18.2%, respectively. The acidity of Ni/Al LDH increased after being composited with TiO2 and ZnO. The optimum reaction time, dosage catalyst, and temperature were 30 min, 0.25 g, and 50°C, respectively, and n-hexane as a solvent. The percentage conversion of dibenzothiophene on Ni/Al-LDH, TiO2, ZnO, Ni/Al-TiO2, and Ni/Al-ZnO were 99.44%, 91.92%, 95.36%, 99.88%, and 99.90%, respectively. The catalysts are heterogeneous system and the advantage is that can be used for reusability. After 3 times catalytic reactions, the conversion of dibenzothiophene still retains more than 80%, even Ni/Al-TiO2 and Ni/Al-ZnO composites still 97.79% and 98.99%, respectively.
References
Abedini, F., S. Allahyari, and N. Rahemi (2021). Oxidative Desulfurization of Dibenzothiophene and Simultaneous Adsorption of Products on BiOBr-C3N4/MCM-41 Visible-Light-Driven Core–Shell Nano Photocatalyst. Applied Surface Science, 569; 151086
Basnet, P., D. Samanta, T. Inakhunbi Chanu, J. Mukherjee, and S. Chatterjee (2019). Assessment of Synthesis Approaches for Tuning The Photocatalytic Property of ZnO Nanoparticles. SN Applied Sciences, 1(6); 1–13
Bazyari, A., A. A. Khodadadi, A. H. Mamaghani, J. Beheshtian, L. T. Thompson, and Y. Mortazavi (2016). Microporous Titania–Silica Nanocomposite Catalyst-Adsorbent for Ultra-Deep Oxidative Desulfurization. Applied Catalysis B: Environmental, 180; 65–77
Chen, L., X. Yang, Y. Tian, Y. Wang, X. Zhao, X. Lei, and F. Zhang (2022). Fabrication of β-Ni(OH)2 Particles by Alkaline Etching Layered Double Hydroxides Precursor for Supercapacitor. Frontiers in Energy Research; 863
Dang, C., W. Yang, J. Zhou, and W. Cai (2021). Porous Ni-Ca-Al-O Bi-Functional Catalyst Derived from Layered Double Hydroxide Intercalated with Citrate Anion for SorptionEnhanced Steam Reforming of Glycerol. Applied Catalysis B: Environmental, 298; 120547
Fraile, J. M., C. Gil, J. A. Mayoral, B. Muel, L. Roldán, E. Vispe, S. Calderón, and F. Puente (2016). Heterogeneous Titanium Catalysts for Oxidation of Dibenzothiophene in Hydrocarbon Solutions with Hydrogen Peroxide: on The Road to Oxidative Desulfurization. Applied Catalysis B: Environmental, 180; 680–686
Gabriel, R., S. H. De Carvalho, J. L. da Silva Duarte, L. M. Oliveira, D. A. Giannakoudakis, K. S. Triantafyllidis, J. I. Soletti, and L. Meili (2021). Mixed Metal Oxides Derived from Layered Double Hydroxide as Catalysts for Biodiesel Production. Applied Catalysis A: General; 118470
Intachai, S., T. Nakato, and N. Khaorapapong (2021). ZnO Decorated on Low Carbonate NiAl-Layered Double Hydroxide as Efficient Photocatalyst for Methyl Orange Degradation. Applied Clay Science, 201; 105927
Kang, L., H. Liu, H. He, and C. Yang (2018). Oxidative Desulfurization of Dibenzothiophene Using Molybdenum Catalyst Supported on Ti-Pillared Montmorillonite and Separation of Sulfones by Filtration. Fuel, 234; 1229-1237
Karim, A. V., A. Hassani, P. Eghbali, and P. Nidheesh (2022). Nanostructured Modified Layered Double Hydroxides (LDHs)-Based Catalysts: a Review on Synthesis, Characterization, and Applications in Water Remediation by Advanced Oxidation Processes. Current Opinion in Solid State and Materials Science, 26(1); 100965
