The Utilization of Modified Chitosan from Shrimp Shell As Photodegradation of Pesticides Paraquat Dichloride
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Keywords:
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Chitosan, Chitosan-ZrO2, Paraquat Dichloride, Photodegradation
Abstract
In this study, the chitosan modification of shrimp shell has been made by impregnated the chitosan from shrimp shell with Ti/ZrO2 and ZrO2 to formed composite of chitosan-Ti/ZrO2 and chitosan-ZrO2. These composites were made by immobilization technique and characterized by FTIR and SEM-EDX. The chitosan-Ti/ZrO2 and chitosan-ZrO2 composite were used as a catalyst to degrade the pesticide paraquat dichloride in the presence of UV light (????= 257 nm). The photodegradation process of paraquat dichloride takes place under 10 watts UV light irradiation and was measured using spectrophotometer UV. The maximum degradation percentage of pesticide paraquat dichloride photodegradation by chitosan-Ti/ZrO2 and chitosan-ZrO2 composites are 61.97% and 57.97% within 30 minutes irradiation time.
References
Ali, R. and S. H. Hassan (2008). Degradation studies onparaquat and malathion using TiO2/ZnO based photocata-lyst.The Malaysian Journal of Analytical Sciences,12(1); 77–87
Ar, F., S. Safni, and Z. Abdullah (2017). Degradation ofParaquat in Gramoxone Pesticide with Addition of ZnO.Molekul,12(2); 159–165
Demircivi, P. and E. B. Simsek (2018). Fabrication of Zr-doped TiO2/chitosan composite catalysts with enhancedvisible-light-mediated photoactivity for the degradation of orange II dye.Water Science and Technology,78(3); 487–495
Eleburuike, N. A., W. A. W. A. Bakar, R. Ali, and M. F. Omar(2016). Photocatalytic degradation of paraquat dichlorideover CeO2-modied TiO2nanotubes and the optimization of parameters by response surface methodology.RSC advances,6(106); 104082–104093
Fil, B. A. (2016). Isotherm, kinetic, and thermodynamic studies on the adsorption behavior of malachite green dye onto montmorillonite clay.Particulate Science and Technology,34(1); 118–126
Kandisa, R. V., K. N. Saibaba, K. B. Shaik, R. Gopinath, et al.(2016). Dye removal by adsorption: a review.Journal of bioremediation and Biodegradation,7(6); 2–4
Kaur, M., A. Verma, H. Setia, and A. P. Toor (2019).Comparative Study on the Photocatalytic Degradation of ParaquatUsing Tungsten-Doped TiO2Under UV and Sunlight. Springer, Singapore
Khodkar, A., S. Khezri, A. Pendashteh, S. Khoramnejadian,and L. Mamani (2019). A designed experimental approach for photocatalytic degradation of paraquat using????-Fe2O3@MIL-101(Cr)@TiO2based on metal-organic framework.International Journal of Environmental Science and technology,16(10); 5741–5756
Kumari, S., S. H. K. Annamareddy, S. Abanti, and P. K. Rath(2017). Physicochemical properties and characterization of chitosan synthesized from sh scales, crab and shrimp shells.International journal of biological macromolecules,104;1697–1705
Moctezuma, E., E. Leyva, E. Monreal, N. Villegas, and D. In-fante (1999). Photocatalytic degradation of the herbicide“paraquat”. Chemosphere,39(3); 511–517
Mohadi, R. (2015). Synthesis Of Nanocomposite Chitosan TiO2And Its Application As Photodegradation Agent OfMethilen Blue In Aqueous Medium.Polish Scientic JournalsDatabase,20; 213–221
Mohadi, R., N. Hidayati, and A. Lesbani (2018). Isolation of????-Chitosan from Squid Bone as Raw Material to Synthesizeof Hybrid Photocatalysts TiO2-Chitosan.Journal of Physics: Conference Series,1095(1); 012032
Nwabor, O. F., S. Singh, S. Paosen, K. Vongkamjan, andS. P. Voravuthikunchai (2020). Enhancement of food shelflife with polyvinyl alcohol-chitosan nanocomposite LMS from bioactive Eucalyptus leaf extracts.Food Bioscience,36;100609