Lesbani, A., A. Agnes, V. Mariska, M. Risfidian, Z. Hilda (2015). Facile Oxidative Desulfurisation of Benzothiophene Using Polyoxometalate H4[????-SiW12O40]/Zr Catalyst. Bulletin of Chemical Reaction Engineering & Catalysis, 10(2); 185–191
Lesbani, A., N. R. Palapa, R. J. Sayeri, T. Taher, and N. Hidayati (2021). High Reusability of NiAl LDH/Biochar Composite in The Removal Methylene Blue from Aqueous Solution. Indonesian Journal of Chemistry, 21(2); 421–434
Li, S. W., W. Wang, and J. S. Zhao (2020). Catalytic Oxidation of DBT for Ultra-Deep Desulfurization Under MoO3 Modified Magnetic Catalyst: The Comparison Influence on Various Morphologies of MoO3. Applied Catalysis A: General, 602; 117671
Luna, M. L., M. A. Taboada-Ortega, M. A. Alvarez-Amparán, and L. Cedeño-Caero (2022). Effect of Iron Incorporation on W Based Catalysts for Oxidative Desulfurization of Dibenzothiophene Compounds. Catalysis Today, 394; 336–347
Lv, H., H. Rao, Z. Liu, Z. Zhou, Y. Zhao, H. Wei, and Z. Chen (2022). NiAl Layered Double Hydroxides with Enhanced Interlayer Spacing Via Ion-Exchange as Ultra-High Performance Supercapacitors Electrode Materials. Journal of Energy Storage, 52; 104940
Mahmoudi, V., A. M. Kermani, M. Ghahramaninezhad, and A. Ahmadpour (2021). Oxidative Desulfurization of Dibenzothiophene by Magnetically Recoverable Polyoxometalate-Based Nanocatalyst: Optimization by Response Surface Methodology. Molecular Catalysis, 509; 111611
Malani, R. S., A. H. Batghare, J. B. Bhasarkar, and V. S. Moholkar (2021). Kinetic Modelling and Process Engineering Aspects of Biodesulfurization of Liquid Fuels: Review and Analysis. Bioresource Technology Reports, 14; 100668
Masoumi, S. and S. A. Hosseini (2020). Desulfurization of DiBenzothiophene from Gasoil Model Using Ni-Co2, Ni-Fe2 and Co-Fe2 Nano Layered-Double Hydroxides as Photocatalysts Under Visible Light. Fuel, 277; 118137
Mgidlana, S., N. Nwahara, and T. Nyokong (2021). Photocatalytic Desulfurization of Dibenzothiophene Using Methoxy Substituted Asymmetrical Zinc(II) Phthalocyanines Conjugated to Metal Tungstate Nanomaterials. Polyhedron, 197; 115053
Mousavi-Kamazani, M., M. Ghodrati, and R. Rahmatolahzadeh (2020). Fabrication of Z-Scheme Flower-Like AgI/Bi2O3 Heterojunctions with Enhanced Visible Light Photocatalytic Desulfurization Under Mild Conditions. Journal of Materials Science: Materials in Electronics, 31(7); 5622–5634
Muhammad, Y., A. Shoukat, A. U. Rahman, H. U. Rashid, and W. Ahmad (2018). Oxidative Desulfurization of Dibenzothiophene Over Fe Promoted Co–Mo/Al2O3 and Ni–Mo/Al2O3 Catalysts Using Hydrogen Peroxide and Formic Acid as Oxidants. Chinese Journal of Chemical Engineering, 26(3); 593–600
Mujahid, A., A. Maryam, A. Afzal, S. Z. Bajwa, T. Hussain, M. I. Din, U. Latif, and M. Irshad (2020). Molecularly Imprinted Poly (Methyl Methacrylate)-Nickel Sulfide Hybrid Membranes for Adsorptive Desulfurization of Dibenzothiophene. Separation and Purification Technology, 237; 116453
Normah, N., N. R. Palapa, T. Taher, R. Mohadi, H. P. Utami, and A. Lesbani (2021). The Ability of Composite Ni/Al-Carbon Based Material Toward Readsorption of Iron(II) in Aqueous Solution. Science and Technology Indonesia, 6(3); 156–165
Palapa, N. R., T. Taher, A. Wijaya, and A. Lesbani (2021). Modification of Cu/Cr Layered Double Hydroxide by Keggin Type Polyoxometalate as Adsorbent of Malachite Green from Aqueous Solution. Science and Technology Indonesia, 6(3); 209–217
Ren, X., G. Miao, Z. Xiao, F. Ye, Z. Li, H. Wang, and J. Xiao (2016). Catalytic Adsorptive Desulfurization of Model Diesel Fuel Using TiO2/SBA-15 Under Mild Conditions. Fuel, 174; 118–125
Rezaee, M., F. Feyzi, and M. R. Dehghani (2021). Extractive Desulfurization of Dibenzothiophene from Normal Octane Using Deep Eutectic Solvents as Extracting Agent. Journal of Molecular Liquids, 333; 115991
Song, Y., J. Bai, S. Jiang, H. Yang, L. Yang, D. Wei, L. Bai, W. Wang, Y. Liang, and H. Chen (2021). Co-Fe-Mo Mixed Metal Oxides Derived from Layered Double Hydroxides for Deep Aerobic Oxidative Desulfurization. Fuel, 306; 121751
Subhan, S., A. U. Rahman, M. Yaseen, H. U. Rashid, M. Ishaq, M. Sahibzada, and Z. Tong (2019). Ultra-Fast and Highly Efficient Catalytic Oxidative Desulfurization of Dibenzothiophene at Ambient Temperature Over Low Mn Loaded Co-Mo/Al2O3 and Ni-Mo/Al2O3 Catalysts Using NaClO as Oxidant. Fuel, 237; 793–805
Taher, T., R. Putra, N. R. Palapa, and A. Lesbani (2021). Preparation of Magnetite-Nanoparticle-Decorated NiFe Layered Double Hydroxide and its Adsorption Performance for Congo Red Dye Removal. Chemical Physics Letters, 777; 138712
Teimouri, A., M. Mahmoudsalehi, and H. Salavati (2018). Catalytic Oxidative Desulfurization of Dibenzothiophene Utilizing Molybdenum and Vanadium Oxides Supported on MCM-41. International Journal of Hydrogen Energy, 43(31); 14816–14833
Trisunaryanti, W., M. Ulfa, Y. L. Nikmah, S. D. Sumbogo, S. A. Novianti, and D. A. Fatmawati (2021). ZnO Activated Carbon Blended as a Catalyst for Oxidative Desulfurization of Dibenzothiophene. Bulletin of Chemical Reaction Engineering & Catalysis, 16(4); 881–887
Vallés-García, C., A. Santiago-Portillo, M. Álvaro, S. Navalón, and H. García (2020). MIL-101 (Cr)-NO2 as Efficient Catalyst for The Aerobic Oxidation of Thiophenols and The Oxidative Desulfurization of Dibenzothiophenes. Applied Catalysis A: General, 590; 117340
Wu, M., B. Chang, T. T. Lim, W. D. Oh, J. Lei, and J. Mi (2018). High-Sulfur Capacity and Regenerable Zn-Based Sorbents Derived from Layered Double Hydroxide for Hot Coal Gas Desulfurization. Journal of Hazardous Materials, 360; 391–401
Xie, J., T. Yamaguchi, and J. M. Oh (2021). Synthesis of a Mesoporous Mg-Al-Mixed Metal Pxide with P123 Template for Effective Removal of Congo Red Via Aggregation-Driven Adsorption. Journal of Solid State Chemistry, 293; 121758
Ye, J., J. Wen, D. Zhao, P. Zhang, A. Li, L. Zhang, H. Zhang, and M. Wu (2020). Macroporous 3D Carbon-Nitrogen (CN) Confined MoOx Catalyst for Enhanced Oxidative Desulfurization of Dibenzothiophene. Chinese Chemical Letters, 31(10); 2819–2824
Zeng, X., X. Xiao, Y. Li, J. Chen, and H. Wang (2017). Deep Desulfurization of Liquid Fuels with Molecular Oxygen Through Graphene Photocatalytic Oxidation. Applied Catalysis B: Environmental, 209; 98–109