Razali, M. H., C. Ruslimie, W. M. Khairul, et al. (2013). Modification and performances of TiO2photocatalyst towards the degradation of paraquat dichloride.Journal of SustainabilityScience and Management,8(2); 244–253Safari, S., K. von Gunten, M. S. Alam, M. Hubmann, T. A.Blewett, Z. Chi, and D. S. Alessi (2019). Biochar colloids and their use in contaminants removal.Biochar,1(2); 151–162Siregar, P. M. S. B. N., N. R. Palapa, A. Wijaya, E. S. Fitri,and A. Lesbani (2021). Structural stability of Ni/Al layered double hydroxide supported on graphite and biochar toward adsorption of congo red. Science and Technology Indonesia,6(2); 85–95
Ar, F., S. Safni, and Z. Abdullah (2017). Degradation ofParaquat in Gramoxone Pesticide with Addition of ZnO.Molekul,12(2); 159–165
Demircivi, P. and E. B. Simsek (2018). Fabrication of Zr-doped TiO2/chitosan composite catalysts with enhancedvisible-light-mediated photoactivity for the degradation of orange II dye.Water Science and Technology,78(3); 487–495
Eleburuike, N. A., W. A. W. A. Bakar, R. Ali, and M. F. Omar(2016). Photocatalytic degradation of paraquat dichlorideover CeO2-modied TiO2nanotubes and the optimization of parameters by response surface methodology.RSC advances,6(106); 104082–104093
Fil, B. A. (2016). Isotherm, kinetic, and thermodynamic studies on the adsorption behavior of malachite green dye onto montmorillonite clay.Particulate Science and Technology,34(1); 118–126
Kandisa, R. V., K. N. Saibaba, K. B. Shaik, R. Gopinath, et al.(2016). Dye removal by adsorption: a review.Journal of bioremediation and Biodegradation,7(6); 2–4
Kaur, M., A. Verma, H. Setia, and A. P. Toor (2019).Comparative Study on the Photocatalytic Degradation of ParaquatUsing Tungsten-Doped TiO2Under UV and Sunlight. Springer, Singapore
Khodkar, A., S. Khezri, A. Pendashteh, S. Khoramnejadian,and L. Mamani (2019). A designed experimental approach for photocatalytic degradation of paraquat using????-Fe2O3@MIL-101(Cr)@TiO2based on metal-organic framework.International Journal of Environmental Science and technology,16(10); 5741–5756
Kumari, S., S. H. K. Annamareddy, S. Abanti, and P. K. Rath(2017). Physicochemical properties and characterization of chitosan synthesized from sh scales, crab and shrimp shells.International journal of biological macromolecules,104;1697–1705
Moctezuma, E., E. Leyva, E. Monreal, N. Villegas, and D. In-fante (1999). Photocatalytic degradation of the herbicide“paraquat”. Chemosphere,39(3); 511–517
Mohadi, R. (2015). Synthesis Of Nanocomposite Chitosan TiO2And Its Application As Photodegradation Agent OfMethilen Blue In Aqueous Medium.Polish Scientic JournalsDatabase,20; 213–221
Mohadi, R., N. Hidayati, and A. Lesbani (2018). Isolation of????-Chitosan from Squid Bone as Raw Material to Synthesizeof Hybrid Photocatalysts TiO2-Chitosan.Journal of Physics: Conference Series,1095(1); 012032
Nwabor, O. F., S. Singh, S. Paosen, K. Vongkamjan, andS. P. Voravuthikunchai (2020). Enhancement of food shelflife with polyvinyl alcohol-chitosan nanocomposite LMS from bioactive Eucalyptus leaf extracts.Food Bioscience,36;100609
Razali, M. H., C. Ruslimie, W. M. Khairul, et al. (2013). Modification and performances of TiO2photocatalyst towards the degradation of paraquat dichloride.Journal of SustainabilityScience and Management,8(2); 244–253Safari, S., K. von Gunten, M. S. Alam, M. Hubmann, T. A.Blewett, Z. Chi, and D. S. Alessi (2019). Biochar colloids and their use in contaminants removal.Biochar,1(2); 151–162Siregar, P. M. S. B. N., N. R. Palapa, A. Wijaya, E. S. Fitri,and A. Lesbani (2021). Structural stability of Ni/Al layered double hydroxide supported on graphite and biochar toward adsorption of congo red. Science and Technology Indonesia,6(2); 85–95
Authors
Mohadi, R., Rahayu Palapa, N., Hartono, R. ., Hidayati, N. ., & Rozirwan. (2021). The Utilization of Modified Chitosan from Shrimp Shell As Photodegradation of Pesticides Paraquat Dichloride. Science and Technology Indonesia, 6(3), 204–208. https://doi.org/10.26554/sti.2021.6.3.204-208
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