Zhu, X., C. Chen, Q. Wang, Y. Shi, D. O’Hare, and N. Cai (2019). Roles for K2CO3 Doping on Elevated Temperature CO2 Adsorption of Potassium Promoted Layered Double Oxides. Chemical Engineering Journal, 366; 181–191
Basnet, P., D. Samanta, T. Inakhunbi Chanu, J. Mukherjee, and S. Chatterjee (2019). Assessment of Synthesis Approaches for Tuning The Photocatalytic Property of ZnO Nanoparticles. SN Applied Sciences, 1(6); 1–13
Bazyari, A., A. A. Khodadadi, A. H. Mamaghani, J. Beheshtian, L. T. Thompson, and Y. Mortazavi (2016). Microporous Titania–Silica Nanocomposite Catalyst-Adsorbent for Ultra-Deep Oxidative Desulfurization. Applied Catalysis B: Environmental, 180; 65–77
Chen, L., X. Yang, Y. Tian, Y. Wang, X. Zhao, X. Lei, and F. Zhang (2022). Fabrication of β-Ni(OH)2 Particles by Alkaline Etching Layered Double Hydroxides Precursor for Supercapacitor. Frontiers in Energy Research; 863
Dang, C., W. Yang, J. Zhou, and W. Cai (2021). Porous Ni-Ca-Al-O Bi-Functional Catalyst Derived from Layered Double Hydroxide Intercalated with Citrate Anion for SorptionEnhanced Steam Reforming of Glycerol. Applied Catalysis B: Environmental, 298; 120547
Fraile, J. M., C. Gil, J. A. Mayoral, B. Muel, L. Roldán, E. Vispe, S. Calderón, and F. Puente (2016). Heterogeneous Titanium Catalysts for Oxidation of Dibenzothiophene in Hydrocarbon Solutions with Hydrogen Peroxide: on The Road to Oxidative Desulfurization. Applied Catalysis B: Environmental, 180; 680–686
Gabriel, R., S. H. De Carvalho, J. L. da Silva Duarte, L. M. Oliveira, D. A. Giannakoudakis, K. S. Triantafyllidis, J. I. Soletti, and L. Meili (2021). Mixed Metal Oxides Derived from Layered Double Hydroxide as Catalysts for Biodiesel Production. Applied Catalysis A: General; 118470
Intachai, S., T. Nakato, and N. Khaorapapong (2021). ZnO Decorated on Low Carbonate NiAl-Layered Double Hydroxide as Efficient Photocatalyst for Methyl Orange Degradation. Applied Clay Science, 201; 105927
Kang, L., H. Liu, H. He, and C. Yang (2018). Oxidative Desulfurization of Dibenzothiophene Using Molybdenum Catalyst Supported on Ti-Pillared Montmorillonite and Separation of Sulfones by Filtration. Fuel, 234; 1229-1237
Karim, A. V., A. Hassani, P. Eghbali, and P. Nidheesh (2022). Nanostructured Modified Layered Double Hydroxides (LDHs)-Based Catalysts: a Review on Synthesis, Characterization, and Applications in Water Remediation by Advanced Oxidation Processes. Current Opinion in Solid State and Materials Science, 26(1); 100965
Lesbani, A., A. Agnes, V. Mariska, M. Risfidian, Z. Hilda (2015). Facile Oxidative Desulfurisation of Benzothiophene Using Polyoxometalate H4[????-SiW12O40]/Zr Catalyst. Bulletin of Chemical Reaction Engineering & Catalysis, 10(2); 185–191
Lesbani, A., N. R. Palapa, R. J. Sayeri, T. Taher, and N. Hidayati (2021). High Reusability of NiAl LDH/Biochar Composite in The Removal Methylene Blue from Aqueous Solution. Indonesian Journal of Chemistry, 21(2); 421–434
Li, S. W., W. Wang, and J. S. Zhao (2020). Catalytic Oxidation of DBT for Ultra-Deep Desulfurization Under MoO3 Modified Magnetic Catalyst: The Comparison Influence on Various Morphologies of MoO3. Applied Catalysis A: General, 602; 117671
Luna, M. L., M. A. Taboada-Ortega, M. A. Alvarez-Amparán, and L. Cedeño-Caero (2022). Effect of Iron Incorporation on W Based Catalysts for Oxidative Desulfurization of Dibenzothiophene Compounds. Catalysis Today, 394; 336–347
Lv, H., H. Rao, Z. Liu, Z. Zhou, Y. Zhao, H. Wei, and Z. Chen (2022). NiAl Layered Double Hydroxides with Enhanced Interlayer Spacing Via Ion-Exchange as Ultra-High Performance Supercapacitors Electrode Materials. Journal of Energy Storage, 52; 104940
Mahmoudi, V., A. M. Kermani, M. Ghahramaninezhad, and A. Ahmadpour (2021). Oxidative Desulfurization of Dibenzothiophene by Magnetically Recoverable Polyoxometalate-Based Nanocatalyst: Optimization by Response Surface Methodology. Molecular Catalysis, 509; 111611
Malani, R. S., A. H. Batghare, J. B. Bhasarkar, and V. S. Moholkar (2021). Kinetic Modelling and Process Engineering Aspects of Biodesulfurization of Liquid Fuels: Review and Analysis. Bioresource Technology Reports, 14; 100668
Masoumi, S. and S. A. Hosseini (2020). Desulfurization of DiBenzothiophene from Gasoil Model Using Ni-Co2, Ni-Fe2 and Co-Fe2 Nano Layered-Double Hydroxides as Photocatalysts Under Visible Light. Fuel, 277; 118137
Mgidlana, S., N. Nwahara, and T. Nyokong (2021). Photocatalytic Desulfurization of Dibenzothiophene Using Methoxy Substituted Asymmetrical Zinc(II) Phthalocyanines Conjugated to Metal Tungstate Nanomaterials. Polyhedron, 197; 115053
Mousavi-Kamazani, M., M. Ghodrati, and R. Rahmatolahzadeh (2020). Fabrication of Z-Scheme Flower-Like AgI/Bi2O3 Heterojunctions with Enhanced Visible Light Photocatalytic Desulfurization Under Mild Conditions. Journal of Materials Science: Materials in Electronics, 31(7); 5622–5634
Muhammad, Y., A. Shoukat, A. U. Rahman, H. U. Rashid, and W. Ahmad (2018). Oxidative Desulfurization of Dibenzothiophene Over Fe Promoted Co–Mo/Al2O3 and Ni–Mo/Al2O3 Catalysts Using Hydrogen Peroxide and Formic Acid as Oxidants. Chinese Journal of Chemical Engineering, 26(3); 593–600
Mujahid, A., A. Maryam, A. Afzal, S. Z. Bajwa, T. Hussain, M. I. Din, U. Latif, and M. Irshad (2020). Molecularly Imprinted Poly (Methyl Methacrylate)-Nickel Sulfide Hybrid Membranes for Adsorptive Desulfurization of Dibenzothiophene. Separation and Purification Technology, 237; 116453
Normah, N., N. R. Palapa, T. Taher, R. Mohadi, H. P. Utami, and A. Lesbani (2021). The Ability of Composite Ni/Al-Carbon Based Material Toward Readsorption of Iron(II) in Aqueous Solution. Science and Technology Indonesia, 6(3); 156–165
Palapa, N. R., T. Taher, A. Wijaya, and A. Lesbani (2021). Modification of Cu/Cr Layered Double Hydroxide by Keggin Type Polyoxometalate as Adsorbent of Malachite Green from Aqueous Solution. Science and Technology Indonesia, 6(3); 209–217
Ren, X., G. Miao, Z. Xiao, F. Ye, Z. Li, H. Wang, and J. Xiao (2016). Catalytic Adsorptive Desulfurization of Model Diesel Fuel Using TiO2/SBA-15 Under Mild Conditions. Fuel, 174; 118–125
Rezaee, M., F. Feyzi, and M. R. Dehghani (2021). Extractive Desulfurization of Dibenzothiophene from Normal Octane Using Deep Eutectic Solvents as Extracting Agent. Journal of Molecular Liquids, 333; 115991
Song, Y., J. Bai, S. Jiang, H. Yang, L. Yang, D. Wei, L. Bai, W. Wang, Y. Liang, and H. Chen (2021). Co-Fe-Mo Mixed Metal Oxides Derived from Layered Double Hydroxides for Deep Aerobic Oxidative Desulfurization. Fuel, 306; 121751
Subhan, S., A. U. Rahman, M. Yaseen, H. U. Rashid, M. Ishaq, M. Sahibzada, and Z. Tong (2019). Ultra-Fast and Highly Efficient Catalytic Oxidative Desulfurization of Dibenzothiophene at Ambient Temperature Over Low Mn Loaded Co-Mo/Al2O3 and Ni-Mo/Al2O3 Catalysts Using NaClO as Oxidant. Fuel, 237; 793–805
Taher, T., R. Putra, N. R. Palapa, and A. Lesbani (2021). Preparation of Magnetite-Nanoparticle-Decorated NiFe Layered Double Hydroxide and its Adsorption Performance for Congo Red Dye Removal. Chemical Physics Letters, 777; 138712
Teimouri, A., M. Mahmoudsalehi, and H. Salavati (2018). Catalytic Oxidative Desulfurization of Dibenzothiophene Utilizing Molybdenum and Vanadium Oxides Supported on MCM-41. International Journal of Hydrogen Energy, 43(31); 14816–14833
Trisunaryanti, W., M. Ulfa, Y. L. Nikmah, S. D. Sumbogo, S. A. Novianti, and D. A. Fatmawati (2021). ZnO Activated Carbon Blended as a Catalyst for Oxidative Desulfurization of Dibenzothiophene. Bulletin of Chemical Reaction Engineering & Catalysis, 16(4); 881–887
Vallés-García, C., A. Santiago-Portillo, M. Álvaro, S. Navalón, and H. García (2020). MIL-101 (Cr)-NO2 as Efficient Catalyst for The Aerobic Oxidation of Thiophenols and The Oxidative Desulfurization of Dibenzothiophenes. Applied Catalysis A: General, 590; 117340
Wu, M., B. Chang, T. T. Lim, W. D. Oh, J. Lei, and J. Mi (2018). High-Sulfur Capacity and Regenerable Zn-Based Sorbents Derived from Layered Double Hydroxide for Hot Coal Gas Desulfurization. Journal of Hazardous Materials, 360; 391–401
Xie, J., T. Yamaguchi, and J. M. Oh (2021). Synthesis of a Mesoporous Mg-Al-Mixed Metal Pxide with P123 Template for Effective Removal of Congo Red Via Aggregation-Driven Adsorption. Journal of Solid State Chemistry, 293; 121758
Ye, J., J. Wen, D. Zhao, P. Zhang, A. Li, L. Zhang, H. Zhang, and M. Wu (2020). Macroporous 3D Carbon-Nitrogen (CN) Confined MoOx Catalyst for Enhanced Oxidative Desulfurization of Dibenzothiophene. Chinese Chemical Letters, 31(10); 2819–2824
Zeng, X., X. Xiao, Y. Li, J. Chen, and H. Wang (2017). Deep Desulfurization of Liquid Fuels with Molecular Oxygen Through Graphene Photocatalytic Oxidation. Applied Catalysis B: Environmental, 209; 98–109
Zhu, X., C. Chen, Q. Wang, Y. Shi, D. O’Hare, and N. Cai (2019). Roles for K2CO3 Doping on Elevated Temperature CO2 Adsorption of Potassium Promoted Layered Double Oxides. Chemical Engineering Journal, 366; 181–191
Authors
Ahmad, N., Wijaya, . A. ., Amri, Fitri, E. S. ., Arsyad, F. S. ., Mohadi, R. ., & Lesbani, A. . (2022). Catalytic Oxidative Desulfurization of Dibenzothiophene by Composites Based Ni/Al-Oxide. Science and Technology Indonesia, 7(3), 385–391. https://doi.org/10.26554/sti.2022.7.3.385-391
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.